2013 Fiscal Year Final Research Report
Synthesis and properties of silenes and germenes
| Project/Area Number |
23550063
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Kurashiki University of Science and the Arts |
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Principal Investigator |
NAKA Akinobu 倉敷芸術科学大学, 生命科学部, 教授 (00289232)
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| Project Period (FY) |
2011 – 2013
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| Keywords | ケイ素 / ゲルマニウム / シレン / ゲルメン |
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| Research Abstract |
We have synthesized acylpolysilane derivatives and investigated their thermal reactions with acetylenes and dienes. The chemical behavior of silenes produced thermally from acylpolysilanes have been revealed. The theoretical calculations for the reaction mechanism have been also reported.
We have investigated the thermal reactions of acylpolysilylgermanes and carried out theoretical calculations to clarify the reaction mechanism for these reactions. We have reported synthesis and thermal reactions of phenylethynyltris(trimethylsilyl)germane and found production of the germapropadiene derivative as a intermediate.
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[Journal Article] Stereochemistry of Disilanylene- Containing Cyclic Compounds. Thermal reactions of cis- and trans-3, 4-Benzo-1, 2-diisopropyl-1, 2- dimethyl-1, 2-disilacyclobut-3-ene2013
Author(s)
Akinobu Naka, Junnai Ikadai, Jun Sakata, Mitsuo Ishikawa, Yoshihiro Hayashi, Liudmil Antonov, Susumu Kawauchi, Tokio Yamabe
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Journal Title
Organometallics
Volume: 32
Pages: 6476-6487
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