2013 Fiscal Year Final Research Report
The chemistry of lanthanide complexes with crown-ether type vanadate ligands
| Project/Area Number |
23550069
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kanazawa University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
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| Keywords | 多核錯体 / 合成 |
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| Research Abstract |
The chemistry of all-inorganic coordination complexes of lanthanide ions have been developed by using an inorganic macrocyclic ligand of VO4-based-polyoxovanadates. The syntheses of macrocyclic polyoxovanadate ligands and those lanthanide complexes are conducted except a radioactive element. The coordination complexes with 6 to 8 coordination spheres were isolated with a different ring size and a different coordination environment. EXAFS analyses revealed the retention of the structure in acetonitrile solution and the FEFF analysis with interpretation of multiple scattering revealed the detailed information about the structure in solution.
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