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2013 Fiscal Year Final Research Report

Development of an organic-inorganic hybrid-type nitric oxide sensor with high selectivity

Research Project

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Project/Area Number 23550073
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionNagoya Institute of Technology

Principal Investigator

OZAWA tomohiro  名古屋工業大学, 工学(系)研究科(研究院), 准教授 (70270999)

Co-Investigator(Kenkyū-buntansha) 米村 俊昭   (90240382)
Project Period (FY) 2011 – 2013
Keywords金属錯体化学 / 化学センサー
Research Abstract

Suitable concentration of nitric oxide (NO) in human body, which is concerned with a release of blood vessel, immune response, and so on, depends on the roles of enzymes producing it. So, serious diseases such as hardness of the blood vessel and septicemia are caused by out of the concentration. In this study, we focused on the NO concentration in the body and tried to construct an NO sensing system. Metal ions whose formal positive charge is decreased by strong donation from coordination atoms are thought to refuse further electron supplement. This means that the metal ion can interact only with a highly reactive molecules. Modification of such a high NO reactive metal-containing molecule has been tried and characterized. The metal center did not showed a strict NO selectivity any longer, because the metal center directly interacts on the electrode surface.

  • Research Products

    (19 results)

All 2013 2012 2011 Other

All Journal Article (4 results) Presentation (14 results) Remarks (1 results)

  • [Journal Article] High selective binding of nitric oxide by Co^III and Fe^III complexes2013

    • Author(s)
      Z. Zhang, T. Suwabe, M. Ishikawa, Y. Fuhnahashi, T. Inomata, T. Ozawa, H. Masuda
    • Journal Title

      Dalton Trans

      Volume: 42 Pages: 4470-4478

  • [Journal Article] A phosphonium-type ionic liquid-modified Au electrode : A new platform for entrapping functional molecules on substrate surface2013

    • Author(s)
      T. Kitagawa, T. Inomata, Y. Funahashi, T. Ozawa, H. Masuda
    • Journal Title

      Chem. Commuun

      Volume: 49 Pages: 10184-10186

  • [Journal Article] Adsorption behavior of microbes on a QCM chip modified with an artificial siderophore-Fe^<3+> complex2012

    • Author(s)
      T. Inomata, H. Eguchi, Y. Funahashi, T. Ozawa, H. Masuda
    • Journal Title

      Langmuir

      Volume: 28 Pages: 1611-1617

  • [Journal Article] A ternary Ruthenium(II)-2, 2':6', 2"-terpyridine complex having intramolecular π-π stacking interaction with ancillary benzyl groups of the mixed ligands2012

    • Author(s)
      T. Aoki, Y. Wasada-Tsutsui, T. Inomata, T. Ozawa, Y. Funahashi, H. Masuda
    • Journal Title

      J. Chem. Chem. Eng

      Volume: 6 Pages: 363-367

  • [Presentation] NO反応性を有する金属錯体の構築と選択性の検討2013

    • Author(s)
      木本雄也・猪股智彦・舩橋靖博・小澤智宏・増田秀樹
    • Organizer
      第3回CSJ 化学フェスタ
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      20130000
  • [Presentation] Non-covalent modification of a Co(III) complex with high NO selectivity on Au electrode2011

    • Author(s)
      T. Ozawa, T. Kitagawa, T. Yano, Y. Funahashi, T. Inomata, H. Masuda
    • Organizer
      International conference on Material for Advanced Technology
    • Place of Presentation
      Singapole
    • Year and Date
      20110000
  • [Presentation] Characterization of Cobalt (III) complexes as a Functional Material for NO sensing and the Modification on Au electrode2011

    • Author(s)
      Z. Zhang, D. Tsurudome, T. Yano, Y. Wasada-Tsutsui, T. Inomata, Y. Funahashi, T. Ozawa, H. Masuda
    • Organizer
      International conference on Material for Advanced Technology
    • Place of Presentation
      Singapole
    • Year and Date
      20110000
  • [Presentation] 電極修飾部位を有するNO高選択型N2O2-Fe錯体合成と金表面への修飾

    • Author(s)
      石川舞・諏訪部達也・猪股智彦・舩橋康博・小澤智宏・増田秀樹
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山理科大学
  • [Presentation] Co-NO結合二化するN2S2配位環境についての理論的研究

    • Author(s)
      和佐田(筒井)裕子・張子正・橋本智裕・和佐田裕昭・猪股智彦・舩橋靖博・小澤智宏・増田秀樹
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター
  • [Presentation] NO 高選択性を示すFe(III)錯体の構築

    • Author(s)
      石川舞・矢野卓真・小澤智宏・増田秀樹
    • Organizer
      第92日本化学会春季年会
    • Place of Presentation
      慶応大学
  • [Presentation] NOセンシング材料を目指したアミダトチオラト型コバルト(III)錯体の合成と性質

    • Author(s)
      水野嵩麗・矢野卓真・小澤智宏・増田秀樹
    • Organizer
      第92日本化学会春季年会
    • Place of Presentation
      慶応大学
  • [Presentation] NO 高選択性を示すFe(III)錯体の合成と金電極表面への修飾

    • Author(s)
      石川舞・諏訪部達也・猪股智彦・舩橋靖博・小澤智宏・増田秀樹
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学
  • [Presentation] 非配位アミノ基を有するアミドーチオール型コバルト(III)錯体の合成と一酸化窒素との反応性

    • Author(s)
      伊藤大展・猪股智彦・舩橋靖博・小澤智宏・増田秀樹
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
  • [Presentation] Characterization and nitrile hydration reaction of a Ru complex with N2S3 donor sets similar to the active site structure of nitrile hydratase

    • Author(s)
      T. Ozawa, T. Wada, T. Inomata, Y. Funahashi, H. Masuda
    • Organizer
      7th International Conference on Porphyrins and Phthelocyanines
    • Place of Presentation
      Korea
  • [Presentation] アミドーチオール型コバルト(III)錯体の合成と一酸化窒素との反応性

    • Author(s)
      伊藤大展・猪股智彦・小澤智宏・増田秀樹
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      名古屋大学
  • [Presentation] NOセンシングを目的としたコバルト(III)錯体の合成と小分子との反応性

    • Author(s)
      木本雄也・猪股智彦・舩橋靖博・小澤智宏・増田秀樹
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      名古屋大学
  • [Presentation] アミド-チオール型錯体による高選択性NOセンシング材料の開発

    • Author(s)
      伊藤大展・猪股智彦・舩橋靖博・小澤智宏・増田秀樹
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学
  • [Presentation] チオカルボン酸を有する光学活性コバルト(III)錯体の合成と多核化反応

    • Author(s)
      中島美波・松本健司・小澤智宏・米村俊昭
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学
  • [Remarks] ホームページ

    • URL

      http://www/ach.nitech.ac.jp/~inorg/masuda/Japanese/Research/index.html

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Published: 2015-07-16  

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