2013 Fiscal Year Final Research Report
Construction of photoactive supramolecular complexes and the arrangement control of the supramolecular on metallic substrate
| Project/Area Number |
23550074
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nagoya Institute of Technology |
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Principal Investigator |
SHIOTSUKA MICHITO 名古屋工業大学, 工学(系)研究科(研究院), 助教 (70293743)
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| Project Period (FY) |
2011 – 2013
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| Keywords | 超分子金属錯体 / ルテニウム錯体 / 白金錯体 / 自己組織化 / 光誘起電子移動 / 分子スイッチ |
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| Research Abstract |
The ruthenium(II)-platinum(II) supramolecular complexes linked with diethynylphenanthroline were synthesized for exploring the photoinduced electron transfer process under the photo-excited state in these supramolecular complexes.
The ruthenium(II) complexes with thiophenol subsituent were prepared for the construction of self-assemble monolayer on gold substrate. The electrochemical and the photophysical properties of these complexes on gold were reported.
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