Optimization of photochemical reactions in ionic liquids using structural analyses with synchrotron light

2015 Fiscal Year Final Research Report

• Project/Area Number: 23550098
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Analytical chemistry
• Research Institution: Kyushu University
• Principal Investigator: Ishioka Toshio 九州大学, 総合理工学研究科(研究院), 助教 (60304838)
• Project Period (FY): 2011-04-28 – 2016-03-31
• Keywords: 光増感反応 / 小角X線散乱 / ポルフィリン / イオン液体

Outline of Final Research Achievements

This research work is aimed to achieve high performance photosensitized reactions in ionic liquids using the structural analyses with synchrotron radiation. During research activities in five years, various combinations of porphyrins as photosensitizers and ionic liquids were measured with a temperature controlling system. Small-angle X-ray diffraction data showed that disk-like aggregated species were present with rotation diameter of 10 nm and 2 nm thickness when photosensitized reaction rate was higher than other combinations.

Free Research Field

分析化学