2013 Fiscal Year Final Research Report
Development of Highly Electron-poor Phosphine for Highly Active Catalytic Reaction
| Project/Area Number |
23550124
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Iwate University (2012-2013)
Okayama University (2011) |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
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| Keywords | ホスフィン配位子 / フッ素 / 電子不足な配位子 / 金属錯体触媒 / 高活性化 |
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| Research Abstract |
Chiral phosphine ligands have been playing a significant role in both steric and electronic adjustment of transition metal-catalyzed reactions. We developed the novel ligand bearing BFPy groups, which showed highly electron-poor nature surpassing that of C6F5-containing phosphine ligand. The BFPy phosphine ligand accelerated the Rh and Pd-catalyzed reactions including asymmetric catalytic reactions. The catalytic activities exceeded the authentic catalytic reactions.
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Research Products
(18 results)
