• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2013 Fiscal Year Final Research Report

Hydrophilic surface induced by pendant group of amphiphilic block copolymer

Research Project

  • PDF
Project/Area Number 23550132
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

ISHIZONE Takashi  東京工業大学, 理工学研究科, 准教授 (60212883)

Project Period (FY) 2011 – 2013
Keywords高分子合成 / 表面解析 / ブロック共重合体 / 水溶性高分子 / 疎水性高分子 / 親水性 / リビングアニオン重合
Research Abstract

A series of new amphiphilic block copolymers composed of water-soluble polymethacrylate and hydrophobic polydimethylsiloxane were synthesized by the living anionic polymerization and the coupling reaction. Those amphiphilic block copolymers possessed predicted molecular weights and compositions and narrow molecular weight distributions. Flat thin film was prepared by casting the block copolymer solution on a silicon wafer. Although the top surface of the film was covered by the hydrophobic polydimethylsiloxane segment under the vacuum conditions, rapid surface reconstruction occurred by treating the surface with water. After water treatment, the surface was covered with water-soluble polymethacrylate segment. Low glass transition temperatures of both segments and the hydrophilic polymethacrylate segment might play important roles to induce the surface reconstruction.

  • Research Products

    (45 results)

All 2014 2013 2012 2011

All Journal Article (26 results) (of which Peer Reviewed: 26 results) Presentation (10 results) Book (7 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 2 results)

  • [Journal Article] Synthesis of Well-Defined Novel Reactive Block Polymers Containing a Poly(1,4-divinylbenzene) Segment by Living Anionic Polymerization2014

    • Author(s)
      Shunsuke Tanaka, Raita Goseki, Takashi Ishizone, Akira Hirao
    • Journal Title

      Macromolecules

      Volume: 47 Pages: 2333-2339

    • DOI

      10.1021/ma402657t

    • Peer Reviewed
  • [Journal Article] Advances in Living Anionic Polymerization : From Functional Monomers, Polymerization Systems, to Macromolecular Architectures2014

    • Author(s)
      Akira Hirao, Raita Goseki, Takashi Ishizone
    • Journal Title

      Macromolecules

      Volume: 47 Pages: 1883-1905

    • DOI

      10.1021/ma401175m

    • Peer Reviewed
  • [Journal Article] Nonvolatile Organic Field-Effect Transistor Memory Devices Using Polymer Electrets with Different Thiophene Chain Lengths2014

    • Author(s)
      Ying-Hsuan Chou, Sanae Takasugi, Raita Goseki, Takashi Ishizone, Wen-Chang Chen
    • Journal Title

      Polym. Chem.

      Volume: 5 Pages: 1063-1071

    • DOI

      10.1039/c3py01124k

    • Peer Reviewed
  • [Journal Article] Synthesis of 1,3-Dehydroadamantanes Possessing Alkyl, Phenyl, and Alkoxyl Substituents by Intramolecular Wurtz-type Coupling Reaction of 1,3-Dibromoadamantanes2013

    • Author(s)
      Sotaro Inomata, Yusuke Harada, Yuya Nakamura, Taisuke Nakamura, Takashi Ishizone
    • Journal Title

      Synthesis

      Volume: 45 Pages: 3332-3340

    • DOI

      10.1055/s-0033-1338554

    • Peer Reviewed
  • [Journal Article] Successive Synthesis of Well-Defined Multiarmed Miktoarm Star Polymers by Iterative Methodology using Living Anionic Polymerization2013

    • Author(s)
      Shotaro Ito, Raita Goseki, Takashi Ishizone, Akira Hirao
    • Journal Title

      Eur. Polym. J.

      Volume: 49 Pages: 2545-2566

    • DOI

      10.1016/j.eurpolymj.2013.05.014

    • Peer Reviewed
  • [Journal Article] Precise Synthesis of Block Polymers Composed of Three or More Blocks by Specially Designed Linking Methodologies in Conjunction with Living Anionic Polymerization System2013

    • Author(s)
      Yuri Matsuo, Ryuji Konno, Takashi Ishizone, Raita Goseki, Akira Hirao
    • Journal Title

      Polymers

      Volume: 5 Pages: 1012-1040

    • DOI

      10.3390/polym5031012

    • Peer Reviewed
  • [Journal Article] Cationic Ring-Opening Polymerization of Novel 1,3-Dehydroadamantanes with Various Alkyl Substituents : Synthesis of Thermally Stable Poly(1,3-adamantane)s2013

    • Author(s)
      Sotaro Inomata, Yusuke Harada, Yuya Nakamura, Yosuke Uehara, Takashi Ishizone
    • Journal Title

      J. Polym. Sci. Part A : Polym. Chem.

      Volume: 51 Pages: 4111-4124

    • DOI

      10.1002/pola.26820

    • Peer Reviewed
  • [Journal Article] Formation of Ultra Narrow Lamellar Structures in POSS-containing Triblock Terpolymers2013

    • Author(s)
      Raita Goseki, Takashi Ishizone, Akira Hirao, Teruaki Hayakawa
    • Journal Title

      J. Photopolym. Sci. Technol.

      Volume: 26 Pages: 39-44

    • DOI

      10.2494/photopolymer.26.39

    • Peer Reviewed
  • [Journal Article] Synthesis and Reaction of Novel 1,3-Dehydroadamantanes Possessing Phenyl and Alkoxyl Substituents2013

    • Author(s)
      Sotaro Inomata, Yusuke Harada, Shin-ichi Matsuoka, Takashi Ishizone
    • Journal Title

      Tetrahedron

      Volume: 69 Pages: 3238-3248

    • DOI

      10.1016/j.tet.2013.02.042

    • Peer Reviewed
  • [Journal Article] Living Anionic Polymerization of Benzofulvene : Highly Reactive Fixed Transoid 1,3-Diene2013

    • Author(s)
      Yuki Kosaka, Keita Kitazawa, Sotaro Inomata, Takashi Ishizone
    • Journal Title

      ACS Macro Lett.

      Volume: 2 Pages: 164-167

    • DOI

      10.1021/mz4000078

    • Peer Reviewed
  • [Journal Article] Crystallization Behavior of Poly(-caprolactone) Chains Confined in Nanocylinders : Effects of Block Chains Tethered to Nanocylinder Interfaces2013

    • Author(s)
      Shintaro Nakagawa, Takumi Tanaka, Takashi Ishizone, Shuichi Nojima, Yasihiko Kakiuchi, Kazuo Yamaguchi, Seiichi Nakahama
    • Journal Title

      Macromolecules

      Volume: 46 Pages: 2199-2205

    • DOI

      10.1021/ma400071f

    • Peer Reviewed
  • [Journal Article] Successive Synthesis of Miktoarm Star Polymers Having up to Seven Arms by a New Iterative Methodology Based on Living Anionic Polymerization Using a Trifunctional Lithium Reagent2013

    • Author(s)
      Shotaro Ito, Raita Goseki, Takashi Ishizone, Saeko Senda, Akira Hirao
    • Journal Title

      Macromolecules

      Volume: 46 Pages: 819-827

    • DOI

      10.1021/ma3024975

    • Peer Reviewed
  • [Journal Article] Living Anionic Polymerization of 1,4-Divinylbenzene and Its Isomers2013

    • Author(s)
      Shunsuke Tanaka, Masayoshi Matsumoto, Raita Goseki, Takashi Ishizone, Akira Hirao
    • Journal Title

      Macromolecules

      Volume: 46 Pages: 146-154

    • DOI

      10.1021/ma302246u

    • Peer Reviewed
  • [Journal Article] Anionic Polymerization Behavior ofα-Methylene-N-methylpyrrolidone2013

    • Author(s)
      Takashi Ishizone, Keita Kitazawa, Takashi Suzuki, Susumu Kawauchi
    • Journal Title

      Macromol. Symp.

      Volume: 323 Pages: 86-91

    • DOI

      10.1002/masy.201100095

    • Peer Reviewed
  • [Journal Article] Precise Synthesis of New Triblock Co- and Terpolymers by a Methodology Combining Living Anionic Polymers with a Specially Designed Linking Reaction2013

    • Author(s)
      Yuri Matsuo, Toshiyuki Oie, Raita Goseki, Takashi Ishizone, Kenji Sugiyama, Akira Hirao
    • Journal Title

      Macromol. Symp.

      Volume: 323 Pages: 26-36

    • DOI

      10.1002/masy.201100102

    • Peer Reviewed
  • [Journal Article] Local Conformation and Relaxation of Polystyrene at Substrate Interface2012

    • Author(s)
      Hirofumi Tsuruta, Yoshihisa Fujii, Naoki Kai, Hiroshi Kataoka, Takashi Ishizone, Masao Doi, Hiroshi Morita, Keiji Tanaka
    • Journal Title

      Macromolecules

      Volume: 45 Pages: 4643-4649

    • DOI

      10.1002/ma3007202

    • Peer Reviewed
  • [Journal Article] Ring-Opening Polymerizations of 1,3-Dehydroadamantanes : Synthesis of Novel Thermally Stable Poly(1,3-adamantane)s2012

    • Author(s)
      Sotaro Inomata, Shin-ichi Matsuoka, Shiko Sakai, Hiroyuki Tajima, Takashi Ishizone
    • Journal Title

      Macromolecules

      Volume: 45 Pages: 4184-4195

    • DOI

      10.1021/ma300395s

    • Peer Reviewed
  • [Journal Article] Crystallization Behavior and Crystal Orientation of Poly(-caprolatone) Homopolymers Confined in Nanocylinders : Effects of Nanocylinder Dimension2012

    • Author(s)
      Shintaro Nakagawa, Ken-ichi Kadena, Takashi Ishizone, Shuichi Nojima, Takafumi Shimizu, Kazuo Yamaguchi, Seiichi Nakahama
    • Journal Title

      Macromolecules

      Volume: 45 Pages: 1982-1900

    • DOI

      10.1021/ma202566f

    • Peer Reviewed
  • [Journal Article] Thermally robust nanocellular thin films of high-T_g semifluorinated block copolymers foamed with supercritical carbon dioxide2011

    • Author(s)
      Rui Zhang, Cedric Dutriez, Kenji Sugiyama, Takashi Ishizone, Hideaki Yokoyama
    • Journal Title

      Soft Matter

      Volume: 7 Pages: 4032-4038

    • DOI

      10.1039/c0sm00736f

    • Peer Reviewed
  • [Journal Article] Facile Synthesis of Triblock Co- and Terpolymers of Styrene, 2-Vinylpyridine, and Methyl Methacrylate by a New Methodology Combining Living Anionic Diblock Copolymers with a Specially Designed Linking Reaction2011

    • Author(s)
      Akira Hirao, Yuri Matsuo, Toshiyuki Oie, Raita Goseki, Takashi Ishizone, Kenji Sugiyama, André H. Gröschel, Axel H. E. Müller
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 6345-6355

    • DOI

      10.1021/ma201352z

    • Peer Reviewed
  • [Journal Article] Selective Ring-Opening Polymerization of Glycidyl Methacrylate : Toward the Synthesis of Cross-Linked (Co)polyethers with Thermoresponsive Properties2011

    • Author(s)
      Amélie Labbé, Anne-Laure Brocas, Emmanuel Ibarboure, Takashi Ishizone, Akira Hirao, Alain Deffieux, Stéphane Carlotti
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 6356-6364

    • DOI

      10.1021/ma201075n

    • Peer Reviewed
  • [Journal Article] Facile Synthetic Approach to Exact Graft (Co)polymers and Double-Tailed Polystyrene : Linking Reaction of Living Anionic Polymers with Specially Designed In-Chain-Multifunctionalized Polystyrenes2011

    • Author(s)
      Akira Hirao, Masahiro Uematsu, Ryosuke Kurokawa, Takashi Ishizone, Kenji Sugiyama
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 5638-5649

    • DOI

      10.1021/ma200956x

    • Peer Reviewed
  • [Journal Article] Living Anionic Polymerization of 1,4-Divinylbenzene2011

    • Author(s)
      Akira Hirao, Shunsuke Tanaka, Raita Goseki, Takashi Ishizone
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 4579-4582

    • DOI

      10.1021/ma2010487

    • Peer Reviewed
  • [Journal Article] Synthesis of Water-Soluble Poly[oligo(ethylene glycol) methacrylate]s by Living Anionic Polymerization of Oligo(ethylene glycol) Vinyl Ether Methacrylates2011

    • Author(s)
      Jun Yamanaka, Takashi Kayasuga, Mana Ito, Hideaki Yokoyama, Takashi Ishizone
    • Journal Title

      Polym. Chem.

      Volume: 2 Pages: 1837-1848

    • DOI

      10.1039/c1py00118c

    • Peer Reviewed
  • [Journal Article] General and Facile Approach to Exact Graft Copolymers by Iterative Methodology Using Living Anionic In-Chain-Functionalized AB Diblock Copolymers as Key Building Blocks2011

    • Author(s)
      Akira Hirao, Kota Murano, Ahmed Abouelmagd, Masahiro Uematsu, Shotaro Ito, Raita Goseki, Takashi Ishizone
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 3302–3311

    • DOI

      10.1021/ma200186p

    • Peer Reviewed
  • [Journal Article] Precise synthesis of thermo-responsive and water-soluble star-branched polymers and star block copolymers by living anionic polymerization2011

    • Author(s)
      Akira Hirao, Reiko Inushima, Takefumi Nakayama, Takumi Watanabe, Hee-Soo Yoo, Takashi Ishizone, Kenji Sugiyama, Toyoji Kakuchi, Stéphane Carlotti, Alain Deffieux
    • Journal Title

      Eur. Polym. J.

      Volume: 47 Pages: 713-722

    • DOI

      10.1016/j.eurpolymj.2010.11.003

    • Peer Reviewed
  • [Presentation] 高分子合成-基礎から分子設計まで2013

    • Author(s)
      石曽根隆
    • Organizer
      2013年度若手社員のための高分子基礎講座
    • Place of Presentation
      平塚
    • Year and Date
      20131024-26
  • [Presentation] Living Anionic Polymerization of Exomethylene Monomers2013

    • Author(s)
      Takashi Ishizone
    • Organizer
      IUPAC International Symposium on Ionic Polymerization (IP'2013)
    • Place of Presentation
      Japan, Awaji
    • Year and Date
      20130923-28
  • [Presentation] エキソメチレンモノマーのリビングアニオン重合2013

    • Author(s)
      石曽根隆
    • Organizer
      高分子学会第8回茨城地区活動講演会
    • Place of Presentation
      つくば,株クラレつくば研究センター
    • Year and Date
      2013-07-19
  • [Presentation] エキソメチレンモノマーのリビングアニオン重合2013

    • Author(s)
      石曽根隆
    • Organizer
      2013年度フロンティア化学教育研究センターセミナー
    • Place of Presentation
      札幌,北海道大学
    • Year and Date
      2013-06-06
  • [Presentation] Anionic Polymerization of Exo-Methylene Monomers2012

    • Author(s)
      Takashi Ishizone
    • Organizer
      Japan-Korea Joint Symposium 2012
    • Place of Presentation
      Korea, Seoul
    • Year and Date
      20121107-09
  • [Presentation] 高分子合成-基礎から分子設計まで2012

    • Author(s)
      石曽根隆
    • Organizer
      2012年度若手社員のための高分子基礎講座
    • Place of Presentation
      平塚
    • Year and Date
      20121025-27
  • [Presentation] Synthesis of Novel Polymers Containing Adamantyl Skeletons2012

    • Author(s)
      Takashi Ishizone
    • Organizer
      IUPAC MACRO2012
    • Place of Presentation
      USA, Virginia
    • Year and Date
      20120624-29
  • [Presentation] Anionic Polymerizability of N,N-Dialkylmethacrylamides andα-Methylene-N-methylpyrrolidone2011

    • Author(s)
      Takashi Ishizone
    • Organizer
      Japan-Korea Joint Seminar 2011
    • Place of Presentation
      Sapporo
    • Year and Date
      20111031-1101
  • [Presentation] Synthesis of New Polymers Containing Adamantyl Groups2011

    • Author(s)
      Takashi Ishizone
    • Organizer
      2011 Taiwan-Japan Bilateral Polymer Symposium
    • Place of Presentation
      Taiwan, Hsinchu
    • Year and Date
      20110915-16
  • [Presentation] Anionic Polymerizability ofα-Methylene-N-methylpyrrolidone2011

    • Author(s)
      Takashi Ishizone
    • Organizer
      IUPAC International Symposium on Ionic Polymerization (IP'2011)
    • Place of Presentation
      USA, Akron
    • Year and Date
      20110710-15
  • [Book] 高分子ナノテクノロジーハンドブック〜最新ポリマーABC技術を中心に〜,第2編第1章3節アニオン重合(西敏夫編集)2013

    • Author(s)
      石曽根隆
    • Total Pages
      280-287
    • Publisher
      NTS
  • [Book] 高分子基礎科学One Point 2精密重合II:イオン・配位・開環・逐次重合,第2章アニオン重合(中健介編著)2013

    • Author(s)
      石曽根隆
    • Total Pages
      9-30
    • Publisher
      高分子学会
  • [Book] Polymer Science : A Comprehensive Reference. K. Matyjaszewski, M. Möller (Ed.), Chapter 3.18 Anionic Polymerization of Protected Functional Monomers2012

    • Author(s)
      Takashi Ishizone, Kenji Sugiyama, Akira Hirao
    • Total Pages
      591-621
    • Publisher
      Elsevier
  • [Book] Synthesis of Polymers : New Structures and Methods, First Edition. A. D. Schlüter, Craig J. Hawker, Junji Sakamoto (Ed.). Chapter 5. Anionic Polymerization : Recent Advances2012

    • Author(s)
      Takashi Ishizone, Akira Hirao
    • Total Pages
      81-133
    • Publisher
      WILEY
  • [Book] マンガ+要点整理+演習問題でわかる高分子化学2012

    • Author(s)
      齋藤勝裕,石曽根隆
    • Total Pages
      203
    • Publisher
      オーム社
  • [Book] Complex Macromolecular Architectures : Synthesis, Characterization, and Self-Assembly, Nikos Hadjichristidis, Akira Hirao, Yasuyuki Tezuka, Filip Du Prez (Ed.), Chapter 14. Synthesis of Well-Defined Poly(meth)acrylamides with Varied Stereoregularity by Living Anionic Polymerization2011

    • Author(s)
      Takashi Ishizone
    • Total Pages
      431-460
    • Publisher
      WILEY
  • [Book] ベーシックマスター高分子化学,第10章,アニオン重合(西久保忠臣編)2011

    • Author(s)
      石曽根隆
    • Total Pages
      206-236
    • Publisher
      オーム社
  • [Patent(Industrial Property Rights)] 耐熱性に優れる重合体の製造方法2013

    • Inventor(s)
      石曽根 隆,大木 弘之,加藤 利典
    • Industrial Property Rights Holder
      国立大学法人東京工業大学,株式会社クラレ
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特願2011-174585,特開2011-252164,特許5362790
    • Filing Date
      2013-09-13
    • Overseas
  • [Patent(Industrial Property Rights)] インダン系重合体及びその製造方法、 並びにインデン系重合体及びその製造方法2012

    • Inventor(s)
      石曽根 隆,椎橋 彬,高嶋 務
    • Industrial Property Rights Holder
      国立大学法人東京工業大学,JX日鉱日石エネルギー株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特願2012-046994,特開2011-193362
    • Filing Date
      2012-03-02
    • Overseas

URL: 

Published: 2015-07-16  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi