2013 Fiscal Year Final Research Report
Facile development of metal-free immortal polymerization of epoxide to synthesize the corresponding functional polymers
| Project/Area Number |
23550144
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Kochi National College of Technology |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
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| Keywords | 高分子合成化学 / イモータル重合 / 開環重合 / エポキシド / メタルフリー |
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| Research Abstract |
This study was carried out to develop a metal-free immortal polymerization of epoxide and to synthesize various kinds of functional polymers as its applications. Specific conclusions are as follows;
1) The metal-free immortal polymerization of epoxide was successfully developed by using commercially available tetra-n-butylammonium fluoride as an initiator. 2) Various kinds of functional polymers such as amphiphilic block copolymers, end-functional polymers, and branched polymers were facilely synthesized by this metal-free immortal polymerization.
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[Journal Article]2011
Author(s)
Hisatoyo Morinaga, Yusuke Ujihara, Naho Yuto, Daisuke Nagai, and Takeshi Endo
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Journal Title
Journal of Polymer Science, Part A : Polymer Chemistry
Volume: Volume 49, Issue 24
Pages: 5210–5216
Peer Reviewed
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