2013 Fiscal Year Final Research Report
Construction of organic-inorganic interface via covalent bonds
| Project/Area Number |
23550165
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Doshisha University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
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| Keywords | 有機―無機複合体 / アルコール / ポルフィリン / 有機薄膜 |
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| Research Abstract |
Bonding of organic molecules on solid inorganic surface is important for development of organic-inorganic hybrid materials. The reaction can be applied to fabrication of bioceramics, organic solar cells and transistors, and organic catalyst on silica gel. Condensation of alcohols and silanols on silicate glass was investigated. We found that tertiary alcohol, which has been considered to be inert, was bonded to silicate glass and the resulting film was stable against alkaline hydrolysis.
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