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2013 Fiscal Year Final Research Report

Rsisue analysis of low molecular weight insectitides with immunoassay

Research Project

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Project/Area Number 23550179
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental chemistry
Research InstitutionToyohashi University of Technology

Principal Investigator

IWASA SEIJI  豊橋技術科学大学, 工学(系)研究科(研究院), 教授 (30303712)

Project Period (FY) 2011 – 2013
Keywords残留農薬 / モノクロナール抗体 / ハプテン / 有機合成 / 触媒反応 / ELISA / イムノアッセイ / ポジティブリスト制
Research Abstract

To develop a residue analysis of low molecular agricultural chemicals is one of most important subjects as for both human health and environmental consideration. For this regard, our objective of this research project is to develop a simple analytical method with immunoassay being comparable to conventional instrumental analysis. During this research project, we established residue analysis of fungicides, azoxystrobin and chlorothalonil with immunoassay in the range from ppm to ppb. This system is simple, rapid, cost-effective, high mobility and high throughput analytical method and now commercially available.

  • Research Products

    (16 results)

All 2014 2013 2012 2011

All Journal Article (10 results) Presentation (6 results)

  • [Journal Article] Development of Direct Competitive ELISA for Residue Analysis of Fungicide Chlorothalonil in Vegetables2014

    • Author(s)
      Okazaki, F.; Hirakawa, Y.; Yamaguchi (Murakami), Y.; Harada, A.; Watanabe, E.; Iwasa, S.; Narita, H.; Miyake, S.
    • Journal Title

      Food Hygiene and Safety Science

      Volume: 55 Pages: 65-72

  • [Journal Article] Highly Stereoselective Synthesis of Cyclopropylphosphonates Catalyzed by Chiral Ru(II)-Pheox Complex2014

    • Author(s)
      Chanthamath, S.; Ozaki, S,; Shibatomi, K.; Iwasa, S.
    • Journal Title

      Organic Letters

      Volume: 16 Pages: 3012–3015

    • DOI

      10.1021/ol501135p

  • [Journal Article] Highly Regio- and Stereoselective Synthesis of Alkylidenecyclopropanes via Ru(II)-Pheox Catalyzed Asymmetric Inter- and Intramolecular Cyclopropanation of Allenes2014

    • Author(s)
      Chanthamath, S.; Chua, H. W.; Kimura, S.; Shibatomi, K.; Iwasa, S.
    • Journal Title

      Organic. Letters

      Volume: 16 (in press)

  • [Journal Article] Quinones Synthesis via Hydrogen Peroxide Oxidation of Dihydroxy Arenes Catalyzed by Homogeneous and Macroporous-Polymer-Supported Ruthenium Catalysts2013

    • Author(s)
      Abu-Elfotoh, A. -M.; Tsuzuki, K.; Nguyen, B. T.; Chanthamath, S.; Shibatomi, K.; Iwasa, S.
    • Journal Title

      Tetrahedron

      Volume: 69 Pages: 8612-6817

  • [Journal Article] Highly Stereoselective Cyclopropanation of α, β-Unsaturated Carbonyl Compounds with Methyl (diazoacetoxy)acetate Catalyzed by Chiral Ru(II)-Pheox Complex2013

    • Author(s)
      Chanthamath, S.; Takaki, S.; Shibatomi, K.; Iwasa, S.
    • Journal Title

      Angewandte Chemie International Editions

      Volume: 52 Pages: 5930-5933

  • [Journal Article] Highly Enantioselective Synthesis of Cyclopropylamine Derivatives via Ru(II)-Pheox Catalyzed Direct Asymmetric Cyclopropanation of Vinylcarbamates2013

    • Author(s)
      Chanthamath, S.; Nguyen, D.; Shibatomi, K.; Iwasa, S.
    • Journal Title

      Organic Letters

      Volume: 15 Pages: 772-775

  • [Journal Article] Water-Soluble Chiral Ruthenium(II) Phenyloxazoline Complex: Reusable and Highly Enantioselective Catalyst for Intramolecular Cyclopropanation Reactions2012

    • Author(s)
      Abu-Elfotoh, A.-M.; Thi Nguyen, D. P.; Chanthamath, S.; Phomkeona, K.; Shibatomi, K.; Iwasa, S.
    • Journal Title

      Advanced Synthesis & Catalysis

      Volume: 354 Pages: 3435-3439

  • [Journal Article] Ru(II)-Pheox Catalyzed N-H Insertion Reaction of Diazoacetamides: Synthesis of N-Substituted α-Aminoamides2012

    • Author(s)
      Chanthamath, S.; Thongjareun, S.; Shibatomi, K.; Iwasa, S.
    • Journal Title

      Tetrahedron Letters

      Volume: 53 Pages: 4862-4865

  • [Journal Article] Highly Stereoselective Ru(II)-Pheox Catalyzed Asymmetric Cyclopropanation of Terminal Olefins with Succinimidyl Diazoacetate2012

    • Author(s)
      Chanthamath, S.; Phomkeona, K.; Shibatomi, K.; Iwasa, S.
    • Journal Title

      Chemical Communications

      Volume: 48 Pages: 7750-7752

  • [Journal Article] Development of Enzyme-Linked Immunosorbent Assay for Residue Analysis of the Fungicide Azoxystrobin in Garden Crops2012

    • Author(s)
      Kondo, M.; Tsuzuki, K.; Hamada, H.; Yamaguchi (Murakami), Y.; Uchigashima, M.; Saka, M.; Iwasa, S.; Narita, H.; Miyake, S.
    • Journal Title

      Journal of Agricultural and Food Chemistry

      Volume: 60 Pages: 904-911

  • [Presentation] Ru(II)-Pheox Catalyzed Asymmetric Cyclopropanation of Diethyl Diazomethylphosphonate with Various Alkenes2014

    • Author(s)
      S. Chanthamath, S. Ozaki, K. Shibatomi and S. Iwasa
    • Organizer
      International Conference of Organometallic Chemistry
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      20140700
  • [Presentation] フェニルオキサゾリン−Ru(II)触媒を用いる新規アレンジアゾアセテートの不斉分子内シクロプロパン化反応2013

    • Author(s)
      Chua Hao Wei, Chanthamath Soda, 柴富一孝, 岩佐精二
    • Organizer
      第44回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      浜松 (2P61)
    • Year and Date
      20130000
  • [Presentation] Ru(II)-Pheox触媒による高立体選択的シクロプロピルホスホネート類の合成2013

    • Author(s)
      Chanthamath Soda, 尾崎星也, 柴富一孝, 岩佐精二
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      東京 (P1A-15)
    • Year and Date
      20130000
  • [Presentation] Highly Enantioselective Synthesis of Alkylidenecyclopropanes via Ru(II)-Pheox Catalyzed Asymmetric Cyclopropanation of Allenes with Succinimidyl Diazoacetate2012

    • Author(s)
      S. Chanthamath, S. Kimura, K. Shibatomi, S. Iwasa
    • Organizer
      International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12)12th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12)
    • Place of Presentation
      Kyoto (Abstract p193 (PC-022))
    • Year and Date
      20121112-16
  • [Presentation] Ru(II)-Pheox触媒によるメチル(ジアゾセトキシ)アセテートのα,β−不飽和カルボニル化合物への不斉シクロプロパン化反応2012

    • Author(s)
      Chanthamath Soda, 柴富一孝, 岩佐精二
    • Organizer
      日本化学会第92春期年会
    • Place of Presentation
      横浜 (1PB037)
    • Year and Date
      20120000
  • [Presentation] フェニルオキサゾリン−Ru(II)触媒を用いる新規アセトニルジアゾアセテートの高速及び高立体選択的シクロプロパン化反応2011

    • Author(s)
      Chua Hao Wei, Chanthamath Soda, 柴富一孝, 岩佐精二
    • Organizer
      第42回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      長野 (Abst. pp.99-99)
    • Year and Date
      20111106-07

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Published: 2015-07-16  

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