2013 Fiscal Year Final Research Report
Elucidation and application of the multifunctional expression mechanism of the environment-oriented optical active hybrid complex
| Project/Area Number |
23550181
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Environmental chemistry
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| Research Institution | Kochi University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
OZAWA Tomohiro 名古屋工業大学, 工学研究科, 准教授 (70270999)
UEDA Tadaharu 高知大学, 教育研究部総合科学系, 准教授 (50294822)
MATSUMOTO Kenji 高知大学, 教育研究部総合科学系, 助教 (30398713)
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| Project Period (FY) |
2011 – 2013
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| Keywords | 環境対応 / 複合材料 / 物性・合成化学 / イオン結晶 |
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| Research Abstract |
We found a specific method to prepare the optical active polynuclear complexes stereoselectively, and on the other hand, it could obtain a various formation ratio by the use of other complexes. Furthermore, it is clarified that we could easily change the polynuclear structures when we changed the substituent of the ligands. We were able to get the knowledge concerning the additional factor for the chiral selectivity in the environmental response type complexes. Since there were remarkable differences between the stereospecificity and the solubility in those products, it is thought that the value as the useful materials are risen. These study contents, which aim at the development of the environmental response type optical active polynuclear complexes, continually examine after a grant period, and we want to enlarge the functional expression using this system.
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[Journal Article] Enantioselective Monofluoro- methylation of Aldehydes with 2-Fluoro-1,3- benzodithiole-1,1,3,3-tetraoxide Catalyzed by a Bifunctional Cinchona Alkaloid-derived Thiourea-titanium Complex2013
Author(s)
H. Ma, K. Matsuzaki, Y. Yang, E. Tokunaga, D. Nakane, T. Ozawa, H. Masuda and N. Shibata
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Journal Title
Chem. Commun.
Volume: 49
Pages: 11206-11208
Peer Reviewed
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