2013 Fiscal Year Final Research Report
Development of functional electrodes using ionic liquid-modified substrates
| Project/Area Number |
23550206
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Functional materials/Devices
|
|---|
| Research Institution | Nagoya Institute of Technology |
|---|
Principal Investigator |
INOMATA Tomohiko 名古屋工業大学, 工学(系)研究科(研究院), 助教 (40397493)
|
|---|
| Project Period (FY) |
2011 – 2013
|
| Keywords | イオン液体 / 修飾電極 / 酸素活性化 / 4電子還元 / 自己組織化 |
|---|
| Research Abstract |
A quaternary ammonium-type ionic liquid with terminal olefins was synthesized and its self-assembled monolayer was prepared. The obtained ionic liquid-modified electrode had spaces due to steric and electrostatic repulsions among the ionic liquid units on the electrode. Then, a diiron complex, which was able to activate O2 molecule, was introduced into the spaces on the electrode. Finally, terminal olefins were cross-linked by the olefin metathesis reaction with Grubbs reagent. The diiron complex was strongly immobilized in the ionic liquid layer. From the measurements by a rotating ring-disk electrode, the number of electrons during the O2 reduction was n = 3.8, indicating that the 4-electron reduction process was dominant.
|
Research Products
(38 results)
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
[Patent(Industrial Property Rights)] 光増感剤2012
Inventor(s)
増田秀樹,小澤智宏,舩橋靖博,猪股智彦,川合佑弥
Industrial Property Rights Holder
名古屋工業大学
Industrial Property Rights Type
特許
Industrial Property Number
特願2012-005831
Filing Date
2012-01-16
Overseas
-
[Patent(Industrial Property Rights)] 光増感剤2012
Inventor(s)
増田秀樹,小澤智宏,舩橋靖博,猪股智彦,山本浩輔
Industrial Property Rights Holder
名古屋工業大学
Industrial Property Rights Type
特許
Industrial Property Number
特願2012-083440
Filing Date
2012-04-02
Overseas
-
-
-
-
-
