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2013 Fiscal Year Final Research Report

Interface Control of Molecular Devices Composed of Semiconducting Fulleride Crystals

Research Project

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Project/Area Number 23550211
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials/Devices
Research InstitutionToho University

Principal Investigator

MORIYAMA Hiroshi  東邦大学, 理学部, 教授 (10126188)

Project Period (FY) 2011 – 2013
Keywordsフラーライド / 有機電子材料 / 分子素子 / 界面制御 / デバイス / X線結晶構造解析 / 電気伝導度 / 電子状態
Research Abstract

Fullerene C60 has high electron affinity and gives anion species named fullerides by accepting an electron. In this study, we have synthesized novel fulleride compounds, especially by using the electrocrystallization method, intended as interface materials in organic solids, and we have investigated their fundamental conditions to clarify their functionality and improve the properties of the molecular devices fabricated from these fulleride materials. Furthermore, we have developed organic molecular devices based on fulleride interfaces by improving the device properties and fabricating robust and dense self-assembled organic layers. In particular, we have synthesized new fulleride crystals and investigated the correlation between structure and properties. We have also investigated their ability to improve the performance of organic photovoltaics.

  • Research Products

    (18 results)

All 2014 2013 2012 2011

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (4 results) Book (2 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 3 results)

  • [Journal Article] Immobilization of Supramolecular Chiral Porphyrin Homoassociates at the Air-Water Interface2014

    • Author(s)
      H. Harada, H. Moriyama, H. Takahashi, K. Umemura, H. Yokota, R. Kawakami, K. Mishima
    • Journal Title

      Appl. Spectrosc.

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] Iionic Conductivity of [Li^+@C_60](PF_6) in organic Solvents and its Electrochemical Reduction to Li^+@C_<60>2013

    • Author(s)
      H. Ueno, K. Kokubo, Y. Nakamura, K. Phkubo, N. Ikuma, H. Moriyama, S. Fukuzumi, T. Oshima
    • Journal Title

      Chem. Commun.

      Volume: 49 Pages: 7376-7378

    • DOI

      10.1039/c3cc43901a

    • Peer Reviewed
  • [Journal Article] Artificial Model System of Fe(III)TMPyP–MBTH–O_2 to Form Peroxide and Azine from MBTH : Reactivity of Superoxohemin (Fe(III)TMPyP–OO^) and Peroxohemin (Fe(III)TMPyP–OO^–)2013

    • Author(s)
      T. Nakano, H. Kakuda H. Shinoda, H. Moriyama
    • Journal Title

      Bull. Chem. Soc. Jp.

      Volume: 86 Pages: 620-627

    • DOI

      10.1246/bcsj.2012.03282

    • Peer Reviewed
  • [Journal Article] On-Off Switching of the Novel Thermochromic Chiroptical Behavior of Psueudoisocyanine Driven by Association /Dissociation2012

    • Author(s)
      H. Harada, R. Kurihara, R. Kurodam H. Moriyama
    • Journal Title

      Chem. Lett.

      Volume: 41 Pages: 1442-1444

    • DOI

      10.1246/cl.2012.1442

    • Peer Reviewed
  • [Journal Article] Synthesis and Characterixation of C_<60>/Polyaniline Composites from Interfacial Polymerization2012

    • Author(s)
      Q. Wang, S. Wang, J. Li, H. Moriyama
    • Journal Title

      J. Polym. Sci. Part B, Polym. Phys

      Volume: 50 Pages: 1426-1432

    • DOI

      10.1002/polb.23142

    • Peer Reviewed
  • [Journal Article] Solid-state Circularity Polarized Luminescence Measurements : Theoretical Analysis2012

    • Author(s)
      H. Harada, R. Kuroda, H. Moriyama
    • Journal Title

      Chem. Phys. Lett.

      Volume: 520 Pages: 126-131

    • DOI

      10.1016/j.cplett.2012.01.059

    • Peer Reviewed
  • [Journal Article] Supramolecular Chirality Measurement of an Optically Anomalous Single Crystal2012

    • Author(s)
      H. Harada, N. Asano N. Tajima, H. Moriyama
    • Journal Title

      Chem. Lett.

      Volume: 41 Pages: 452-454

    • DOI

      10.1246/cl.2012.452

    • Peer Reviewed
  • [Journal Article] Carbon Nanotube-based Thin Films : Synthesis and Properties2011

    • Author(s)
      Q. Wang, H. Moriyama
    • Journal Title

      Carbon Nanotube : Syntheis,, Characterization, Application"(ed, by S. Yellampalli,)

      Volume: Chapter 23 Pages: 487-514

    • DOI

      10.5772/22021

    • Peer Reviewed
  • [Journal Article] Photocurrent Generation of Heterostructured Films Composed of Donor-Acceptorandd Donor-Insulator Networks on ITO Electrodes2011

    • Author(s)
      K. Kanaizuka, S. Kato, H. Moriyama,C. Pac
    • Journal Title

      J. Mater. Res.

      Volume: 26 Pages: 236-239

    • DOI

      10.1557/jmr.2010.21

    • Peer Reviewed
  • [Presentation] Development of Novel n-type Fullerene Derivatives for Potential Printable OPV Use2013

    • Author(s)
      H. Moriyama, T. Hayashi, K. Matsumoto, Y. Kawai, K. Uchiyama, M. Igarashi, J. Oh, H. Lee, J. Jang, C. Pac
    • Organizer
      2013 International Workshop on Flexible and Printable Electronics
    • Place of Presentation
      Jeonju, Korea
    • Year and Date
      2013-11-22
  • [Presentation] Synthesis and Characterization of Fullerene Derivatives with Thiophene Moiety in Organic Photo -voltaic Devices2013

    • Author(s)
      T. Hayashi, J. Oh, H. Lee, J.-J. Ann, J. S. Lee, J. Jang, C. Pac, H. Moriyama
    • Organizer
      2013 International Workshop on Flexible and Printable Electronics
    • Place of Presentation
      Jeonju, Korea
    • Year and Date
      2013-11-21
  • [Presentation] Novel Fullerene Derivatives with Phosphonic Ester on Organic Photovoltaic Devices2012

    • Author(s)
      S. Miura, J. Oh, M. Ryu, H. Lee, J. Jang, C. Pac, H. Moriyama
    • Organizer
      The 7^<th> Aseanian Conference on Dye- Sensitized and Organic Solar Cells (DSC-OPV7)
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2012-10-27
  • [Presentation] A Structural Effect in Novel Electron Acceptors of C_<60> Derivatives with Poly(3-hexyl- thiophene) for Organic Photovoltaic Application2011

    • Author(s)
      S. Miura, J. Oh, M. Ryu, H. Lee, J. Jang, C. Pac, H. Moriyama
    • Organizer
      The 6^<th> Aseanian Conference on Dye-sensitized and Organic Solar Cells (DSC-OPV6)
    • Place of Presentation
      Beppu, Japan
    • Year and Date
      2011-10-17
  • [Book] フラーレン誘導体・内包技術の最前線(分担執筆5.ハロゲン化フラーレンを用いた多付加フラーレンの合成)2014

    • Author(s)
      内山幸也、五十嵐望紀、森山広思
    • Total Pages
      70-79
    • Publisher
      シーエムシー出版
  • [Book] フラーレン誘導体・内包技術の最前線(分担執筆4.メタノフラーレンを中心とした電子受容体材料の性能評価)2014

    • Author(s)
      林達也、三浦匠悟、森山広思
    • Total Pages
      187-197
    • Publisher
      シーエムシー出版
  • [Patent(Industrial Property Rights)] フラーレン誘導体及びその製造方法、並びにその利用2013

    • Inventor(s)
      森山廣思、内山幸也
    • Industrial Property Rights Holder
      森山廣思、内山幸也
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特願2013-194209
    • Filing Date
      2013-03-04
    • Overseas
  • [Patent(Industrial Property Rights)] フラーレン誘導体及びその製造方法、並びにその利用2012

    • Inventor(s)
      森山廣思、内山幸也
    • Industrial Property Rights Holder
      森山廣思、内山幸也
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特願2012-194209
    • Filing Date
      2012-09-08
    • Overseas
  • [Patent(Industrial Property Rights)] 円二色性スペクトルの測定方法および測定装置2011

    • Inventor(s)
      原田拓典、森山広思
    • Industrial Property Rights Holder
      原田拓典、森山広思
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特願2011-188685
    • Filing Date
      2011-08-31
    • Overseas

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Published: 2015-07-16   Modified: 2023-03-16  

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