2013 Fiscal Year Final Research Report
Development of Fullerene Monolayer Characterized by Fluoroalkyl and Gemini
| Project/Area Number |
23550216
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic industrial materials
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| Research Institution | Kyoto Institute of Technology |
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Principal Investigator |
KAWASE TOKUZO 京都工芸繊維大学, 工芸科学研究科, 教授 (60152956)
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| Project Period (FY) |
2011 – 2013
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| Keywords | フラーレン / Aziridinofullerene / 単分子膜 / 表面圧－面積測定 / 2鎖多親水基型 / フルオロメチレン鎖 / フルオロアルキル基3鎖型 |
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| Research Abstract |
In this study, with focusing on the alignment control of C60 monolayer, aziridinofullerene deicatives were synthesized to investigate the new concepts of (1) two-chain and multi-hydrophilic structure and (2) the rigid fluoroalkyl chain, and also (3) a novel film forming method of C60 over the monolayer of three-fluoroalkyl chain material as matrix molecules.
From surface pressure-area measurements, C2v symmetry aziridinofullerenes showed the limiting area of 1.25nm2. Also, the rigidity of fluoroalkyl chain was proved very effective in the alignment control of C60. In addition, C60 monolayer formation would proceed successfully over the monolayer of matrix molecules.
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