2013 Fiscal Year Final Research Report
Development of highly selective metal nanoparticle catalytic reaction in supercritical carbon dioxide
| Project/Area Number |
23550218
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic industrial materials
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| Research Institution | Kinki University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
FUJIHARA Hisashi 近畿大学, 理工学部, 教授 (30190101)
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| Project Period (FY) |
2011 – 2013
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| Keywords | 超臨界二酸化炭素 / 金属ナノ粒子 / 触媒 / キラリティ / フッ化アルキル基 / BINAP |
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| Research Abstract |
In this study, asymmetric Suzuki-Miyaura cross coupling reaction was discussed in supercritical carbon dioxide with optically-active Pd nanoparticles as a catalyst possessing specific affinity for supercritical carbon dioxide. Examination for various combinations of solubilization agent and co-catalyst resulted in both higher reactivity and higher selectivity comparing to the reaction in organic solvent when ethylene glycol and silver oxide were used as a solubilization agent and a co-catalyst respectively.
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