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2013 Fiscal Year Final Research Report

Creation of chiral interlayer catalytic system by use of straddled pillar complexes and inorganic layer crystal hosts

Research Project

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Project/Area Number 23560929
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionChiba University

Principal Investigator

SHIMAZU Shogo  千葉大学, 工学(系)研究科(研究院), 教授 (10178957)

Project Period (FY) 2011 – 2013
Keywords不斉水素化 / 粘土鉱物 / キラルピラー錯体 / プロキラルカルボニル化合物 / キラル層間触媒 / ロジウム錯体 / インターカレーション / 開脚型錯体
Research Abstract

The asymmetric hydrogenation using our newly developed "chiral interlayer catalysts" is described. Generally chiral homogeneous catalyst can be created by use of bulky ligands to fix the chiral conformation. Because the main drawback of the homogenous catalytic system is usually pointed out the difficulty in catalyst separation from the products and the recycling, we have developed a new type of catalysts, i.e., chiral interlayer catalysts have been synthesized by the intercalation of chiral Rh(I) pillar complexes (Straddled chiral pillar complexes) with linear alkyl chains into lithium taeniolite (LiTN). We found that the long alkyl chain groups in the pillar complexes were held between layers as a linear chain shape and the interlayer spacing was proportional to the chain length. By means of our novel chiral interlayer catalysts, we attained the asymmetry selectivity exceeding the corresponding homogeneous catalysts as well as the comparable high activity with the homogeneous ones.

  • Research Products

    (15 results)

All 2014 2013 2012 2011

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (3 results) Book (2 results)

  • [Journal Article] Iron Oxide-pillared Clay Catalyzed the Synthesis of Acetonides from Epoxides2014

    • Author(s)
      P. Trikittiwong, N. Sukpirom, S. Shimazu, W. Chavasiri
    • Journal Title

      Catalysis Communications

    • DOI

      10.1016/j.catcom.2014.05.002

    • Peer Reviewed
  • [Journal Article] Recyclable Pd-incorporated perovskite-titanate catalysts synthesized in molten salts for the liquid-phase oxidation of alcohols with molecular oxygen2013

    • Author(s)
      I. B. Adilina, T. Hara, N. Ichikuni, N. Kumada, and S. Shimazu
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 86(1) Pages: 146-152

    • Peer Reviewed
  • [Journal Article] Low temperature synthesis of ATiO_3 (A:Mg, Ca, Sr, Ba) by using molten salt2013

    • Author(s)
      N. Kumada, A. Miura, T. Takei, I. B. Adilina and S. Shimazu
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 121 Pages: 74-79

    • Peer Reviewed
  • [Journal Article] Ring-opening of oxiranes using taeniolite-supported tris(β-diketonato)zirconium2012

    • Author(s)
      Y. Permana, N. Ichikuni, S. Shimazu
    • Journal Title

      ITB Journal of Science

      Volume: 44 A(3) Pages: 263-274

    • Peer Reviewed
  • [Journal Article] Highly efficient and selective hydrogenation of unsaturated carbonyl compounds using Ni-Sn alloy catalysts2012

    • Author(s)
      Rodiansono, T. Hara, N. Ichikuni, and S. Shimazu
    • Journal Title

      Catalysis Science & Technology

      Volume: 2(10) Pages: 2139-2145

    • Peer Reviewed
  • [Journal Article] Oxidative cleavage of isoeugenol to vanillin under molecular oxygen catalysed by cobalt porphyrin intercalated into lithium taeniolite clay2012

    • Author(s)
      I. B. Adilina, T. Hara, N. Ichikuni, and S. Shimazu
    • Journal Title

      J. Mol. Catal. A:Chem.

      Volume: 361-362 Pages: 72-79

    • Peer Reviewed
  • [Journal Article] A Novel Preparation Method of Ni-Sn Alloy Catalysts Supported on Aluminium Hydroxide:Application to Chemoselective Hydrogenation of Unsaturated Carbonyl Compounds2012

    • Author(s)
      Rodiansono, T. Hara, N. Ichikuni, and S. Shimazu
    • Journal Title

      Chemistry Letters

      Volume: 41(8) Pages: 769-771

    • Peer Reviewed
  • [Journal Article] Preparation of Clay-Supported Sn Catalysts and Application to Baeyer-Villiger Oxidation2012

    • Author(s)
      T. Hara, M. Hatakeyama, A. Kim, N. Ichikuni, and S. Shimazu
    • Journal Title

      Green Chem.

      Volume: 14(3) Pages: 771-777

    • Peer Reviewed
  • [Journal Article] An anionic D-Valine-Palladium(II) Complex Supported on Hydroxy Double Salt with Brønsted Basic Phosphate Anion:Application for Heterogeneous Catalyst toward Aerobic Alcohol Oxidation2011

    • Author(s)
      T. Hara, J. Sawada, Y. Nakamura, N. Ichikuni, and S. Shimazu
    • Journal Title

      Catalysis Science & Technology

      Volume: 1 Pages: 1376-1382

    • Peer Reviewed
  • [Journal Article] Hemicellulose Decomposition and Saccharides Production from Various Plant Biomass by Sulfonated Allophane Catalyst2011

    • Author(s)
      Y. Ogaki, Y. Shinozuka, T. Hara, N. Ichikuni, and S. Shimazu
    • Journal Title

      Catal. Today

      Volume: 164 Pages: 415-418

    • Peer Reviewed
  • [Presentation] アルキルアンモニウム修飾粘土鉱物層間への不斉Rh(I)ピラー錯体の固定化と不斉水素化触媒作用2014

    • Author(s)
      鈴木海土, 原孝佳, 一國伸之, 島津省吾
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(名古屋)
    • Year and Date
      2014-03-28
  • [Presentation] Development of Intercalation Catalysts and Application for Various Organic Reactions2012

    • Author(s)
      S. Shimazu
    • Organizer
      インドネシア化学会国際会議(ICICS2012)
    • Place of Presentation
      Brawijaya University, Indonesia
    • Year and Date
      20120904-05
  • [Presentation] L-プロリン誘導体を用いた新規Rhピラー錯体による固体不斉触媒反応場の構築と不斉水素化反応への応用2011

    • Author(s)
      遠藤水彩, 原孝佳, 一國伸之, 島津省吾
    • Organizer
      日本化学会第5回関東支部大会
    • Place of Presentation
      東京農工大学
    • Year and Date
      2011-08-31
  • [Book] トコトンやさしいイオン交換の本,4章32無機イオン交換体触媒2013

    • Author(s)
      島津省吾
    • Publisher
      日刊工業新聞社
  • [Book] 触媒調製ハンドブック、1章Pd/粘土鉱物層間固定化触媒2011

    • Author(s)
      島津省吾
    • Total Pages
      32-33
    • Publisher
      NTS

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Published: 2015-07-16  

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