2013 Fiscal Year Final Research Report
Creation of and Application of Metal-Organic Nanotube Hybrid Catalysts for Low Environmental Impact Chemical Process
| Project/Area Number |
23560937
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | National Institute of Advanced Industrial Science and Technology |
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Principal Investigator |
AOYAGI Masaru 独立行政法人産業技術総合研究所, ナノシステム研究部門, 主任研究員 (50356333)
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| Project Period (FY) |
2011 – 2013
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| Keywords | 自己集合 / ナノチューブ / 配位錯体 / 金属イオン / 不均一系触媒 / 酸化反応 |
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| Research Abstract |
We demonstrated that metal coordinated organic nanotubes self-assembled from peptide lipids and transition metals catalyzed oxidation of organic compounds such as styrene by hydrogen peroxide as an oxidant. The catalytic activities depend on not only metal ions, but also combination with lipid molecules and dimension of the nanotubes. Reaction of transition metals and an organic nanotube self-assembled from sugar-oleic acid conjugated lipid gave metal nanoparticle-organic nanotube hybrids. The metal nanoparticles located in and/or on the wall of the organic nanotubes.
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