Development of solar cell using single-walled carbon nanotube with perfect carbon network

2012 Fiscal Year Final Research Report

• Project/Area Number: 23651082
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Environmental technology/Environmental materials
• Research Institution: Tohoku University
• Principal Investigator: TOHJI Kazuyuki 東北大学, 大学院・環境科学研究科, 教授 (10175474)
• Co-Investigator(Kenkyū-buntansha): TAKAHASHI Hideyuki 東北大学, 大学院・環境科学研究科, 准教授 (90312652) ; SATO Yoshinori 東北大学, 大学院・環境科学研究科, 准教授 (30374995)
• Project Period (FY): 2011 – 2012
• Keywords: グリーンケミストリー

Research Abstract

A high crystallinity single-walled carbon nanotube (SWCNT) film/Ag cell was fabricated. When the SWCNT/Ag interface of the cell was irradiated with a visible light (650 nm), photovoltaic electromotive force of 0.16mV occurred. After checking the current-voltage (I-V) characteristic of the cell at the time of the light irradiation, the slope of the curve showed the constant linear nature, and the interface of SWCNT/Ag was found to be ohmic junction. As a result of having measured the electromotive force outbreak properties for the on/off of light irradiation, the electromotive force showed relaxation time. We found that the photovoltaic electromotive force was derived from thermoelectromotive force by light absorption having changed for heat.

Research Products

• [Journal Article] Influence of the structure of the nanotube on mechanical properties of binder-free multi-walledcarbon nanotube solids (2012)
  • Author(s): Yoshinori Sato, Hikaru Nishizaka, ShunichiSawano, Atsushi Yoshinaka, KazutakaHirano, Shinji Hashiguchi, Takayuki Arie, Seiji Akita, Go Yamamoto, Toshiyuki Hashida, Hisamichi Kimura, Kenichi Motomiya, Kazuyuki Tohji
  • Journal Title: Carbon Volume: 50巻 Pages: 34-39
  • DOI: DOI:10.1016/j. carbon.2011.07.047
  • Peer Reviewed
• [Journal Article] Nitrogen physisorption and site blocking on single-walled carbon nanotubes (2012)
  • Author(s): S. -K. Lee, S. Iwata, S. Ogura, Y. Sato, K.Tohji, K. Fukutani
  • Journal Title: Surface Science Volume: 606巻 Pages: 293-296
  • DOI: DOI:10.1016/j.susc.2011.10.009
  • Peer Reviewed
• [Journal Article] Influence of carbon structure of the anode on the production of graphite in single-walled carbon nanotube soot synthesized by arc discharge using a Fe-Ni-S catalyst (2011)
  • Author(s): Hikaru Nishizaka, Masaru Namura, Kenichi Motomiya, Yasumasa Ogawa, Yasuo Udagawa, Kazuyuki Tohji, Yoshinori Sato
  • Journal Title: Carbon Volume: 49巻 Pages: 3607-3614
  • DOI: DOI:10.1016/j.carbon.2011.04.063
  • Peer Reviewed
• [Presentation] 単層カーボンナノチューブ膜の光熱起電力特性 (2013)
  • Author(s): 榊原甫、佐藤義倫、伊野浩介、伊藤暁彦、末永智一、後藤孝、本宮憲一、田路和幸
  • Organizer: 第44回フラーレン・ナノチューブ・グラフェン総合シンポジウム
  • URL: http://fullerene-jp.org/jp/sympo44/
  • Place of Presentation: 東京
  • Year and Date: 2013-03-13
• [Presentation] カーボンナノチューブ繊維を構成しているカーボンナノチューブ単体の引張強度 (2013)
  • Author(s): 鈴木英彰、佐藤義倫、山本剛、本宮憲一、橋田俊之、田路和幸
  • Organizer: 第44回フラーレン・ナノチューブ・グラフェン総合シンポジウム
  • URL: http://fullerene-jp.org/jp/sympo44/
  • Place of Presentation: 東京
  • Year and Date: 2013-03-12
• [Book] Technological advancement in the carbon nanotube (CNT) based polymer composites: Processing, performance and application (2013)
  • Author(s): Yoshinori Sato, Mei Zhang, Kazuyuki Tohji
  • Publisher: Springer