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2013 Fiscal Year Final Research Report

Direct observation of critical Casimir effect using capacitance measurements for thin polymer films

Research Project

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Project/Area Number 23654154
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Biophysics/Chemical physics
Research InstitutionRitsumeikan University

Principal Investigator

FUKAO Koji  立命館大学, 理工学部, 教授 (50189908)

Project Period (FY) 2011 – 2012
Keywords微小力測定 / 臨界カシミール効果 / 高分子ブレンド系 / α過程 / 界面相互作用
Research Abstract

The purpose of the present study was to elucidate the existence of Casimir force for thin films of polymer blends with a critical component. We made precise measurements of electric capacitance at 100kHz for thin films of poly(dimethyl siloxane)/poly(ethyl methyl siloxane) with 55 % wt fraction of PEMS. The electric capacitance decreases with increasing temperature above the glass transition temperature and then shows a plateau around the critical temperatures. This results suggest that there is an attractive interaction between two electrodes. The origin of the attractive force might be due to the Casimir forces, although the detailed measurements could not yet be done successfully. Secondly, we measured the dynamics of alpha-process of poly(2-chlorostyrene) thin films between two polystyrene thin films with various thicknesses using dielectric spectroscopy for annealing process. This experiment will be important for understanding of the microscopic mechanism of the Casimir effect.

  • Research Products

    (20 results)

All 2014 2013 2012 2011 Other

All Journal Article (12 results) (of which Peer Reviewed: 11 results) Presentation (4 results) (of which Invited: 3 results) Book (3 results) Remarks (1 results)

  • [Journal Article] Segmental and local dynamics of stacked thin films of poly(methyl methacrylate)2014

    • Author(s)
      T. Hayashi, K. Fukao
    • Journal Title

      Phys. Rev. E

      Volume: 89 Pages: 022602-1-10

    • DOI

      10.1103/PhysRevE.89.022602

    • Peer Reviewed
  • [Journal Article] Dielectric relaxation behavior of polymerized ionic liquids with various charge densities2013

    • Author(s)
      K. Nakamura, K. Fukao
    • Journal Title

      Polymer

      Volume: 54 Pages: 3306-3313

    • DOI

      10.1016/j.polymer.2013.04.039

    • Peer Reviewed
  • [Journal Article] Viscoelastic behavior of polymerized ionic liquids with various charge densities2013

    • Author(s)
      K. Nakamura, K. Fukao, T. Inoue
    • Journal Title

      Nihon Reoroji Gakkaishi

      Volume: 41 Pages: 21-27

    • DOI

      10.1678/rheology.41.21

    • Peer Reviewed
  • [Journal Article] Glass transition and aging dynamics in single and stacked thin polymer films2012

    • Author(s)
      K. Fukao, T. Terasawa, Y. Oda, K. Nakamura, D. Tahara
    • Journal Title

      J. Soc. Rheo. Jpn

      Volume: 40 Pages: 121-128

    • DOI

      10.1678/rheology.40.121

    • Peer Reviewed
  • [Journal Article] A Kinetic study on the response of the relaxation time of the αprocess to quick temperature change around the glass transition2012

    • Author(s)
      A. Harada, T. Oikawa, H. Yao, K. Fukao, Y. Saruyama
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 81 Pages: 065001-1-2

    • DOI

      10.1143/JPSJ.81.065001

    • Peer Reviewed
  • [Journal Article] Dielectric relaxation and visco- elastic behavior of polymerized ionic liquids with various counter anions2012

    • Author(s)
      K. Nakamura, K. Fukao, T. Inoue
    • Journal Title

      Macromolecules

      Volume: 45 Pages: 3850-3858

    • DOI

      10.1021/ma300040b

    • Peer Reviewed
  • [Journal Article] Glass transition dynamics of stacked thin polymer films2011

    • Author(s)
      K. Fukao, T. Terasawa, Y. Oda, K. Nakamura, D. Tahara
    • Journal Title

      Phys. Rev. E

      Volume: 84 Pages: 041808

    • DOI

      10.1103/PhysRevE.84.041808

    • Peer Reviewed
  • [Journal Article] Polymer crystallization mechanism through a meso-morphic state2011

    • Author(s)
      T. Konishi, W. Sakatsuji, K. Fukao, Y. Miyamoto
    • Journal Title

      Phys. Rev. B

      Volume: 84 Pages: 132102

    • DOI

      10.1103/PhysRevB.84.132102

    • Peer Reviewed
  • [Journal Article] Glass transition and thermal expansivity in silica-polystyrene nanocomposites2011

    • Author(s)
      M. Mizuno, K. Nakamura, T. Konishi, K. Fukao
    • Journal Title

      J. Non-Cryst. Solids

      Volume: 357 Pages: 594-597

    • DOI

      10.1016/j.jnoncrysol.2010.06.061

    • Peer Reviewed
  • [Journal Article] Viscoelastic behavior of the polymerized ionic liquid poly(1- ethyl-3-vinylimidazolium bis(tri- fluoromethanesulfonylimide))2011

    • Author(s)
      K. Nakamura, K. Fukao, T. Saiwaki, T. Inoue
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 7719-7726

    • DOI

      10.1021/ma201611q

    • Peer Reviewed
  • [Journal Article] Systematic dielectric relaxation study of solid- like polyelectrolyte surfactant complexes formed between poly(styrene sulfonate) and cationic surfactants2011

    • Author(s)
      K. Nakamura, K. Fukao
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 3053-3061

    • DOI

      10.1021/ma102808y

    • Peer Reviewed
  • [Journal Article] 誘電測定で見る高分子薄膜のガラス転移と非平衡緩和2011

    • Author(s)
      深尾 浩次
    • Journal Title

      高分子

      Volume: 60(4) Pages: 174-177

  • [Presentation] Glass transition and dynamics of multi-layered thin polymer films2013

    • Author(s)
      K. Fukao, H. Takaki, T. Hayashi
    • Organizer
      7th International Discussion Meeting on Relaxations in Complex Systems
    • Place of Presentation
      Barcelona, Spain
    • Year and Date
      2013-07-24
    • Invited
  • [Presentation] Heterogeneous and aging dynamics in single and stacked thin polymer films2012

    • Author(s)
      K. Fukao, H. Takaki, T. Terasawa, K. Nakamura, D. Tahara
    • Organizer
      7th International Conference on Broadband Dielectric Spectroscopy and its Applications
    • Place of Presentation
      Leipzig, Germany
    • Year and Date
      2012-09-06
    • Invited
  • [Presentation] Glass transition dynamics of stacked thin films of polymers2011

    • Author(s)
      K. Fukao, T. Terasawa, Y. Oda, K. Nakamura, D. Tahara
    • Organizer
      French-Japanese meeting on Jamming, Glasses and Phase transitions, Institut Henri Poincare
    • Place of Presentation
      Paris, France
    • Year and Date
      2011-12-07
    • Invited
  • [Presentation] Glass transition dynamics of stacked thin films of polymers2011

    • Author(s)
      K. Fukao, T. Terasawa, Y. Oda, K. Nakamura, D. Tahara
    • Organizer
      Discussion Meeting : Challenges in and Potential of Polymer Physics
    • Place of Presentation
      Schluchsee, Germany
    • Year and Date
      2011-05-05
  • [Book] Heterogeneous dynamics of multi- layered thin polymer films, Chap.9 of "Advances in Dielectrics"2014

    • Author(s)
      K. Fukao, H. Takaki, T. Hayashi
    • Publisher
      Springer(印刷中)
  • [Book] Heterogeneous and aging dynamics in single and stacked thin polymer films2013

    • Author(s)
      K. Fukao, T. Terasawa, Y. Oda, K. Nakamura, D. Tahara
    • Total Pages
      65-106
    • Publisher
      Adv. Polym. Sci.
  • [Book] 高分子の誘電インピーダンス測定の原理, 測定例と注意点, 電気化学/インピーダンス測定のノウハウと正しいデータ解釈2013

    • Author(s)
      深尾 浩次
    • Total Pages
      508-511
    • Publisher
      技術情報協会
  • [Remarks] 研究代表者のホームページ

    • URL

      http://www.softmat.se.ritsumei.ac.jp

URL: 

Published: 2015-06-25  

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