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2012 Fiscal Year Final Research Report

Studies on synthesis and evaluation of physical properties of novel carbon materials fabricated by plasma reaction in super critical fluid

Research Project

  • PDF
Project/Area Number 23654202
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Plasma science
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

WATANABE Toshiyuki  東京農工大学, 大学院工学研究院, 教授 (10210923)

Co-Investigator(Kenkyū-buntansha) TOTANI Kenro  東京農工大学, 大学院工学府, 技術職員 (50397014)
Project Period (FY) 2011 – 2012
Keywordsダイヤモンド / カーボンチューブ / 超臨界流体
Research Abstract

Reaction vessel that can generate plasma discharge in super critical fluid was fabricated. Carbon nanotubes were obtained on graphite electrode by use of plasma discharge in super critical fluid of nitrogen. Maximum loading ratio of nitrogen found to be 9.1 at %. Obtained chemical structure of carbon depends on pressure of super critical fluid. Content of quaternary position of nitrogen reached their maximum values at 6.5 Mpa. TEM observation reveals that nano tubes have many nodes like a bamboo.

  • Research Products

    (7 results)

All 2014 2013 2012 2011 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (3 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Material transformation from carbon dioxide to nano-diamond and metal oxides by chemical supercritical fluid deposition2014

    • Author(s)
      Y. Suga, M. Sone, T. Watanabe
    • Journal Title

      J. Nanosci. Nanotech

      Volume: 14巻 (in press)

    • Peer Reviewed
  • [Journal Article] Thermoresponsive Persistent Phosphorescence Color Change using Efficient Thermally Activated Reverse Energy Transfer with a Large Energy Difference2013

    • Author(s)
      K. Totani, Y. Okada, S. Hirata, M. Vacha, T. Watanabe
    • Journal Title

      Adv. Opt. Mater

      Volume: 1巻 Pages: 283-288

    • DOI

      10.1002/adom.201300013

    • Peer Reviewed
  • [Presentation] 窒素導入バンブーライクナノチューブの合成2013

    • Author(s)
      村上光一、高橋裕、渡辺敏行
    • Organizer
      ナノ学会第11回大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2013-06-08
  • [Presentation] 有機溶媒に分散するナノカーボン材料の合成2012

    • Author(s)
      高橋裕、渡辺敏行
    • Organizer
      ナノ学会第10回大会
    • Place of Presentation
      大阪大学会館
    • Year and Date
      2012-06-12
  • [Presentation] Reversible on-off recording of long-lived room temperature phosphorescence2011

    • Author(s)
      K.Totani, C. Adachi, S. Hirata, H. Kaji, S. R. Marder, T. Watanabe, J. Zhang
    • Organizer
      ICONO12/ICOPE2011
    • Place of Presentation
      Trinity College, Dublin, Ireland
    • Year and Date
      2011-09-07
  • [Book] 「高分子と光が織りなす新機能新物性」分担執筆第10章「感熱型蛍光記録材料」2012

    • Author(s)
      渡辺敏行、平田修造
    • Total Pages
      120-122
    • Publisher
      化学同人
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~watanabe

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Published: 2015-06-25   Modified: 2015-10-05  

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