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2012 Fiscal Year Final Research Report

Synthesis and functionalization of discrete porphyrin tube

Research Project

  • PDF
Project/Area Number 23655034
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic chemistry
Research InstitutionKyoto University

Principal Investigator

OSUKA Atsuhiro  京都大学, 大学院・理学研究科, 教授 (80127886)

Project Period (FY) 2011 – 2012
Keywordsポルフィリン / 二光子吸収 / クロスカップリング
Research Abstract

We’ve achieved the synthesis of pyridine-bridgedβ,β-doubly linked porphyrin cyclic tetramer by means of Suzuki-coupling that can encapsulate C60. We’ve developed an efficient method to synthesize 3mer and studied a variety of metal complexes.

  • Research Products

    (18 results)

All 2012 2011 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (5 results) Remarks (1 results)

  • [Journal Article] Preferential Formation of Cyclic Trimers by Palladium-Catalyzed Oxidative Coupling Reactions of 2,18-Diethynylporphyrins2012

    • Author(s)
      Tokuji, S. ; Yorimitsu, H. ; Osuka, A., Angew
    • Journal Title

      Chem. Int. Ed

      Volume: 51 Pages: 12357-12361

    • DOI

      DOI:10.1002/anie.201207763

    • Peer Reviewed
  • [Journal Article] Hexaphyrin Fused to Two Anthracenes2012

    • Author(s)
      Naoda, K. ; Mori, H. ; Aratani, N. ; Lee, B. S. ; Kim, D. Osuka, A.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51 Pages: 9856-9859

    • DOI

      DOI:10.1002/anie.201204446

    • Peer Reviewed
  • [Journal Article] A meso-Spiro[Cyclopentadiene-Isoporphyrin] from a Phenylethynyl Porphyrin Platinum(II) Pincer Complex2012

    • Author(s)
      Anabuki, S.; Shinokubo, H.; Aratani, N.: Osuka, A
    • Journal Title

      Angew. Chem.

      Volume: 51 Pages: 3174-3177

    • DOI

      DOI:10.1002/ange.19380510103

    • Peer Reviewed
  • [Journal Article] Direct meso-Alkynylation of Porphyrins Doubly Assisted by Pyridyl Coordination2012

    • Author(s)
      Anabuki, S.; Tokuji, S.; Aratani, N.; Osuka. A
    • Journal Title

      Org. Lett.

      Volume: 14 Pages: 2778-2781

    • DOI

      DOI:10.1021/ol301005b

    • Peer Reviewed
  • [Journal Article] Directly Linked Corrole Oligomers via Facile Oxidative 3-3' Coupling Reaction2012

    • Author(s)
      Hirabayashi, S.; Omote, M.; Aratani, N.; Osuka, A.
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 85 Pages: 558-562

    • Peer Reviewed
  • [Journal Article] A Hexameric Porphyrin Triangle Constructed by Suzuki-Miyaura Cross-coupling Reaction2011

    • Author(s)
      Song, J.; Anabuki, S.; Aratani, N.; Shinokubo, H.; Osuka, A
    • Journal Title

      Chem. Lett.

      Volume: 40 Pages: 902-902

    • URL

      http://dx.doi.org/10.1246/cl.2011.902

    • Peer Reviewed
  • [Journal Article] Song, J.; Aratani, N.; Shinokubo, H.; Osuka, A.2011

    • Author(s)
      A β-to-β 2,5-Thienylene-bridged Cyclic Porphyrin Tetramer: Its Rational Synthesis and Binding of C60
    • Journal Title

      Chem. Sci.

      Volume: 2 Pages: 748-751

    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Hybrid Porphyrin Tapes2011

    • Author(s)
      Tanaka, T.; Lee, B S.; Aratani, N.; Yoon, M-C.; Kim, D.; Osuka, A
    • Journal Title

      Chem. Eur. J

      Volume: 17 Pages: 14400-14412

    • DOI

      DOI:10.1039/C0SC00605J

    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed β-Selective Direct Arylation of Porphyrins2011

    • Author(s)
      Kawamata, Y.; Tokuji, S.; Yorimitsu, H.; Osuka, A
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 50 Pages: 8867-8870

    • DOI

      DOI:10.1002/anie.201102318

    • Peer Reviewed
  • [Journal Article] Planar Subporphyrin Borenium Cations2011

    • Author(s)
      Tsurumaki, E.; Hayashi, S.; Tham, F.S.; Reed, C.A.; Osuka, A
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 133 Pages: 11956-11959

    • DOI

      DOI:10.1246/bcsj.20110373

    • Peer Reviewed
  • [Journal Article] Rearrangements of a [36]Octaphyrin Triggered by Nickel(II) Metalation: Metamorphosis to a Directly meso-β-Linked Diporphyrin2011

    • Author(s)
      Tanaka, Y.; Mori, H.; Koide, T.; Yorimitsu, H.; Aratani, N.; Osuka, A
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 50 Pages: 11460-11464

    • DOI

      DOI:10.1002/anie.201105809

    • Peer Reviewed
  • [Journal Article] New Synthetic Strategy for Diporphyrins: Pinacol Coupling-Rearrangement2011

    • Author(s)
      Tokuji, S.; Maeda, C.; Yorimitsu, H.; Osuka, A.
    • Journal Title

      Chem. Eur. J.

      Volume: 17 Pages: 7154-7157

    • DOI

      DOI:10.1002/chem.201100872

    • Peer Reviewed
  • [Presentation] 縮環ヘキサフィリンの合成と光物性2012

    • Author(s)
      荒谷直樹・直田耕治・田中隆行・森裕貴・Dongho Kim・大須賀篤弘
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      20120912-14
  • [Presentation] Catalytic Selective Direct Arylation of Porphyrin Periphery2012

    • Author(s)
      Hideki Yorimitsu, Atsuhiro Osuka
    • Organizer
      7th International Conference on Porphyrins and Phthalocyanines
    • Place of Presentation
      韓国 済州島
    • Year and Date
      20120701-06
  • [Presentation] パラジウム架橋ポルフィリン多量体の合成と光物性2011

    • Author(s)
      荒谷直樹・宋建新・穴吹翔馬・忍久保洋・大須賀篤弘
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎大学
    • Year and Date
      20110906-08
  • [Presentation] Novel Fullerene Receptors based on Multi-Porphyrin Arrays2011

    • Author(s)
      Naoki Aratani, Jianxin Song, Hiroshi Shinokubo, Atsuhiro Osuka
    • Organizer
      The first symposium on "Carbon Nanoforms"
    • Place of Presentation
      Toledo, Spain
    • Year and Date
      20110602-03
  • [Presentation] Construction of Multi-porphyrin Arrays via Pd-catalyzed Coupling Reactions2011

    • Author(s)
      Naoki Aratani, Jianxin Song, Hiroshi Shinokubo, Atsuhiro Osuka
    • Organizer
      219th ECS meeting
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      20110501-06
  • [Remarks]

    • URL

      http://kuchem.kyoto-u.ac.jp/shuyu

URL: 

Published: 2014-09-25  

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