Studies on Cationic Metalloporphyrin Catalyzed Reaction

2012 Fiscal Year Final Research Report

• Project/Area Number: 23655035
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Organic chemistry
• Research Institution: Kyoto University
• Principal Investigator: KURAHASHI Takuya 京都大学, 大学院・工学研究科, 准教授 (50432365)
• Project Period (FY): 2011 – 2012
• Keywords: ポルフィリン / 遷移金属 / 触媒反応

Research Abstract

The transition metal catalyzed reaction is a useful transformation to prepare complicated compounds in a single step. Ｗe developed unprecedented type of transition metal catalyzed reaction by means of cationic metalloporpyrin complexes.

Research Products

• [Journal Article] Cationic Iron(III) Porphyrin Catalyzed [4+2] Cycloaddition of Unactivated Aldehydes with Simple Dienes (2012)
  • Author(s): 藤原恭平、倉橋拓也、松原誠二郎
  • Journal Title: J. Am. Chem. Soc Volume: 134 Pages: 5512-5514
  • DOI: DOI: 10.1021/ja300790x
• [Journal Article] Cobalt(III) Porphyrin Catalyzed Aza-Diels-Alder Reaction (2012)
  • Author(s): 若林亮太、倉橋拓也、松原誠二郎
  • Journal Title: Org. Lett. Volume: 14 Pages: 4794-4797
  • DOI: DOI: 10.1021/ol3020946
• [Journal Article] Manganese Porphyrin Catalyzed Cycloisomerization of Enynes (2012)
  • Author(s): 小澤卓也、倉橋拓也、松原誠二郎
  • Journal Title: Org. Lett. Volume: 14 Pages: 3008-3011
  • DOI: DOI:10.1021/ol301416f
• [Journal Article] Ruthenium Porphyrin Catalyzed Friedel-Crafts Type Reaction of Arenes with Imines (2012)
  • Author(s): 寺田拓真、倉橋拓也、松原誠二郎
  • Journal Title: Heterocycles Volume: 85 Pages: 2415-2419
  • DOI: DOI:10.3987/COM-12-12556
• [Journal Article] Dehydrogenative Diels!Alder Reaction (2011)
  • Author(s): 小澤卓也、倉橋拓也、松原誠二郎
  • Journal Title: Org. Lett. Volume: 13 Pages: 5390-5393
  • DOI: DOI:10.1021/ol202283d
• [Journal Article] Nickel-Catalyzed Cycloaddition of o-Arylcarboxybenzonitriles and Alkynes via Cleavage of Two Carbon-Carbon σBonds (2011)
  • Author(s): 中井健一朗、倉橋拓也、松原誠二郎
  • Journal Title: J. Am. Chem. Soc. Volume: 133 Pages: 11066-11068
  • DOI: DOI: 10.1021/ja203829j
• [Presentation] Phosphine-Mediated Cycloaddition of Thiophtalic Anhydrides with Polyynes (2013)
  • Author(s): 井波輔、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学びわこ・くさつキャンパス
  • Year and Date: 2013-03-22
• [Presentation] Iron-Porphinoid-Catalyzed Hetero Diels-Alder Reaction by Dienes and Aldehydes (2013)
  • Author(s): 桑野徹、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学びわこ・くさつキャンパス
  • Year and Date: 2013-03-22
• [Presentation] Iron-Porphyrin-Catalyzed [3+2] Cycloaddition Reaction by Aziridines and Carbonyl Compounds (2013)
  • Author(s): 寺西覚、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学びわこ・くさつキャンパス
  • Year and Date: 2013-03-22
• [Presentation] Diels-Alder Reaction Catalyzed byCationic Ruthenium Porphyrin Complex (2013)
  • Author(s): 寺田拓真、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学びわこ・くさつキャンパス
  • Year and Date: 2013-03-22
• [Presentation] Palladium Porphyrin Catalyzed Hydrogenation (2013)
  • Author(s): 西林亮、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学びわこ・くさつキャンパス
  • Year and Date: 2013-03-22
• [Presentation] Nickel-Catalyzed Cycloaddition via Elimination of Carbon Monoxide and Carbon Dioxide (2013)
  • Author(s): 中井健一朗、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学びわこ・くさつキャンパス
  • Year and Date: 2013-03-22
• [Presentation] Platinum Porphyrin Catalyzed Cycloisomerization of Enynes (2013)
  • Author(s): 長谷川誠、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学びわこ・くさつキャンパス
  • Year and Date: 2013-03-22
• [Presentation] Nickel-Catalyzed Cycloaddition via Elimination of Small Molecule (2012)
  • Author(s): 倉橋拓也、松原誠二郎
  • Organizer: ICCCS-3
  • Place of Presentation: 中華人民共和国杭州大学
  • Year and Date: 2012-11-01
• [Presentation] Synthesis of Ruthenium Porphyrin Complexes and their Application in Organic Synthesis (2012)
  • Author(s): 寺田拓真、倉橋拓也、松原誠二郎
  • Organizer: 第23回基礎有機化学討論会
  • Place of Presentation: 京都テルサ
  • Year and Date: 2012-09-19
• [Presentation] Synthesis of Iron Porphyrin Complexes and their Application in Organic Synthesis (2012)
  • Author(s): 寺西覚、倉橋拓也、松原誠二郎
  • Organizer: 第23回基礎有機化学討論会
  • Place of Presentation: 京都テルサ
  • Year and Date: 2012-09-19
• [Presentation] Cationic Metalloporphyrin-Catalyzed [4+2] Cycloaddition (2012)
  • Author(s): 倉橋拓也、藤原恭平、松原誠二郎
  • Organizer: 第59回有機金属化学討論会
  • Place of Presentation: 大阪大学吹田キャンパス
  • Year and Date: 2012-09-14
• [Presentation] Nickel-catalyzed Cycloaddition via Elimination of Nitrile (2012)
  • Author(s): 中井健一朗、倉橋拓也、松原誠二郎
  • Organizer: 第59回有機金属化学討論会
  • Place of Presentation: 大阪大学吹田キャンパス
  • Year and Date: 2012-09-14
• [Presentation] Nickel-catalyzed Decarbonylative Cycloaddition with Thioisatins: Acceleration of Decarbonylation by Sulfur Coordination (2012)
  • Author(s): 井波輔、倉橋拓也、松原誠二郎
  • Organizer: 第59回有機金属化学討論会
  • Place of Presentation: 大阪大学吹田キャンパス
  • Year and Date: 2012-09-14
• [Presentation] Nickel-Catalyzed Decarbonylative Cycloaddition of Thioisatins to Alkynes (2012)
  • Author(s): 井波輔、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶應義塾大学日吉キャンパス
  • Year and Date: 2012-03-25
• [Presentation] Nickel-Catalyzed Coupling Reaction of Aldehydes and Alkynes (2012)
  • Author(s): 吉田有次、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶應義塾大学日吉キャンパス
  • Year and Date: 2012-03-25
• [Presentation] Iron-Porphyrin-Catalyzed Friedel-Crafts Reaction with Dehydration by Alcohols and Arenes (2012)
  • Author(s): 寺西覚、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶應義塾大学日吉キャンパス
  • Year and Date: 2012-03-25
• [Presentation] Synthesis of Ruthenium Porphyrin Complexes and their Application (2012)
  • Author(s): 寺田拓真、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶應義塾大学日吉キャンパス
  • Year and Date: 2012-03-25
• [Presentation] Nickel-catalyzed Decarbonylative Cycloaddition of Phthalimides with Alkynes via gem- Carboamination (2012)
  • Author(s): 芝隆宏、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶應義塾大学日吉キャンパス
  • Year and Date: 2012-03-25
• [Presentation] Nickel-catalyzed Decarbonylative Polymerizations of Alkynyl Phthalimide and Phthalic Anhydride (2012)
  • Author(s): 竹内真、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶應義塾大学日吉キャンパス
  • Year and Date: 2012-03-25
• [Presentation] Nickel-Catalyzed Cycloaddition via Elimination of Nitrile (2012)
  • Author(s): 中井健一朗、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶應義塾大学日吉キャンパス
  • Year and Date: 2012-03-25
• [Presentation] Nickel-Catalyzed [3+2] Cycloaddition of Vinylcyclopropanes and Allenes (2012)
  • Author(s): 頓部李歩子、倉橋拓也、松原誠二郎
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶應義塾大学日吉キャンパス
  • Year and Date: 2012-03-25
• [Presentation] Creation of Reactive Intermediates from Low-valent Nickel Complexes and Carbonyl Compounds: Their Application for Catalytic Organic Synthesis (2012)
  • Author(s): 倉橋拓也
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶應義塾大学日吉キャンパス
  • Year and Date: 2012-03-25
• [Presentation] Nickel-Catalyzed Cycloaddition of α,β,γ,δ-Unsaturated Ketones with Alkynes (2011)
  • Author(s): 堀江宏彰、倉橋拓也、松原誠二郎
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋大学東山キャンパス
  • Year and Date: 2011-09-07
• [Presentation] Nickel-Catalyzed Cycloaddition of Thiophthalic Anhydrides with Methylenecyclopropanes to Form Thiophthalides; New Use for Methylenecyclopropane as C1 Synthetic Units (2011)
  • Author(s): 井波輔、倉橋拓也、松原誠二郎
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋大学東山キャンパス
  • Year and Date: 2011-09-07
• [Presentation] Nicke-Catalyzed Cycloaddition via Cleavage of Two Carbon-Carbon s Bonds (2011)
  • Author(s): 中井健一朗、倉橋拓也、松原誠二郎
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋大学東山キャンパス
  • Year and Date: 2011-09-07
• [Book] [4+2] Cycloaddition via Metallacycles (2012)
  • Author(s): 倉橋拓也、松原誠二郎
  • Publisher: Transition-Metal-Mediated Aromatic Ring Construction, Wiley(in press)