2013 Fiscal Year Final Research Report
Synthetic application of acid activated diazonium carbon species
| Project/Area Number |
23655036
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
HASHIMOTO Takuya 京都大学, 理学(系)研究科(研究院), 助教 (20437198)
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| Project Period (FY) |
2011 – 2013
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| Keywords | ジアゾカルボニル化合物 / 酸触媒 / 不斉合成 |
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| Research Abstract |
One main focus of organic chemistry is to develop a catalysis with which a complex molecule can be synthesized starting from simple substrates. In this regard, use of transition metal such as palladium, rhodium and copper has been widely studied. This is also true for the reactions using diazo carbonyl compounds as substrate. In this research project, use of environmentally benign, non-metallic Bronsted acid was chosen as a catalyst for the activation of diazocarbonyl compounds and successfully developed a couple of useful transformations.
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