2012 Fiscal Year Final Research Report
Development of hydrophosphination of unsaturated hydrocarbons catalyzed by iron complex
| Project/Area Number |
23655056
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka City University |
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Principal Investigator |
NAKAZAWA Hiroshi 大阪市立大学, 大学院・理学研究科, 教授 (00172297)
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| Co-Investigator(Kenkyū-buntansha) |
ITAZAKI Masumi 大阪市立大学, 大学院・理学研究科, 講師 (60382032)
KAMEO Hajime 大阪市立大学, 大学院・理学研究科, 特任講師 (50597218)
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| Project Period (FY) |
2011 – 2012
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| Keywords | ヒドロリン化反応 / 触媒反応 / 鉄錯体 |
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| Research Abstract |
The first catalytic double hydrophosphination of alkynes was achieved by reaction with diarylphosphines in the presence of an iron catalyst. The double hydrophosphination proceeded regioselectively and effectively for various secondary aryl pho
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