2012 Fiscal Year Final Research Report
Development of Chiral Tetraaminophosphonium Peroxyacids for Asymmetric Catalyses
| Project/Area Number |
23655080
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2012
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| Keywords | 有機分子触媒 / 酸化反応 / 不斉合成 |
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| Research Abstract |
Novel chiral salts which are constructed from P-spiro chiral aminophosphonium ion and peroxoacid ions were achieved. It was revealed that the salts can be used for oxidation reactions. In addition, we found the ability of chiral iminophosphorane for activating hydrogen peroxide and applied this fact to develop asymmetric oxidation of N-sulfonyl imines.
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Research Products
(5 results)
