2012 Fiscal Year Final Research Report
Development of Novel Synthetic Methods of Soluble Graphene Derivatives Having Transistor Performance
| Project/Area Number |
23655090
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Synthetic chemistry
|
|---|
| Research Institution | Keio University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Keywords | C-H活性化 / 有機トランジスタ / アリール化 / グラフェン類 / オリゴアセン類アリールボロン酸エステル / 芳香族ケトン / 遷移金属錯体触媒 |
|---|
| Research Abstract |
We have studied development of short syntheses of polycyclic aromatic hydrocarbons using coupling of aromatic ketones and arylboronates via carbon-hydrogen, carbon-oxygen, and carbon-nitrogen bond cleavages and have examined applications of these polycycl
1) development of multi-arylation of acetophenones via unreactive carbon bond cleavage and construction of benzene ring by transformation of acetyl groups;
2) development of new methods of short synthesis of polycyclic aromatic hydrocarbons having graphene frameworks by our multi-arylation protocols;
3) measurements of OFET performance of the synthesized polycyclic aromatic hydrocarbons.
|
