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2013 Fiscal Year Final Research Report

Development of self-healing supramolecular functional polymer

Research Project

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Project/Area Number 23655105
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionHiroshima University

Principal Investigator

HAINO Takeharu  広島大学, 理学(系)研究科(研究院), 教授 (80253053)

Project Period (FY) 2011 – 2013
Keywords非共有結合高分子 / 超分子ポリマー / 分子認識 / フラーレン / ポルフィリン
Research Abstract

In this research work, we have developed extended polymer networks based on non-covalent interactions. Fullerene-calix[5]arene and bisporphyrin-trinitrofluorenone complexes are good supramolecular motifs for constructing supramolecular polymers. Utilizing these supramolecular interactions produced supramolecular fullerene polymers and supramolecular porphyrin polymers.

  • Research Products

    (55 results)

All 2014 2013 2012 2011 Other

All Journal Article (25 results) (of which Peer Reviewed: 22 results) Presentation (27 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] White-Light-Emitting Edge-Functionalized Graphene Quantum Dots2014

    • Author(s)
      R. Sekiya, Y. Uemura, H. Murakami, T. Haino
    • Journal Title

      Angewandte Chemie International Edition

      Volume: Vol. 53 Pages: 5619-5623

    • Peer Reviewed
  • [Journal Article] Self-assembly of Oligo(phenylisoxazolyl)benzenes Induced by Multiple Dipole-Dipole Interactions2014

    • Author(s)
      T. Haino, Y. Ueda, T. Hirao, T. Ikeda, M. Tanaka
    • Journal Title

      Chemistry Letters

      Volume: Vol. 43 Pages: 414-416

    • Peer Reviewed
  • [Journal Article] Synthesis of Optically Active Poly(m-phenyleneethynylene-aryleneethynylen e)s Bearing Hydroxy Groups and Examination of the Higher Order Structures2013

    • Author(s)
      H. Sogawa, M. Shiotsuki, T. Hirao, T. Haino, F. Sanda
    • Journal Title

      Macromolecules

      Volume: Vol. 46 Pages: 8161-8170

    • Peer Reviewed
  • [Journal Article] Head-to-tail polymeric columnar structure of calix[4]arene possessing catechol arms in the solid state2013

    • Author(s)
      R. Sekiya, Y. Yamasaki, S. Katayama, H. Shio, T. Haino
    • Journal Title

      CrystEngComm

      Volume: Vol. 15 Pages: 8404-8407

    • Peer Reviewed
  • [Journal Article] Size- and Orientation-Selective Encapsulation of C70 by Cycloparaphenylenes2013

    • Author(s)
      T. Iwamoto, Y. Watanabe, H. Takaya, T. Haino, N. Yasuda, S. Yamago
    • Journal Title

      Chemistry - A European Journal

      Volume: Vol. 19 Pages: 14061-14068

    • Peer Reviewed
  • [Journal Article] Selective Synthesis of [2]- and [3]Catenane Tuned by Ring Size and Concentration2013

    • Author(s)
      H. Iwamoto, W. Takizawa, K. Itoh, T. Hagiwara, E. Tayama, E. Hasegawa, T. Haino
    • Journal Title

      The Journal of Organic Chemistry

      Volume: Vol. 78 Pages: 5205-5217

    • Peer Reviewed
  • [Journal Article] Photoresponsive Two-Component Organogelators based on Trisphenylisoxazolylbenzene2013

    • Author(s)
      T. Haino, Y. Hirai, T. Ikeda, H. Saito
    • Journal Title

      Organic & Biomolecular Chemistry

      Volume: Vol. 11 Pages: 4164-4170

    • Peer Reviewed
  • [Journal Article] Supramolecular Polymerization of Rim-to-Rim Connected Bisresorcinarene2013

    • Author(s)
      T. Haino
    • Journal Title

      高分子 Hot Topics

      Volume: Vol. 62 Pages: 661

    • Peer Reviewed
  • [Journal Article] Supramolecular Chemistry : From Host-guest Complexes to Supramolecular Polymers2013

    • Author(s)
      T. Haino
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan

      Volume: Vol. 71 Pages: 1172-1181

    • Peer Reviewed
  • [Journal Article] 超分子化学を用いる分子配列構造の制御2013

    • Author(s)
      T. Haino
    • Journal Title

      Organo Metallic NEWS

      Pages: 54-60

    • Peer Reviewed
  • [Journal Article] Molecular-recognition-directed formation of supramolecular polymers2013

    • Author(s)
      T. Haino
    • Journal Title

      Polymer Journal

      Volume: Vol. 45 Pages: 363-383

    • Peer Reviewed
  • [Journal Article] スライドするグラフト共重合体-超分子ポリマーの新展開2012

    • Author(s)
      池田俊明, 灰野岳晴
    • Journal Title

      化学

      Volume: Vol. 67 Pages: 64-65

    • Peer Reviewed
  • [Journal Article] Modified Synthesis and Supramolecular Polymerization of Rim-to-Rim Connected Bisresorcinarenes2012

    • Author(s)
      H. Yamada, T. Ikeda, T. Mizuta, T. Haino
    • Journal Title

      Organic Letters

      Volume: Vol. 14 Pages: 4510-4513

    • Peer Reviewed
  • [Journal Article] Structures of (3n-Crown-n)-Phenol (n=4, 5, 6, 8) Host-Guest Complexes : Formation of a Uniquely Stable Complex for n=6 via Collective Intermolecular Interaction2012

    • Author(s)
      R. Kusaka, Y. Inokuchi, T. Haino, T. Ebata
    • Journal Title

      Journal of Physical Chemistry Letters

      Volume: Vol. 3 Pages: 1414-1420

    • Peer Reviewed
  • [Journal Article] Ion Selectivity of Crown Ethers Investigated by UV and IR Spectroscopy in a Cold Ion Trap2012

    • Author(s)
      Y. Inokuchi, O. V. Boyarkin, R. Kusaka, T. Haino, T. Ebata, T. R. Rizzo
    • Journal Title

      Journal of Physical Chemistry A

      Volume: Vol. 116 Pages: 4057-4068

    • Peer Reviewed
  • [Journal Article] Circular dichroism and circularly polarized luminescence triggered by self-assembly of tris(phenylisoxazolyl) benzenes possessing a perylenebisimide moiety2012

    • Author(s)
      T. Ikeda, T. Masuda, T. Hirao, J. Yuasa, H. Tsumatori, T. Kawai, T. Haino
    • Journal Title

      Chemical Communications

      Volume: Vol. 48 Pages: 6025-6027

  • [Journal Article] Supramolecular Polymerization Triggered by Molecular Recognition between Bisporphyrin and Trinitrofluorenone2012

    • Author(s)
      T. Haino, A. Watanabe, T. Hirao, T. Ikeda
    • Journal Title

      Angewandte Chemie International Edition

      Volume: Vol. 51 Pages: 1473-1476

    • Peer Reviewed
  • [Journal Article] Molecular Recognition of Hydrocarbon Guests by a Supramolecular Capsule Formed by the 4 : 4 Self-Assembly of Tris(Zn2+-Cyclen) and Trithiocyanurate in Aqueous Solution2012

    • Author(s)
      S. Aoki, S. Suzuki, M. Kitamura, T. Haino, M. Shiro, M. Zulkefeli, E. Kimura
    • Journal Title

      Chemistry-an Asian Journal

      Volume: Vol. 7 Pages: 944-956

    • Peer Reviewed
  • [Journal Article] 分子認識により重合する超分子ポリマーの新展開2011

    • Author(s)
      灰野岳晴
    • Journal Title

      高分子

      Volume: Vol. 60 Pages: 437-440

    • Peer Reviewed
  • [Journal Article] Self-Assembly and Gelation Behavior of Tris(phenylisoxazolyl)benzenes2011

    • Author(s)
      M. Tanaka, T. Ikeda, J. Mack, N. Kobayashi, T. Haino
    • Journal Title

      The Journal of Organic Chemistry

      Volume: Vol. 76 Pages: 5082-5091

    • Peer Reviewed
  • [Journal Article] Structure of host-guest complexes between dibenzo-18-crown-6 and water, ammonia, methanol, and acetylene : Evidence of molecular recognition on the complexation2011

    • Author(s)
      R. Kusaka, S. Kokubu, Y. Inokuchi, T. Haino, T. Ebata
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: Vol. 13 Pages: 6827-6836

    • Peer Reviewed
  • [Journal Article] Size-Selective Encapsulation of C60 by [10]Cycloparaphenylene : Formation of the Shortest Fullerene-Peapod2011

    • Author(s)
      T. Iwamoto, Y. Watanabe, T. Sadahiro, T. Haino, S. Yamago
    • Journal Title

      Angewandte Chemie International Edition

      Volume: Vol. 50 Pages: 8342-8344

    • Peer Reviewed
  • [Journal Article] Highly shape-selective guest encapsulation in the precisely defined cavity of a calix[4]arene-capped metalloporphyrin2011

    • Author(s)
      H. Iwamoto, S. Nishi, T. Haino
    • Journal Title

      Chemical Communications

      Volume: Vol. 47 Pages: 12670-12672

  • [Journal Article] UV and IR Spectroscopic Studies of Cold Alkali Metal Ion-Crown Ether Complexes in the Gas Phase2011

    • Author(s)
      Y. Inokuchi, O. V. Boyarkin, R. Kusaka, T. Haino, T. Ebata, T. R. Rizzo
    • Journal Title

      Journal of the American Chemical Society

      Volume: Vol. 133 Pages: 12256-12263

    • Peer Reviewed
  • [Journal Article] Electrochemically switchable supramolecular complex between bisporphyrin cleft and electron-deficient aromatic guest2011

    • Author(s)
      T. Ikeda, A. Watanabe, T. Oshita, T. Haino
    • Journal Title

      Heteroatom Chemistry

      Volume: Vol. 22 Pages: 590-593

  • [Presentation] Helical self-assembly of platinum(II) complexes possessing phenylisoxazolylbenzene units2013

    • Author(s)
      Takayama, M., T. Ikeda T. Haino
    • Organizer
      The 10th Nano Bio Info Chemistry Symposium
    • Place of Presentation
      Hiroshima
    • Year and Date
      20131214-15
  • [Presentation] Synthesis of Supramolecular Graft Copolymer via Specific Guest Encapsulation by Coordination Capsule2013

    • Author(s)
      Tsunoda, Y., R. Sekiya T. Haino
    • Organizer
      The 10th Nano Bio Info Chemistry Symposium
    • Place of Presentation
      Hiroshima
    • Year and Date
      20131214-15
  • [Presentation] Supramolecular Polymerization via Self-assembly of Functional Molecules2013

    • Author(s)
      T. Haino
    • Organizer
      3rd Annual World Congress of Nano Science & Technology 2013
    • Place of Presentation
      Xi'an, China
    • Year and Date
      20130926-28
  • [Presentation] 光機能性部位を導入したとリス(フェニルイソオキサゾリル)ベンゼンのらせん集積とキロプティカル特性2013

    • Author(s)
      灰野岳晴, 増田哲也, 高山みどり, 平尾岳大池田俊明
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢
    • Year and Date
      20130911-13
  • [Presentation] Supramolecular Polumer Formed by Molecular Association of Calix[5]arene-Based Homoditopic Host and Dumbbell-Fullerene2013

    • Author(s)
      Hirao, T., K. Sakamoto, Y. Matsumoto, T. Ikeda T. Haino
    • Organizer
      15th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Taipei
    • Year and Date
      20130728-0802
  • [Presentation] Molecular Recognition-Directed Supramolecular Polymerization of Functional Molecules2013

    • Author(s)
      T. Haino
    • Organizer
      Collaborative Conference on 3D & Materials Research (CC3DMR) 2013
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      20130624-28
  • [Presentation] Circularly Polarized Luminescent Helical Self-assemblies of Tris(phenylisoxazolyl)benzenes2013

    • Author(s)
      T. Ikeda, T. Masuda, M. Takayama, T. Haino
    • Organizer
      第62高分子学会年次大会
    • Place of Presentation
      京都
    • Year and Date
      20130529-31
  • [Presentation] Supramolecular Porphyrin Polymerization Through Charge-Transfer Host-Guest Interaction2013

    • Author(s)
      T. Haino
    • Organizer
      223rd ECS Meeting
    • Place of Presentation
      Toronto, ON, Canada
    • Year and Date
      20130512-16
  • [Presentation] Supramolecular Fullerene Polymers Formed by Host-Guest Complexation between Calix[5]arene and C602013

    • Author(s)
      T. Haino
    • Organizer
      223rd ECS Meeting
    • Place of Presentation
      Toronto, ON, Canada
    • Year and Date
      20130512-16
  • [Presentation] Helical self-assembly of platinum(II) complexes possessing bis(phenylisoxazolyl)benzenes2012

    • Author(s)
      M. Takayama, T. Ikeda, T. Haino
    • Organizer
      The 9th Nano Bio Info Chemistry Symposium and The 6th Japanese-Russian Seminar
    • Place of Presentation
      Hiroshima
    • Year and Date
      20121208-09
  • [Presentation] Synthesis and Supramolecular Polymerization of Rim-to-Rim Connected Biscalix[4]resorcinarene Bridged by Alkyl Chains2012

    • Author(s)
      H. Yamada, T. Ikeda, T. Mizuta, T. Haino
    • Organizer
      The 9th Nano Bio Info Chemistry Symposium and The 6th Japanese-Russian Seminar
    • Place of Presentation
      Hiroshima
    • Year and Date
      20121208-09
  • [Presentation] Supramolecular Assembly of Trisphenylisoxazolyl benzene2012

    • Author(s)
      T. Haino
    • Organizer
      7th Japan-Taiwan Bilateral Symposium
    • Place of Presentation
      Hsinchu, Taiwan
    • Year and Date
      20121022-23
  • [Presentation] Supramolecular Polymerization driven by Unique Host-Guest Interaction2012

    • Author(s)
      T. Haino
    • Organizer
      Japan-India Bilateral Seminor on Supramolecular Nanomaterials for Energy Innovation
    • Place of Presentation
      Takamatsu, Kagawa
    • Year and Date
      20121015-16
  • [Presentation] カリックス[5]アレーンとフラーレンのホスト-ゲスト相互作用を基盤とした超分子ポリマー2012

    • Author(s)
      灰野岳晴, 平尾岳大, 平井恵梨 池田俊明
    • Organizer
      第61回高分子討論 特定テーマS13特異形態を持つ高分子組織化材料の創製と機能
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      20120919-21
  • [Presentation] ペリレンビスイミドを導入したトリス(フェニルイソオキサゾリル)ベンゼンのらせん集積とキロプティカル物性2012

    • Author(s)
      灰野岳晴, 増田哲也, 平尾岳大, 池田俊明, 湯浅順平, 妻鳥紘之 河. 壯
    • Organizer
      第61回高分子討論会 特定テーマS4キラル高分子・超分子の合成と機能
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      20120919-19
  • [Presentation] Polymeric Porphyrin Assemblies Driven by Molecular Recognition2012

    • Author(s)
      T. Haino
    • Organizer
      221st ECS Meeting
    • Place of Presentation
      Seattle, WA, USA
    • Year and Date
      20120506-10
  • [Presentation] Cross-linking of C60-Tagged Polyphenylacetylene by Molecular Recognition2012

    • Author(s)
      T. Haino, E. Hirai, Y. Fujiwara K. Kashihara
    • Organizer
      243rd ACS National Meeting
    • Place of Presentation
      San Diego, CA, USA
    • Year and Date
      20120325-29
  • [Presentation] 多様な分子間相互作用が織りなす超分子構造と革新的機能2012

    • Author(s)
      灰野岳晴
    • Organizer
      近畿化学協会有機金属部会「第3回例会」
    • Place of Presentation
      広島大学
    • Year and Date
      2012-10-26
  • [Presentation] Photochromic Organogel Formed by Molecular Association of Tris(phenylisoxazolyl)benze and Bis(pyridylethynyl)benzene2011

    • Author(s)
      Y. Hirai, T. Ikeda, T. Haino
    • Organizer
      Nano Bio Info Chemistry Symposium
    • Place of Presentation
      Hiroshima Uiversity
    • Year and Date
      20111210-11
  • [Presentation] Supramolecula fullerene networks driven by molecular recognitio of calix[5]arene and C602011

    • Author(s)
      T. Hirao, T. Ikeda, T. Haino
    • Organizer
      Nano Bio Info Chemistry Symposium
    • Place of Presentation
      Hiroshima University
    • Year and Date
      20111210-11
  • [Presentation] Self-assembly and chiroptical properties of chiral tris(phenylisoxazolyl)benzene possessing perylenebisimide2011

    • Author(s)
      T. Ikeda, T. Masuda, T. Haino
    • Organizer
      Nano Bio Info Chemistry Symposium
    • Place of Presentation
      Hiroshima University
    • Year and Date
      20111210-11
  • [Presentation] Self-assembly of extended π-conjugated molecule based on penylisoxazoles2011

    • Author(s)
      Y. Ueda, T. Ikeda, T. Haino
    • Organizer
      Nano Bio Info Chemistry Symposium
    • Place of Presentation
      Hiroshima University
    • Year and Date
      20111210-11
  • [Presentation] 分子認識により自己集合する超分子ポリマー2011

    • Author(s)
      灰野岳晴
    • Organizer
      第12回リングチューブ超分子研究会
    • Place of Presentation
      大阪
    • Year and Date
      20111101-02
  • [Presentation] クレフト型ビスポルフィリンの分子認識により形成される超分子ポリマー.2011

    • Author(s)
      灰野岳晴, 藤井隆吏, 渡邉亮英, 高. 麗, 平尾岳大, 金城可愛志 池田俊明
    • Organizer
      第60回高分子討論会 特定テーマS4 キラル高分子・超分
    • Place of Presentation
      岡山大学
    • Year and Date
      20110928-30
  • [Presentation] Supramolecular Polymer Formed via Molecular Recognition2011

    • Author(s)
      T. Haino
    • Organizer
      6th Japan-Taiwan Bilateral Symposium
    • Place of Presentation
      Higashi-Hiroshima, Japan
    • Year and Date
      20110818-19
  • [Presentation] Supramolecular Cross-linking of C60-grafted Polyphenylacetylene driven by Molecular Recognition2011

    • Author(s)
      T. Haino
    • Organizer
      219th ECS Meeting
    • Place of Presentation
      Montreal, QC, Canada
    • Year and Date
      20110501-06
  • [Presentation] 金属配位により自己集合する超分子ホストの分子認識2011

    • Author(s)
      T. Haino
    • Organizer
      第4回中国四国地区錯体化学研究会
    • Place of Presentation
      東広島
    • Year and Date
      2011-04-23
  • [Book] In Supramolecular Chemistry of Fullerenes and Carbon Nanotubes; Martín(N., Nierengarten, J.-F., Eds)2011

    • Author(s)
      T. Haino, T. Ikeda
    • Publisher
      Wiley-VCH : Weinheim
  • [Remarks]

    • URL

      http://home.hiroshima-u.ac.jp/orgchem/

  • [Patent(Industrial Property Rights)] グラフェン構造体2013

    • Inventor(s)
      灰野岳晴, 関谷亮
    • Industrial Property Rights Holder
      灰野岳晴, 関谷亮
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特願2013-263218
    • Filing Date
      2013-12-20

URL: 

Published: 2015-06-25  

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