2013 Fiscal Year Final Research Report
Development of degradation and functional technique of cellulose with low environmental burden
| Project/Area Number |
23655147
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Environmental chemistry
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| Research Institution | Meijo University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
MASATO Sakaguchi 静岡県立大学, 環境科学研究所, 教授 (40113328)
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| Project Period (FY) |
2011 – 2013
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| Keywords | メカノケミカル / セルロース / HEMA / 立体規則性 / ブロック共重合体 |
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| Research Abstract |
In this study, we investigated the degradation and surface modification of cellulose using mechano-chemical reaction. The mechano-chemically degradation of cellulose proceeded from the surface at the molecular level. Next, mechano-chemical reaction of cellulose and 2-hydroxyethyl methacrylate (HEMA) in a tube under vacuum showed the production of block copolymer of cellulose-block-poly(HEMA). Furthermore mechano-chemical reaction of benzyl cellulose and HEMA in a tube under vacuum also produced the block copolymer, whereas the tacticity of HEMA polymerized varied as compared with the case of cellulose.
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