Development of Functional Materials Based on Revolver-shaped Molecules

2012 Fiscal Year Final Research Report

• Project/Area Number: 23655178
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Functional materials/Devices
• Research Institution: Hiroshima University
• Principal Investigator: NISHIHARA Sadafumi 広島大学, 大学院・理学研究科, 准教授 (00405341)
• Co-Investigator(Renkei-kenkyūsha): INOUE Katsuya 広島大学, 大学院・理学研究科, 教授 (40265731)
• Project Period (FY): 2011 – 2012
• Keywords: 有機電子材料 / 素子

Research Abstract

The purpose of this project is to develop a functional material with ion motion in the solid state by using revolver-shaped molecules which are composed of a crown-ether and a metal ion. Herein, we report crystal structures and physical properties of two salts including revolver-shaped molecules. From the crystal structures, crown-ethers are one-dimensionally stacked giving an ion channel structure and the ion conductivities are estimated from an AC impedance measurement.

Research Products

• [Journal Article] Crystal structure and magnetic properties of honeycomb-like lattice antiferromagnet p-BIP-V-2 (2013)
  • Author(s): H. Yamaguchi, S. Nagata, M. Tada, K. Iwase, T. Ono, S. Nishihara, Y. Hosokoshi, T. Shimokawa, H. Nakano, H. Nojiri, A. Matsuo, K. Kindo and T. Kawakami
  • Journal Title: Phys.Rev. B Volume: 87 Pages: 125120-1-8
  • DOI: DOI:10.1103/Physrevb.87.125120
  • Peer Reviewed
• [Journal Article] Chiral Magnetic Soliton Lattice on a Chiral Helimagnet (2012)
  • Author(s): Y. Togawa, T. Koyama, K. Takayanagi, S. Mori, Y. Kousaka, J. Akimitsu, S. Nishihara, K. Inoue, A. S. Ovchinnikov and J. Kishine
  • Journal Title: Phys. Rev. Lett Volume: 108 Pages: 127202-1-5
  • DOI: DOI:10.1103/Physrevlett.108.107202
  • Peer Reviewed
• [Journal Article] Molecular Photoconductor with Simultaneously Photocontrollable Localized Spins (2012)
  • Author(s): T. Naito, T. Karasudani, S. Mori, K. Ohara, K. Konishi, T. Takano, Y. Takahashi, T. Inabe, S. Nishihara and K. Inoue
  • Journal Title: J. Am. Chem. Soc. Volume: 134 Pages: 18656-18666
  • DOI: DOI:10.1021/Ja306260b
  • Peer Reviewed
• [Journal Article] Syntheses, crystal structures and physical properties of two unusual 4d-4f heterometallic coordination polymers (2012)
  • Author(s): G. X. Liu, H. Zhou, X. C. Zha, C. Y. Zhang, Y. Wang, S. Nishihara and X. M. Ren
  • Journal Title: Inorganica Chimica Acta Volume: 387 Pages: 308-313
  • DOI: DOI:10.1016/j.ica.2012.02.010
  • Peer Reviewed
• [Journal Article] Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands (2012)
  • Author(s): G. X. Liu, X. C. Zha, Y. Wang, S. Nishihara and X. M. Ren
  • Journal Title: J. Inorg. Organomet. P Volume: 22 Pages: 258-263
  • DOI: DOI:10.1007/s10904-011-9530-6
  • Peer Reviewed
• [Journal Article] Temperature-induced assembly of MOF polymorphs: Syntheses, structures and physical properties (2012)
  • Author(s): G. X. Liu, H. Xu, H. Zhou, S. Nishihara and X. M. Ren
  • Journal Title: CrystEngComm Volume: 14 Pages: 1856-1864
  • DOI: DOI:10.1039/C1ce05369h
  • Peer Reviewed
• [Journal Article] A Coordination Polymer With a (3,4)-Connected (6(2).8)(2)(6(2).8(4)) 3D Network: Synthesis, Crystal Structure and Luminescent Properties (2012)
  • Author(s): G. X. Liu, W. Guo, S. Nishihara and X. M. Ren
  • Journal Title: Synth. React. Inorg. M Volume: 42 Pages: 1222-1226
  • DOI: DOI:10.1080/15533174.2012.680092
  • Peer Reviewed
• [Journal Article] Synthesis, Crystal Structure, and Magnetic Properties of a 3d-3d Mixed Heterometallic Coordination Polymer (2012)
  • Author(s): X. J. Kong, C. Guo, G. X. Liu, Y. Wang and S. Nishihara
  • Journal Title: Russ. J. Coord. Chem Volume: 38 Pages: 134-139
  • DOI: DOI:10.1134/S1070328412010046
  • Peer Reviewed
• [Journal Article] Syntheses, Structures and Luminescent Properties of Zinc(II) and Cadmium(II) Complexes With the Ditopic Ligand 1,3-Bis(imidazol-1-ylmethyl)benzene (2012)
  • Author(s): R. Y. Huang, G. X. Liu, H. M. Xu, S. Nishihara and X. M. Ren
  • Journal Title: J. Chem. Crystallogr Volume: 42 Pages: 416-422
  • DOI: DOI:10.1007/s10870-011-0257-6
  • Peer Reviewed
• [Journal Article] A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1,3,5-Triacetate Acid with Phenanthroline (2011)
  • Author(s): G. X. Liu, X. C. Zha, Y. Wang, S. Nishihara and X. M. Ren
  • Journal Title: J. Inorg. Organomet. Poly. Mat Volume: 21 Pages: 201-206
  • DOI: DOI:10.1007/s10904-010
  • Peer Reviewed
• [Journal Article] Construction of two metal coordination polymers based on 1,4-terephthalate and 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene (2011)
  • Author(s): G. X. Liu, X. L. Xu, Y. Y. Xu, S. Nishihara and X. M. Ren
  • Journal Title: Russ. J. Coord. Chem. Volume: 37 Pages: 202-210
  • DOI: DOI:10.1134/S1070328411020035
  • Peer Reviewed
• [Journal Article] Synthesis, structure and magnetic properties of a pentanuclear Cu(II) coordination polymer with 4-(imidazol-1-yl)-benzoic acid (2011)
  • Author(s): G. X. Liu, X. F. Wang, H. Zhou and S. Nishihara
  • Journal Title: Inorg. Chem. Commun Volume: 14 Pages: 1444-1447
  • DOI: DOI:10.1016/j.inoche.2011.05.043
  • Peer Reviewed
• [Journal Article] Synthesis, Crystal Structure, Electronic Absorption and Magnetic Properties of a Novel Anion-Radical Salt Based on 7,7,8,8-Tetracyanoquinodimethane (2011)
  • Author(s): G. X. Liu, W. Guo, H. Yang, S. Nishihara and X. M. Ren
  • Journal Title: J. Chem. Crystallogr Volume: 41 Pages: 1262-1267
  • DOI: DOI:10.1007/s10870-011-0085-8
  • Peer Reviewed
• [Journal Article] A chiral copper(II) inverse-9-metallacrown-3 complex: Synthesis, crystal structure, ferroelectric and magnetic properties (2011)
  • Author(s): G. X. Liu, W. Guo, S. Nishihara and X. M. Ren
  • Journal Title: Inorganica Chimica Acta Volume: 368 Pages: 165-169
  • DOI: DOI:10.1016/j.ica.2010.12.067
  • Peer Reviewed
• [Journal Article] An unusual two-dimensional 2-fold interpenetrating metal -organic framework based on tetranuclear manganese(II) clusters: Synthesis, structure and magnetic properties (2011)
  • Author(s): G. X. Liu, X. C. Cha, X. L. Li, C. Y. Zhang, Y. Wang, S. Nishihara and X. M. Ren
  • Journal Title: Inorg. Chem. Commun Volume: 14 Pages: 867-872
  • DOI: DOI:10.1016/j.inoche.2011.03.013
  • Peer Reviewed
• [Presentation] 超分子化学的手法を用いた低温駆動リチウム固体電解質の開発 (2013)
  • Author(s): 西原禎文、今野大輔、井上克也、芥川智行、中村貴義
  • Organizer: 日本化学会第93 春季年会
  • Place of Presentation: 滋賀
  • Year and Date: 2013-03-23
• [Presentation] ランタノイドイオンを内包した Preyssler 型 POM、K_12[TbP_5W_30O_110]の構造と物性 (2013)
  • Author(s): 加藤智佐都,西原禎文,綱島亮,帯刀陽子,井上克也
  • Organizer: 日本化学会第93 春季年会
  • Place of Presentation: 滋賀
  • Year and Date: 2013-03-23
• [Presentation] [Ca_4Cl_2(H_2O)_8(CB[6])]Cl_6・x(H_2O) 塩内の水分子揺らぎの観測と機能発現 (2012)
  • Author(s): 佐古渚, 西原禎文,井上克也
  • Organizer: 第6回分子科学討論会
  • Place of Presentation: 東京
  • Year and Date: 2012-09-21
• [Presentation] イオンチャネル構造を有する [Ni(dmit)2] 塩の作製と物性 (2012)
  • Author(s): 今野大輔, 西原禎文 , 秋田素子, 井上克也, 芥川智行, 中村貴義
  • Organizer: 第6回分子科学討論会
  • Place of Presentation: 東京
  • Year and Date: 2012-09-21
• [Presentation] Cucurbit[n]uril に含まれた水分子の結晶内揺らぎの発現と物性評価 (2012)
  • Author(s): 佐古渚,今野大輔 , 西原禎文, 井上克也
  • Organizer: 「物質・デバイ ス領域共同研究拠点」研究会
  • Place of Presentation: 北海道
  • Year and Date: 2012-06-18
• [Presentation] ランタノイドイオンを包接した Preyssler 型 POM の合成と機能発現 (2012)
  • Author(s): 加藤智佐都,西原禎文,綱島亮,帯刀陽子,井上克也
  • Organizer: 「物質・デバイス領域共同研究拠点」研究会
  • Place of Presentation: 北海道
  • Year and Date: 2012-06-18
• [Presentation] イオンチャネル構造を有するLi_2([15]crown-5)_3[Ni(dmit)_2]_2(H_2O)_2 塩の作製と物性 (2012)
  • Author(s): 今野大輔,西原禎文,秋田素子,井上克也,芥川智行,中村貴義
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 神奈川
  • Year and Date: 2012-03-27
• [Presentation] ランタノイドイオンを内包したPreyssler 型POM、K_12[GdP_5W_30O_110]の構造と磁気物性 (2012)
  • Author(s): 加藤智佐都, 西原禎文, 綱島亮, 帯刀陽子, 井上克也
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 神奈川
  • Year and Date: 2012-03-27
• [Presentation] Cucurbituril を含む機能分子材料の開発 (2012)
  • Author(s): 佐古渚 ,西原禎文,井上克也
  • Organizer: 日本化学会第92 春季年会
  • Place of Presentation: 神奈川
  • Year and Date: 2012-03-26
• [Presentation] Observation of Magnetic and Structural Phase Transition in Li_2([15]crown-5)_3[Ni(dmit)_2]_2(H_2O)_2 (2011)
  • Author(s): Daisuke Konno, Sadafumi Nishihara, Motoko Akita, Katsuya Inoue, Tomoyuki Akutagawa, and Takayoshi Nakamura
  • Organizer: The Fifth Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices.
  • Place of Presentation: Awaji, Japan
  • Year and Date: 2011-11-14
• [Presentation] Crystal Structure and Magnetic Properties of A Doughnut-shaped POM Including Gadolinium(III) (2011)
  • Author(s): Chisato Kato , Sadafumi Nishihara , Ryo Tsunashima, Yoko Tatewaki, Katsuya Inoue
  • Organizer: The Fifth Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices
  • Place of Presentation: Awaji, Japan
  • Year and Date: 2011-11-14
• [Presentation] Crystal Structure and Physical Properties of Li_2([18]crown-6)_3[Ni(dmit)_2]_2(H_2O)_4Salt Having an Ion Channel (2011)
  • Author(s): Daisuke Konno, Sadafumi Nishihara, Motoko Akita, Katsuya Inoue, Tomoyuki Akutagawa, and Takayoshi Nakamura
  • Organizer: 9th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets
  • Place of Presentation: Poznan, Poland
  • Year and Date: 2011-11-12
• [Presentation] イオンチャネル構造を有するLi_2([18]crown-6)_3[Ni(dmit)_2]_2(H_2O)_4 塩の電気物性評価発表者 (2011)
  • Author(s): 今野大輔, 西原禎文, 秋田素子,井上克也,芥川智行,中村貴義
  • Organizer: 錯体化学会第61回討論会
  • Place of Presentation: 岡山
  • Year and Date: 2011-09-18
• [Remarks]
  • URL: http://seeds.hiroshima-u.ac.jp/soran/e2dgfd7/a.html
• [Patent(Industrial Property Rights)] 有機ラジカル化合物 (2013)
  • Inventor(s): 井上克也, 西原禎文,谷本晃一
  • Industrial Property Rights Holder: 井上克也, 西原禎文,谷本晃一
  • Industrial Property Number: 2013-006705
  • Filing Date: 2013-01-17