2012 Fiscal Year Final Research Report
Fabrication of one-dimensionally aligned reactive sites with non-contact process
| Project/Area Number |
23655186
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic industrial materials
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| Research Institution | Kobe University |
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Principal Investigator |
UEDA Yasukiyo 神戸大学, 大学院・工学研究科, 教授 (40116190)
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| Co-Investigator(Kenkyū-buntansha) |
MISAKI Masahiro 神戸大学, 自然科学研究科, 助教 (00462862)
KOSHIBA Yasuko 神戸大学, 大学院・工学研究科, 助手 (70243326)
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| Project Period (FY) |
2011 – 2012
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| Keywords | 分子配向反応場 / 非接触プロセス / 光異性 / 一軸配向 / 有機トランジスタ |
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| Research Abstract |
With the aim of fabrication of one-dimensionally oriented reaction site, we studied on photo-induced orientation behavior of polyamic acid with azo-benzene moiety (Azo-PAA), introduction of reaction site into silicon substrate, synthesis of fluorene derivatives with azo-benzene moiety and introduction of reaction site into partially imidized Azo-PAA. Partially imidized Azo-PAA with 3-aminopropyl-triethoxysilane aligned one-dimensionally by irradiation of polarized UV light with trans-cis isomerization of azo-benzene moiety. Triethoxysilane groups at top surface of aligned Azo-PAA may act as reaction sites with various functional groups
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[Journal Article] Synthesis, Characterization, Photo-induced Alignment, and Surface Orientation of Poly(9,9-dioctylfluorene- alt- azobenzene)s2012
Author(s)
K. Kinashi, Yuki Kambe, M. Misaki, Y. Koshiba, K. Ishida, Y. Ueda
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Journal Title
J. Polym. Sci., Part A,Polym. Chem
Volume: Vol. 50
Pages: 5107-5114
DOI
Peer Reviewed
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