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2012 Fiscal Year Final Research Report

Control of graphene properties based on atomic structure design on substrate surfaces

Research Project

  • PDF
Project/Area Number 23656029
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionYokohama National University

Principal Investigator

OGINO Toshio  横浜国立大学, 大学院・工学研究院, 教授 (70361871)

Project Period (FY) 2011 – 2012
Keywordsグラフェン / ナノカーボン / 表面界面基板 / 酸化物単結晶 / ポーラスアルミナ / 原子間力顕微鏡 / ラマン分光
Research Abstract

We investigated structure of the interfacial water layers between graphene sheets and a sapphire substrate by observing them through graphene sheets at room temperature. When graphene sheets were deposited at a low relative humidity, the interfacial water layers appeared as small islands. This study shows that the electrical properties of graphene sheets are tunable by controlling the hydrophilicity of substrate surfaces. For bandgap opening, we attached monolayer graphene sheets grown by chemical vapor deposition to porous alumina membranes with ordered hexagonal pores. We confirmed that strains are introduced into the graphene sheets. Porous alumina membranes are useful for strain engineering of graphene sheets.

  • Research Products

    (61 results)

All 2013 2012 2011 Other

All Journal Article (10 results) (of which Peer Reviewed: 6 results) Presentation (46 results) Book (3 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] 溶液中の金属酸化物表面と吸着水の構造評価2012

    • Author(s)
      荻野俊郎, 山崎憲慈
    • Journal Title

      表面科学

      Volume: 33巻 Pages: 339-344

  • [Journal Article] Evolution of step morphology on vicinal sapphire (1-102) surfaces accompanied with self-assemblyof comb-shaped chemical domains2012

    • Author(s)
      H. Komurasaki, T. Isono, T. Tsukamoto, and T. Ogino
    • Journal Title

      Appl. Surf. Sci.

      Volume: 258巻 Pages: 5666-5671

    • DOI

      DOI:10.1016/j.apsusc.2012.02.052

    • Peer Reviewed
  • [Journal Article] Layered structures of interfacial water and their effects on Raman spectra in grapheme-on-sapphire systems2012

    • Author(s)
      H. Komurasaki, T. Tsukamoto, K. Yamazaki, and T. Ogino
    • Journal Title

      J. Phys. Chem. C

      Volume: 115巻 Pages: 10084-10089

    • DOI

      DOI:10.1021/jp301402u

    • Peer Reviewed
  • [Journal Article] Control of graphene etching by atomic structures of the supporting surfaces2011

    • Author(s)
      T. Tsukamoto and T. Ogino
    • Journal Title

      J. Phys. Chem. C

      Volume: 115巻 Pages: 8580-8585

    • DOI

      DOI:org/10.1021/jp1094933

    • Peer Reviewed
  • [Journal Article] ポーラスアルミナ三次元マイクロ構造体2011

    • Author(s)
      塚本貴広、加瀬貴之、荻野 俊郎
    • Journal Title

      表面技術

      Volume: 62巻 Pages: 330-334

  • [Journal Article] Fabrication of three-dimensional porous alumina microstructures using imprinting method2011

    • Author(s)
      T. Tsukamoto and T. Ogino
    • Journal Title

      J. Electrochem. Soc

      Volume: 159巻 Pages: C155-159

    • DOI

      DOI:10.1149/2.038204jes

  • [Journal Article] Effects of Surface Chemistry of Substrates on Raman Spectra in Graphene2011

    • Author(s)
      T. Tsukamoto, K. Yamazaki, H. Komurasaki, and T. Ogino
    • Journal Title

      J. Phys.Chem. C

      Volume: 116巻 Pages: 4732-4737

    • DOI

      DOI:org/10.1021/jp2113158

    • Peer Reviewed
  • [Journal Article] Graphene etching controlled by atomic structures on the substrate surface2011

    • Author(s)
      T. Tsukamoto and T. Ogino
    • Journal Title

      CARBON

      Volume: 50巻 Pages: 674-679

    • DOI

      DOI:10.1016/j.carbon.2011.09.026

    • Peer Reviewed
  • [Journal Article] Selective deposition of lipid membranes on locally anodic-oxidized silicon surface2011

    • Author(s)
      M. Nakamura and T. Ogino
    • Journal Title

      e-J Surf. Sci. Nanotech

      Volume: 9巻 Pages: 357-362

    • Peer Reviewed
  • [Journal Article] Selective adsorption of protein molecules on phase-separated sapphire surfaces2011

    • Author(s)
      K. Yamazaki, T. Ikeda, T. Isono, and T. Ogino
    • Journal Title

      J. Colloid and Interface Science

      Volume: 351巻 Pages: 64-70

    • DOI

      DOI:10.1016/j.jcis.2011.05.016

  • [Presentation] 単結晶絶縁性基板上のグラフェン2013

    • Author(s)
      荻野俊郎,飯田祐介,加瀬貴之,齋藤 昂,山崎憲慈
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2013-03-29
  • [Presentation] 自発展開法による脂質ラフトドメイン形成2013

    • Author(s)
      横田圭司, 國井俊佑, 豊城晃彦, 山崎憲慈, 荻野俊郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2013-03-29
  • [Presentation] UV照射した自己組織化単分子膜上でのタンパク質吸着評価2013

    • Author(s)
      神谷康敬, 山崎憲慈, 荻野俊郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2013-03-29
  • [Presentation] 応用電子物性の展開-ナノ からバイオ・その先2013

    • Author(s)
      荻野俊郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2013-03-28
  • [Presentation] 原子配列の異なる表面に対するチタン認識フェリチンの吸着特性2013

    • Author(s)
      上原知之, 荻野 俊郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2013-03-28
  • [Presentation] グラフェン表面への脂質膜形成における支持表面の効果2013

    • Author(s)
      山崎憲慈, 荻野俊郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2013-03-28
  • [Presentation] AFM電流マッピングによるグラフェンの局所的性質の評価2013

    • Author(s)
      井辻宏章,梶ヶ谷晋矢,荻野俊郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2013-03-27
  • [Presentation] 銀コートAFM探針を用いたグラフェンへの触媒微粒子配置制御2013

    • Author(s)
      増山大祐,飯田祐介,荻野俊郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2013-03-27
  • [Presentation] Study on morphology of three-component lipid membranes formed by self-spreading method2013

    • Author(s)
      K. Yokota, S. Kunii, A.Toyoki, K. Yamazaki T. Ogino
    • Organizer
      Int. Conf. on Molecular Electronics and Bioelectronics
    • Place of Presentation
      Fukuoka
    • Year and Date
      2013-03-19
  • [Presentation] Characterization of the Interfaces, Direct Growth and Patterning of Graphene Films on Sapphire Substrates and its Applicatin to Bioelectronics Symposium on Medical2013

    • Author(s)
      T. Ogino, K. Saito, Y. Iida, T. Kase and K. Yamazaki
    • Organizer
      Bio- and Nano-Electronics
    • Place of Presentation
      Sendai
    • Year and Date
      2013-02-28
  • [Presentation] Characterization of the Interfaces, Direct Growth and Patterning of Graphene Films on Sapphire Substrates2013

    • Author(s)
      T. Ogino, K. Saito, Y. Iida, T. Kase and K.Yamazaki
    • Organizer
      6th Int. Workshop on New Group IV Semiconductor Nanoelectronics
    • Place of Presentation
      Sendai
    • Year and Date
      2013-02-22
  • [Presentation] Structural control of single-crystalline metal oxide sufaces toward bioapplications2013

    • Author(s)
      T. Ogino
    • Organizer
      KVS-JVS-SSSJ joint symposium in the 44th Winter Conference of The Korean Vacuum Society
    • Place of Presentation
      Pyongchang, (韓国)
    • Year and Date
      2013-02-19
  • [Presentation] Effect of chemical doping from support substrate to graphene in aqueous environment2012

    • Author(s)
      Kenji Yamazaki and Toshio Ogino
    • Organizer
      The 10th Japan-Russia Seminar on Semiconductor Surfaces
    • Place of Presentation
      Tokyo
    • Year and Date
      20120926-20120925
  • [Presentation] Evolution of Graphene Growth on Sapphire (0001) and (11-20) Surfaces by Self-catalytic Chemical Vapor Deposition2012

    • Author(s)
      K. Saito, Y. Iida .K. Yamazaki, T. Ogino
    • Organizer
      Mat. Res. Soc. Fall Meeting
    • Place of Presentation
      Boston, MA (米国)
    • Year and Date
      2012-11-27
  • [Presentation] Characterization of Graphene Surface in Aqueous Environment by Protein Adsorption and AFM Force Measurements2012

    • Author(s)
      K.Yamazaki,T. Ogino
    • Organizer
      Mat. Res. Soc. Fall Meeting
    • Place of Presentation
      Boston, MA (米国)
    • Year and Date
      2012-11-27
  • [Presentation] Fabrication of Graphene NanoribbonsUsing Biologically Synthesized Metal Nanoparticles2012

    • Author(s)
      Y. Iida, K. Yamazaki, T. Ogino
    • Organizer
      Mat. Res. Soc. Fall Meeting
    • Place of Presentation
      Boston, MA (米国)
    • Year and Date
      2012-11-27
  • [Presentation] Strain Engineering of Graphene by Porous Alumina Membrane2012

    • Author(s)
      T. Kase, T. Ogino
    • Organizer
      Mat. Res. Soc. Fall Meeting
    • Place of Presentation
      Boston, MA (米国)
    • Year and Date
      2012-11-27
  • [Presentation] 表面構造制御のナノ・バイ オへの展開2012

    • Author(s)
      荻野俊郎
    • Organizer
      第32回表面科学学術講演会
    • Place of Presentation
      仙台
    • Year and Date
      2012-11-21
  • [Presentation] Graphene on Sapphire-Characterization of the Interfaces, Direct Growth, and Patterning2012

    • Author(s)
      T. Ogino, K. Saito, Y. Iida, T. Kase and K.Yamazaki
    • Organizer
      3rd International Symposium on GrapheneDevices ISGD-2012
    • Place of Presentation
      Saint-Aubin, (フランス)
    • Year and Date
      2012-11-08
  • [Presentation] Character- ization of Interfaces between Graphene Flakes, Support Substrates, and Biomolecules in Aqueous Environment2012

    • Author(s)
      K. Yamazaki, T. Ogino
    • Organizer
      3rd International Symposium onGraphene Devices
    • Place of Presentation
      Saint-Aubin, (フランス)
    • Year and Date
      2012-11-08
  • [Presentation] Effects of an interfacial water layer on protein adsorption to graphene sheets on solid substrates2012

    • Author(s)
      Kenji Yamazaki and Toshio Ogino
    • Organizer
      AVS 59th Int. Symp. & Exhibition
    • Place of Presentation
      Tampa, Florida (米 国)
    • Year and Date
      2012-10-08
  • [Presentation] Effects of Interfacial Water on Raman Spectra of Graphene Films Deposited on the Substrates under Various Relative Humidities2012

    • Author(s)
      Shinya Kajigaya, Hiroki Komurasaki, Takahiro Tsukamoto and Toshio Ogino
    • Organizer
      The 10th Japan-Russia Seminar on Semiconductor Surfaces
    • Place of Presentation
      Tokyo
    • Year and Date
      2012-09-25
  • [Presentation] Effects of InterfacialWater on Raman Spectra of Graphene Films Deposited on the Substrates under Various Relative Humidities2012

    • Author(s)
      Toshiyuki Takami, Ryosuke Seino, andToshio Ogino
    • Organizer
      The 10th Japan-Russia Seminar on Semiconductor Surfaces
    • Place of Presentation
      Tokyo
    • Year and Date
      2012-09-25
  • [Presentation] ポリマーを炭素源とするCu基板上でのグラフェン成長2012

    • Author(s)
      高見俊志, 加瀬貴之, 齊藤昂介, 荻野俊郎
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Year and Date
      2012-09-14
  • [Presentation] CVD法によるサファイア(11-20)面へのグラフェン成長2012

    • Author(s)
      齊藤昂介, 飯田祐介, 山崎憲慈, 荻野俊郎
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Year and Date
      2012-09-14
  • [Presentation] 銀微粒子を用いた架橋グラフェンへの細孔形成2012

    • Author(s)
      増山大祐, 飯田祐介, 戸邊翼, 荻野俊郎
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Year and Date
      2012-09-14
  • [Presentation] コロイドプローブによる溶液中でのグラフェン表面の相互作用力測定2012

    • Author(s)
      山崎憲慈,荻野俊郎
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Year and Date
      2012-09-13
  • [Presentation] 単結晶酸化チタン表面におけるチタン認識フェリチンの吸着特性2012

    • Author(s)
      上原知之,吉原万莉,大矢剛嗣,山下一郎,荻野俊郎
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Year and Date
      2012-09-13
  • [Presentation] グラフェン支持基板表面におけるフェリチン配置制御2012

    • Author(s)
      飯田祐介,山崎憲慈,荻野俊郎
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Year and Date
      2012-09-12
  • [Presentation] ポーラスアルミナ基板によるグラフェンへの周期的歪みの導入2012

    • Author(s)
      加瀬貴之,高見俊志,荻野俊郎
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Year and Date
      2012-09-12
  • [Presentation] Structural control of single-crystalline metal oxide surfaces toward bioallications2012

    • Author(s)
      T. Ogino
    • Organizer
      3rd Int. Workshop on Nanostructures&Nanoelectronics
    • Place of Presentation
      Sendai
    • Year and Date
      2012-03-22
  • [Presentation] 単結晶固体基板上におけるペプチド吸着特性の観察2012

    • Author(s)
      上原知之, 羽中田祥司, 山崎憲慈, 吉原万莉, 荻野俊郎
    • Organizer
      応用物理学関係連合講演会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-17
  • [Presentation] 固体表面上に貼り付けたグラフェンによる脂質二重膜の展開制2012

    • Author(s)
      國井俊佑, 荻野俊郎
    • Organizer
      御応用物理学関係連合講演会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-17
  • [Presentation] 固体表面に吸着したタンパク質の脱離評価2012

    • Author(s)
      神谷康敬,山崎憲慈,和田朋也,荻野俊郎
    • Organizer
      応用物理学関係連合講演会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-17
  • [Presentation] 自己組織化単分子膜の形成による金属酸化物表面における相分離の検証2012

    • Author(s)
      吉原万莉,荻野俊郎
    • Organizer
      応用物理学関係連合講演会応用物理学関係連合講演会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-17
  • [Presentation] グラフェン表面へのタンパク質分子吸着における支持基板表面の影響(2)2012

    • Author(s)
      山崎憲慈,塚本貴広,小紫大希,荻野俊郎
    • Organizer
      応用物理学関係連合講演会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-17
  • [Presentation] Observation of adsorption characteristics of peptides to single-crystalline solid surface2011

    • Author(s)
      T. Uehara, S. Hachuda, K. Yamazaki, M.Yoshihara, T. Ogino
    • Organizer
      21st Academic Symp. on MRS-Japan. International Session
    • Place of Presentation
      Yokohama
    • Year and Date
      2011-12-20
  • [Presentation] Phase separation in ternary-system membranes formed by self-spreading method2011

    • Author(s)
      A. Toyoki, T. Isono, and T. Ogino
    • Organizer
      Int. Symp. on Surf. Sci.
    • Place of Presentation
      Tokyo
    • Year and Date
      2011-12-13
  • [Presentation] Characterization of the phase-separated sapphire substrate in liquid by AFM force measurement2011

    • Author(s)
      T. Wada, K. Yamazaki, and T. Ogino
    • Organizer
      Int. Symp. on Surf. Sci
    • Place of Presentation
      Tokyo
    • Year and Date
      2011-12-13
  • [Presentation] Raman spectroscopy study of graphene sheets on porous alumina membranes2011

    • Author(s)
      T. Kase, T. Tsukamoto, and T. Ogino
    • Organizer
      Int. Symp. on Surf. Sci. Int. Symp. on Surf. Sci.
    • Place of Presentation
      Tokyo
    • Year and Date
      2011-12-13
  • [Presentation] Graphene growth on sapphire surfaces2011

    • Author(s)
      K Saito, T. Tsukamoto, and T. Ogino
    • Organizer
      Int. Symp. on Surf. Sci.
    • Place of Presentation
      Tokyo
    • Year and Date
      2011-12-13
  • [Presentation] Investigation graphene/substrate interface with Raman spectroscopy2011

    • Author(s)
      T. Tsukamoto, H. Komurasaki, K. Yamazaki, and T. Ogino
    • Organizer
      Int. Symp. on Surf. Sci.
    • Place of Presentation
      Tokyo
    • Year and Date
      2011-12-13
  • [Presentation] Fabrication of comb-shaped nanostructures on sapphire (1-102) surfaces by the scratch process2011

    • Author(s)
      S. Taguchi, H. Komurasaki, and T. Ogino
    • Organizer
      Int. Symp. on Surf. Sci.
    • Place of Presentation
      Tokyo
    • Year and Date
      2011-12-13
  • [Presentation] Atomic processes in self-assembly of chemical nanodomainson TiO2(100)2011

    • Author(s)
      M. Yoshihara, T. Isono, H. Komurasaki, and T. Ogino
    • Organizer
      Int. Symp. on Surf. Sci
    • Place of Presentation
      Tokyo
    • Year and Date
      2011-12-13
  • [Presentation] Role of Supported Substrates on Protein Adsorption to Graphene Surfaces2011

    • Author(s)
      K. Yamazaki, Y. Iida and T. Ogino
    • Organizer
      Mat. Res. Soc. Fall Meeting
    • Place of Presentation
      Boston(米国)
    • Year and Date
      2011-11-28
  • [Presentation] Effects of the Atomic Structure of a Substrate on Raman Spectra in Graphene2011

    • Author(s)
      T. Tsukamoto, Y. Iida and T. Ogino
    • Organizer
      Mat. Res. Soc. Fall Meeting
    • Place of Presentation
      Boston(米国)
    • Year and Date
      2011-11-28
  • [Book] Contributions and Premises (Chapter 3), Wiley-Blackwell2013

    • Author(s)
      M. Matsuda, A. Goto, T. Ogino, Y. Tanaka
    • Total Pages
      19
    • Publisher
      Nanotechnology and Public Health
  • [Book] グラフェンが拓く材料の新領 域 -物性・作製法から実用化まで-2012

    • Author(s)
      荻野俊郎
    • Total Pages
      12
    • Publisher
      株式会社エヌ・ティー・エス
  • [Book] Physics andApplication of Graphene2011

    • Author(s)
      T. Ogino and T. Tsukamoto
    • Total Pages
      18
    • Publisher
      Intech
  • [Remarks] Ogino Laboratory

    • URL

      http://oginolab.ynu.ac.jp/index.html

  • [Patent(Industrial Property Rights)] グラフェンリボンを備える単結晶絶縁性基板の製造方法及びグラフェンリボンを 備える単結晶絶縁性基板2011

    • Inventor(s)
      荻野俊郎,塚本貴広,飯田祐介, 小山浩司
    • Industrial Property Rights Holder
      荻野俊郎,塚本貴広,飯田祐介, 小山浩司
    • Industrial Property Number
      特許 2011-174978
    • Filing Date
      2011-08-10

URL: 

Published: 2014-09-25  

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