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2013 Fiscal Year Final Research Report

Bipolar resistance switching in magnetic films for the memristive device application

Research Project

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Project/Area Number 23656215
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Electronic materials/Electric materials
Research InstitutionOsaka Electro-Communication University (2013)
Kyoto University (2011-2012)

Principal Investigator

NAKAMURA Toshihiro  大阪電気通信大学, 工学部, 准教授 (90293886)

Project Period (FY) 2011 – 2013
Keywordsメモリスター / 抵抗スイッチング / ReRAM / マンガン酸化物 / ペロブスカイト / 電気化学インピーダンス法 / 分光エリプソメトリー / プラズマ還元
Research Abstract

Recently, bipolar resistance switching of metal oxide has been identified as being physical examples of memristors and/or memristive devices. The underlying mechanism of the memristive switching behavior is still poorly understood, although there have been various proposed models of the resistance switching mechanism. The comprehensive understanding for the origin of the memristive switching is required to meet the requirement for the next-generation memristive device application. In this work, the mechanism of bipolar resistance switching was investigated in perovskite manganite films for memristive devices. Impedance spectroscopic measurements indicated that the interface resistance significantly depends on the dopant concentration in the film. The correlation between dielectric function and resistance switching behavior was found by spectroscopic ellipsometry. The voltage required for resistance switching was reduced by plasma-assisted reduction of the film surface.

  • Research Products

    (26 results)

All 2014 2013 2012 2011

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (22 results) (of which Invited: 3 results)

  • [Journal Article] Spectroscopic ellipsometry analysis of perovskite manganite films for resistance switching devices2013

    • Author(s)
      M. Yamada, O. Sakai, and T. Nakamura
    • Journal Title

      Thin Solid Films

      Volume: (in press)

    • DOI

      10.1016/j.tsf.2013.11.145

    • Peer Reviewed
  • [Journal Article] Isotopic study on metalorganic chemical vapor deposition of manganite films2013

    • Author(s)
      T. Nakamura
    • Journal Title

      Surface & Coatings Technology

      Volume: 230 Pages: 213-218

    • DOI

      10.1016/j.surfcoat.2013.06.060

    • Peer Reviewed
  • [Journal Article] Thin film deposition of metal oxides in resistance switching devices : electrode material dependence of resistance switching in manganite films2013

    • Author(s)
      T. Nakamura, K. Homma, and K. Tachibana
    • Journal Title

      Nanoscale Research Letters

      Volume: 8(1) Pages: 76-1-7

    • DOI

      10.1186/1556-276X-8-76

    • Peer Reviewed
  • [Journal Article] Impedance Spectroscopy of Manganite Films Prepared by Metalorganic Chemical Vapor Deposition2011

    • Author(s)
      T. Nakamura, K. Homma, and K. Tachibana
    • Journal Title

      Journal of Nanoscience and Nanotechnology

      Volume: 11(9) Pages: 8408-8411

    • DOI

      10.1166/jnn.2011.5092

    • Peer Reviewed
  • [Presentation] パルスRF スパッタリング法による抵抗変化材料薄膜の作製2014

    • Author(s)
      塚本真大, 山田昌樹, 酒井道, 中村敏浩
    • Organizer
      2014年(平成26年)春季 第61回応用物理学関係連合講演会
    • Place of Presentation
      青山学院大学(相模原キャンパス)
    • Year and Date
      20140317-20
  • [Presentation] 大気圧プラズマを用いて生成されたヒドラジンによる抵抗変化薄膜の還元処理2014

    • Author(s)
      山田昌樹, 酒井道, 中村敏浩
    • Organizer
      2014年(平成26年)春季 第61回応用物理学関係連合講演会
    • Place of Presentation
      青山学院大学(相模原キャンパス)
    • Year and Date
      20140317-20
  • [Presentation] Atomic Composition on Surface and I-V Characteristics of Pr_<1-x>Ca_<x>MnO_<3> treated in H_<2> Plasmas2014

    • Author(s)
      T. Ishida, K. Takahashi, and T. Nakamura
    • Organizer
      The 8th International Conference on Reactive Plasmas (ICRP-8) and the 31st Symposium on Plasma Processing (SPP-31)
    • Place of Presentation
      Fukuoka, Japan
    • Year and Date
      20140203-07
  • [Presentation] Impedance spectroscopic study on resistance switching memory devices2013

    • Author(s)
      T. Nakamura
    • Organizer
      Energy, Materials, and Nanotechnology (EMN) Fall Meeting (2013 EMN Fall Meeting)
    • Place of Presentation
      Orlando, Florida, USA
    • Year and Date
      20131207-10
    • Invited
  • [Presentation] Correlation of Resistance Switching Behaviors with Dielectric Functions of Manganite Films : A Study by Spectroscopic Ellipsometry2013

    • Author(s)
      M. Yamada, T. Nakamura, and O. Sakai
    • Organizer
      Materials Research Society (MRS) Fall Meeting & Exhibit (2013 MRS Fall Meeting & Exhibit)
    • Place of Presentation
      Boston, Massachusetts, USA
    • Year and Date
      20131201-06
  • [Presentation] Pr_<1-x>Ca_xMnO_3 薄膜の光学特性と抵抗スイッチング特性との相関2013

    • Author(s)
      山田昌樹, 酒 井道, 中 村敏浩
    • Organizer
      2013年(平成25年)秋季 第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学(京田辺キャンパス)
    • Year and Date
      20130916-20
  • [Presentation] Isotopic Study on Metalorganic Chemical Vapor Deposition of Manganite Films2013

    • Author(s)
      T. Nakamura
    • Organizer
      The 19th European Conference on Chemical Vapor Deposition (EUROCVD-19)
    • Place of Presentation
      Varna, Bulgaria
    • Year and Date
      20130901-06
  • [Presentation] Spectroscopic ellipsometry analysis of perovskite manganite films for resistance switching devices2013

    • Author(s)
      M. Yamada, T. Xu, and T. Nakamura
    • Organizer
      The 6th International Conference on Spectroscopic Ellipsometry (ICSE-VI)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      20130526-31
  • [Presentation] 分光エリプソメトリーを用いたPr_<1-x>Ca_xMnO_3薄膜の光学的解析2013

    • Author(s)
      山田昌樹, 中村敏浩
    • Organizer
      2013年(平成25年)春季 第60回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      20130327-30
  • [Presentation] 二酸化チタン薄膜を用いた光電気化学効果セルの基礎検討(II)2013

    • Author(s)
      秋山知英, 中村敏浩, 酒井道
    • Organizer
      2013年(平成25年)春季 第60回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      20130327-30
  • [Presentation] Arプラズマにより処理したPr_<1-x>Ca_xMnO_3薄膜の表面構造及び電気的特性2013

    • Author(s)
      石田拓也, 高橋和生, 中村敏浩
    • Organizer
      第30回プラズマプロセシング研究会(SPP-30)
    • Place of Presentation
      アクトシティ浜松・研修交流センター
    • Year and Date
      20130121-23
  • [Presentation] タンデム型光電気化学セル実現へ向けた紫外光吸収層の高周波マグネトロン成膜2013

    • Author(s)
      秋山智英, 中村敏浩, 酒井道
    • Organizer
      第30回プラズマプロセシング研究会(SPP-30)
    • Place of Presentation
      アクトシティ浜松・研修交流センター
    • Year and Date
      20130121-23
  • [Presentation] Crystallinity and composition dependence of resistance switching in manganite films : A study by impedance spectroscopy2012

    • Author(s)
      T. Nakamura
    • Organizer
      Energy, Materials, and Nanotechnology (EMN) Fall Meeting (2012 EMN Fall Meeting)
    • Place of Presentation
      Las Vegas, Nevada, USA
    • Year and Date
      20121129-1202
    • Invited
  • [Presentation] Preparation of improved absorptive Si solar cells with TiO2 thin films2012

    • Author(s)
      T. Akiyama, T. Nakamura, and O. Sakai
    • Organizer
      The 11th Asia-Pacific Conference on Plasma Science and Technology (APCPST) and the 25th Symposium on Plasma Science for Materials
    • Place of Presentation
      (SPSM), Kyoto, Japan
    • Year and Date
      20121002-05
  • [Presentation] Sputter deposition of metal oxides in resistance switching devices2012

    • Author(s)
      M. Yamada, T. Xu, and T. Nakamura
    • Organizer
      The 11th Asia-Pacific Conference on Plasma Science and Technology (APCPST) and the 25th Symposium on Plasma Science for Materials (SPSM)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      20121002-05
  • [Presentation] 分光エリプソメトリーを用いたPr_<1-x>Ca_xMnO_3 薄膜の解析2012

    • Author(s)
      山田昌樹, 徐婷婷, 中村敏浩
    • Organizer
      2012年(平成24年)秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Year and Date
      20120911-14
  • [Presentation] プラズマによりエッチング処理したPr_<1-x>Ca_xMnO_3薄膜の電気的特性及び表面化学組成の解析2012

    • Author(s)
      石田拓也, 高橋和生, 中村敏浩
    • Organizer
      2012年(平成24年)秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Year and Date
      20120911-14
  • [Presentation] 二酸化チタン薄膜を用いた光電気化学効果セルの基礎検討2012

    • Author(s)
      秋山知英, 中村敏浩, 酒井道
    • Organizer
      2012年(平成24年)秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Year and Date
      20120911-14
  • [Presentation] X-ray absorption spectroscopic study of ferromagnetic transparent conducting films2012

    • Author(s)
      T. Nakamura and S. Isozaki
    • Organizer
      Joint European Magnetic Symposia 2012 (JEMS2012)
    • Place of Presentation
      Parma, Italy
    • Year and Date
      20120909-14
  • [Presentation] Thin film deposition of metal oxides in resistance switching devices2012

    • Author(s)
      T. Nakamura
    • Organizer
      Collaborative Conference on Materials Research 2012 (CCMR2012)
    • Place of Presentation
      Seoul, South Korea
    • Year and Date
      20120625-29
    • Invited
  • [Presentation] Pr_<1-x>Ca_xMnO_3 薄膜の分光エリプソメトリーによる解析2012

    • Author(s)
      徐婷婷, 中村敏浩
    • Organizer
      2012年(平成24年)春季 第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(早稲田キャンパス)/ 早稲田中・高等学校興風館
    • Year and Date
      20120315-18
  • [Presentation] Impedance Spectroscopy of Manganite Films Prepared by Metalorganic Chemical Vapor Deposition2011

    • Author(s)
      T. Nakamura, K. Homma, and K. Tachibana
    • Organizer
      The 18th European Conference on Chemical Vapor Deposition (EUROCVD-18)
    • Place of Presentation
      Kinsale, Ireland
    • Year and Date
      20110904-09

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Published: 2015-06-25  

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