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2012 Fiscal Year Final Research Report

Formation of A Water/Carbon Dioxide Microemulsion with Fluorine-free Surfactant

Research Project

  • PDF
Project/Area Number 23685034
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Environmental chemistry
Research InstitutionHirosaki University

Principal Investigator

SAGISAKA Masanobu  弘前大学, 大学院・理工学研究科, 助教 (60374815)

Project Period (FY) 2011 – 2012
Keywords界面活性剤 / 超臨界二酸化炭素 / マイクロエマルション / 逆ミセル / フッ素フリー
Research Abstract

Supercritical CO_2 (scCO_2) have been attracted much attention as a substitute solvent of VOC, however it is usually poor solvent for polar materials. To use scCO_2 in various industrial fields, scCO_2 should have dispersed water droplets, that is, a water/scCO_2 microemulsion (W/CO_2 μE). This study successfully developed an inexpensive and environmentally-acceptable non-fluorinated surfactant as a stabilizer for W/CO_2 μE.

  • Research Products

    (28 results)

All 2013 2012 2011 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (19 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Efficient Nanoparticle Synthesis using W/CO-2Microemulsions having a high solubilizing power fluorinated surfactant2013

    • Author(s)
      Masanobu Sagisaka, Shuho Iwama, Junya Tamada, Atsushi Yoshizawa
    • Journal Title

      Mater. Technol

      Volume: 31, 2 Pages: 44-55

    • Peer Reviewed
  • [Journal Article] An Effective and Efficient Surfactant for CO_2 Having Only Short Fluorocarbon Chains2012

    • Author(s)
      Masanobu Sagisaka, Shuho Iwama, AtsushiYoshizawa, Azmi Mohamed, Stephen Cummings, Julian Eastoe
    • Journal Title

      Langmuir

      Volume: 28, 30 Pages: 10988-10996

    • Peer Reviewed
  • [Journal Article] Hybrid CO_2-philic Surfactants with LowFluorine Content2012

    • Author(s)
      Azmi Mohamed, Masanobu Sagisaka, Martin Hollamby, Sarah E. Rogers, Richard K Heenan, Robert Dyer and Julian Eastoe
    • Journal Title

      Langmuir

      Volume: 28,15 Pages: 6299-6306

    • Peer Reviewed
  • [Journal Article] Low Fluorine Content CO_2-philic surfactants2011

    • Author(s)
      Julian Eastoe, Azmi Mohamed, Masanobu Sagisaka, Fredric Guittard, Stephen Cummings, Alison Paul, Sarah Rogers, Richard Heenan, Robert Dyer
    • Journal Title

      Langmuir

      Volume: 27, 17 Pages: 10562-10569

    • Peer Reviewed
  • [Journal Article] Super-Efficient Surfactant for StabilizingWater-in-Carbon Dioxide Microemulsions2011

    • Author(s)
      Masanobu Sagisaka, Shuho Iwama, Satoshi Hasegawa, Atsushi Yoshizawa, Azmi Mohamed, Stephen Cummings, Sarah E. Rogers, Richard K. Heenan, Julian Eastoe
    • Journal Title

      Langmuir

      Volume: 27,10 Pages: 5772-5780

    • Peer Reviewed
  • [Journal Article] Near-Infrared Spectroscopic Study of aWater-in-Supercritical CO_2 Microemulsion as a Function of the Water Content2011

    • Author(s)
      Yoshihiro Takebayashi, Masanobu Sagisaka, Kiwamu Sue, Satoshi Yoda, Yukiya Hakuta, Takeshi Furuya
    • Journal Title

      J. Phys. Chem. B

      Volume: 115, 19 Pages: 6111-6118

    • Peer Reviewed
  • [Journal Article] Highly Methyl-Branched Hydrocarbon Surfactant as a CO_2-philic Solubilizer for Water/Supercritical CO_2 Microemulsion

    • Author(s)
      Masanobu Sagisaka, Kotaro Kudo, Shota Nagoya, Atsushi Yoshizawa
    • Journal Title

      J. Oleo Sci

      Volume: accepted

    • Peer Reviewed
  • [Presentation] Self-assemblies ofHighly Methyl-Branched HydrocarbonSurfactants in Supercritical Carbon Dioxide2013

    • Author(s)
      Masanobu Sagisaka
    • Organizer
      87th ACS Colloid & Surface Science Symposium
    • Place of Presentation
      University of California, Riverside, USA
    • Year and Date
      2013-06-25
  • [Presentation] フッ素系多鎖型界面活性剤の超臨界CO_2中での水可溶化能力2012

    • Author(s)
      鷺坂将伸
    • Organizer
      2012年材料技術研究協会討論会
    • Place of Presentation
      東京理科大学(野田)
    • Year and Date
      2012-12-08
  • [Presentation] W/CO_2系分子集合体の曲率に及ぼすフッ素系二鎖型界面活性剤の混合の効果2012

    • Author(s)
      鷺坂 将伸
    • Organizer
      2012年材料技術研究協会討論会
    • Place of Presentation
      東京理科大学(野田)
    • Year and Date
      2012-12-08
  • [Presentation] ラメラ液晶の動的形成-崩壊挙動~ミクロ相分離と分子不均一性の共同作用~2012

    • Author(s)
      鷺坂将伸
    • Organizer
      日本液晶学会ソフトマターフォーラム第2回勉強会
    • Place of Presentation
      弘前大学(弘前)
    • Year and Date
      2012-10-19
  • [Presentation] 水とCO_2を溶媒とした機能性分子集合体の形成と高効率ナノ材料製造等将来技術への応用2012

    • Author(s)
      鷺坂将伸
    • Organizer
      日本化学会秋季事業第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学(東京)
    • Year and Date
      2012-10-15
  • [Presentation] Formation of HighlyFunctional Molecular Assemblies in Supercritical Carbon Dioxide2012

    • Author(s)
      Masanobu Sagisaka
    • Organizer
      World Congress on Oleo Science (WCOS 2012) &29th ISF Congress-JOCS/AOCS/KOCS/ISF Joint Meeting
    • Place of Presentation
      アルカス佐世保(佐世保)
    • Year and Date
      2012-10-03
  • [Presentation] 超臨界二酸化炭素中での分子集合体の形成制御と将来技術2012

    • Author(s)
      鷺坂将伸
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      北大学(仙台)
    • Year and Date
      2012-09-19
  • [Presentation] 鎖長の異なる二鎖型フッ素系界面活性剤の混合によるW/CO_2系逆ミセ ルの曲率制御2012

    • Author(s)
      鷺坂将伸
    • Organizer
      第10回超臨界流体ミニワークショップ
    • Place of Presentation
      新潟会館(新潟)
    • Year and Date
      2012-09-09
  • [Presentation] 多分岐型C12炭化水素を疎水鎖とした界面活性剤のW/CO_2マイクロ エマルションの形成能力2012

    • Author(s)
      鷺坂将伸
    • Organizer
      第10回超臨界流体ミニワークショップ
    • Place of Presentation
      新潟会館(新潟)
    • Year and Date
      2012-09-09
  • [Presentation] 圧力や温度に応答する分子集合体の構築と応用~分子集合体の新たな可能性の創出を目指して~2012

    • Author(s)
      鷺坂将伸
    • Organizer
      2012年度日本油化学会若手の会サマースクール
    • Place of Presentation
      愛知健康プラザ(知多郡)
    • Year and Date
      2012-08-02
  • [Presentation] 超臨界CO_2中での自己組織化と水の分散2012

    • Author(s)
      鷺坂将伸
    • Organizer
      化学工学会東北支部第20回 若手の会セミナー
    • Place of Presentation
      八戸工業高等専門学校(八戸)
    • Year and Date
      2012-06-16
  • [Presentation] Fluorinated Double-tail CO_2-philic Surfactants with Sulfoglutarate Head Groups2012

    • Author(s)
      Masanobu Sagisaka
    • Organizer
      InternationalAssociation of Colloid and InterfaceScientists' Conference (IACIS2012)
    • Place of Presentation
      Sendai,Japan
    • Year and Date
      2012-05-17
  • [Presentation] 超臨界CO_2中に形成した二鎖型フッ素系界面活性剤逆ミセルの形態と挙動2011

    • Author(s)
      鷺坂将伸,岩間修穂,工藤厚太郎,長谷川聡,吉澤篤
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学(名古屋)
    • Year and Date
      2011-09-15
  • [Presentation] 水と二酸化炭素からなる省エ ネルギー型グリーンソルベント2011

    • Author(s)
      鷺坂将伸
    • Organizer
      イノベーション・ジャパン2011-大学見本市
    • Place of Presentation
      東京国際フォーラム(東京)
    • Year and Date
      2011-09-12
  • [Presentation] 多分岐型炭化水素系界面活性剤によるW/CO_2マイクロエマルションの構築2011

    • Author(s)
      工藤厚太郎,鷺坂将伸,吉澤篤
    • Organizer
      第63回コロイドおよび界面化学討論会
    • Place of Presentation
      京都大学吉田キャンパス(京都)
    • Year and Date
      2011-09-08
  • [Presentation] 水/CO_2マイクロエマルションの形成に及ぼす二鎖型フッ素系界面活性剤のフッ化炭素鎖長およびスペーサー長の影響2011

    • Author(s)
      岩間修穂,吉澤篤,鷺坂将伸
    • Organizer
      第63回コロイドおよび界面化学討論会
    • Place of Presentation
      京都大学吉田キャンパス(京都)
    • Year and Date
      2011-09-08
  • [Presentation] 鎖長に依存しないフッ素系グルタレート型界面活性剤のCO_2中への水の可溶化能2011

    • Author(s)
      岩間修穂,吉澤篤,鷺坂将伸
    • Organizer
      第9回超臨界流体ミニワークショップ
    • Place of Presentation
      東京理科大学大子研修センター(茨城)
    • Year and Date
      2011-08-21
  • [Presentation] イソステアリル基を有する界面活性剤のCO_2中への水の可溶化2011

    • Author(s)
      工藤厚太郎,吉澤篤,鷺坂将伸
    • Organizer
      第9回超臨界流体ミニワークショップ
    • Place of Presentation
      東京理科大学大子研修センター(茨城)
    • Year and Date
      2011-08-21
  • [Presentation] 水/二酸化炭素複合系分子集合体の構築と高効率/低環境負荷技術への応用2011

    • Author(s)
      鷺坂将伸
    • Organizer
      社団法人新化学技術推進協会新素材技術部会講演会
    • Place of Presentation
      新化学発展協会(東京)
    • Year and Date
      2011-04-15
  • [Remarks]

    • URL

      http://www.st.hirosaki-u.ac.jp/~lclab/

  • [Patent(Industrial Property Rights)] Surfactant for Stabilizing Water/Supercritical Carbon Dioxide Microemulsion2012

    • Inventor(s)
      Masanobu Sagisaka, Kudo Kotaro, Hida Masahiro, Yasufumi Shikauchi
    • Industrial Property Rights Holder
      Masanobu Sagisaka, Kudo Kotaro, Hida Masahiro, Yasufumi Shikauchi
    • Industrial Property Number
      特許、13/582,580
    • Filing Date
      2012-10-02

URL: 

Published: 2014-08-29  

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