Development of Oxidative Carbon-Carbon Bond Forming Reactions Based on the Concept of Site Isolation

2014 Fiscal Year Final Research Report

• Project/Area Number: 23685036
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Environmental chemistry
• Research Institution: Shibaura Institute of Technology
• Principal Investigator: TAJIMA TOSHIKI 芝浦工業大学, 工学部, 准教授 (50361770)
• Project Period (FY): 2011-04-01 – 2015-03-31
• Keywords: 有機化学 / 活性点分離 / 炭素カチオン

Outline of Final Research Achievements

We have successfully developed direct oxidative carbon-carbon bond forming reactions based on the concept of site isolation. We have also developed indirect oxidative carbon-carbon bond forming reactions using anodic hydroxylation as a key step. Furthermore, one-pot electrosynthesis (paired electrosynthesis) of β-nitroalcohols using benzylalcohols as a starting material has been achieved based on the site isolation between an anode and a cathode in electrochemical reactions.

Free Research Field

有機電気化学