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2013 Fiscal Year Final Research Report

Development of novel host molecule-metal ion complexes having enzyme-like catalytic activities for the highly efficient removal and degradation of toxic compounds

Research Project

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Project/Area Number 23710090
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental technology/Environmental materials
Research InstitutionNagoya University

Principal Investigator

MATSUMIYA Hiroaki  名古屋大学, エコトピア科学研究所, 准教授 (10362287)

Project Period (FY) 2011 – 2013
Keywordsチアカリックスアレーン / 複核金属錯体 / 金属ナノ粒子 / アルキルアンモニウム塩 / アドミセル / 加水分解 / 還元的脱塩素化 / 起泡分離
Research Abstract

The present study was conducted with a view to developing highly efficient environ mental purification systems by which the removal and subsequent detoxification of hazardous chemicals can be achieved with novel host molecule metal ion complexes having enzyme-like activities. Taking fenitrothion and perchloroethylene as examples of hazardous chemicals, hybrid materials were prepared for their removal from water followed by their degradation. As an extension of the present study, quaternary ammonium salts having chemical structures similar to those of surfactants of importance in the above-mentioned hybrid materials were applied as reaction media to hydrolyze cellulose, which is a key step in processing plant-origin biomasses, and to convert the hydrolysis products into a platform chemical of valuable materials.

  • Research Products

    (9 results)

All 2013 2012 2011

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (6 results)

  • [Journal Article] Collection of trace metals with cationic surfactant-silica particles followed by flotation with an anionic surfactant for seawater analysis2012

    • Author(s)
      H. Matsumiya, K. Kitakata, M. Hiraide
    • Journal Title

      Analytical and Bioanalytical Chemistry

      Volume: vol.402, no.5 Pages: 1973-1977

    • Peer Reviewed
  • [Journal Article] Ionic liquid-based extraction of heteropoly molybdic acids for the sensitive determination of Si, P, and As in high-purity iron2012

    • Author(s)
      H. Matsumiya, Y. Inagaki, M. Hiraide
    • Journal Title

      ISIJ International

      Volume: vol.52, no.1 Pages: 101-104

    • Peer Reviewed
  • [Journal Article] 界面活性剤ミセル溶液中におけるセリウム(IV)-チアカリックス[4]アレーン錯体のリン酸エステルに対する加水分解触媒活性2012

    • Author(s)
      永井真二,松宮弘明,平出正孝
    • Journal Title

      分析化学

      Volume: vol.61, no.8 Pages: 723-726

    • Peer Reviewed
  • [Presentation] 水中テトラクロロエチレンの迅速捕集とその場分解を指向する Fe/Ni担持アドミセルの調製2013

    • Author(s)
      赤星祐樹,近藤傑,松宮弘明
    • Organizer
      第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県名古屋市)
    • Year and Date
      20131122-23
  • [Presentation] 環境水中の医療用ガドリニウム錯体の存在形態別分析2012

    • Author(s)
      井上博人,松宮弘明,平出正孝
    • Organizer
      第31回溶媒抽出討論会
    • Place of Presentation
      石川県文教会館(石川県金沢市)
    • Year and Date
      20121116-17
  • [Presentation] チアカリックスアレーン錯体を利用するイムノアッセイ用標識の設計2012

    • Author(s)
      松宮弘明,福島浩之,平出正孝
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学角間キャンパス(石川県金沢市)
    • Year and Date
      20120919-21
  • [Presentation] アドミセルによる水中有機リン系農薬フェニトロチオンの濃縮および加水分解と簡易定量2012

    • Author(s)
      松宮弘明,彦坂博之,平出正孝
    • Place of Presentation
      金沢大学角間キャンパス(石川県金沢市)
    • Year and Date
      20120919-21
  • [Presentation] Chemical speciation of clinically used Gd complexes in environmental water2011

    • Author(s)
      H. Matsumiya, H. Inoue, M. Hiraide
    • Organizer
      International Symposium on EcoTopia Science 2011
    • Place of Presentation
      Nagoya University (Nagoya, Japan)
    • Year and Date
      20111209-11
  • [Presentation] イオン液体を用いるヘテロポリ酸の抽出と高純度鉄分析への応用2011

    • Author(s)
      松宮弘明,稲垣育亮,平出正孝
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県名古屋市)
    • Year and Date
      20110914-16

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Published: 2015-06-25  

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