2013 Fiscal Year Final Research Report
Synthesis and application of electron-deficient heterocyclic carbene species
| Project/Area Number |
23750038
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
SEGAWA Yasutomo 名古屋大学, 理学(系)研究科(研究院), 特任准教授 (60570794)
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| Project Period (FY) |
2011 – 2013
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| Keywords | カルベン / ピリジリデン / パラジウム / Ｘ線結晶構造解析 |
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| Research Abstract |
In this research, we uncovered properties of new chemical species "pyridylidene" and synthesized a new pyridylidene metal complex toward the application to catalytic reaction. First we successfully generated free pyridylidene and reacted it with several reagents. Moreover, decomposition pathway of pyridylidene was also found. Next we synthesized bidentate bis-2-pyridylidene palladium complex, which has very unique electronic and structural characters and moreover it can be synthesized only three steps from commercially available compounds easily. The synthetic method can also be applicable to other late transition metals so that establishment of new catalyst library utilizing high stability and donation ability of pyridylidene.
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