2012 Fiscal Year Final Research Report
Development of chiral organic conductor based on TTF-functionalized oligo(imidazole)-helicates
| Project/Area Number |
23750039
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
MURATA Tsuyoshi 大阪大学, 大学院・理学研究科, 招へい研究員 (40535358)
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| Project Period (FY) |
2011 – 2012
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| Keywords | 有機導体 / キラリティー / ヘリケート / 合成化学 |
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| Research Abstract |
In order to explore multi-functional molecular materials by the combination of the helical chirality of oligoimidazole-helicates and TTF-based molecular conductors, we designed TTF-functionalized oligoimidazoles. We succeeded in the synthesis of a benzo-TTF substituted quaterimidazole, which selectively formed a dinuclear triple-helicate with Ni(II) ion. TTF skeletons of the helicate were oxidized with iodine to give a semiconducting salt.
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