2012 Fiscal Year Final Research Report
Development of Synthetic Methods of Polyaromatics by UsingCarbon-phosphorus Triple-bond Molecules
| Project/Area Number |
23750051
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Fukuoka University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2012
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| Keywords | 有機元素化学 / 芳香族化合物 / 環化付加反応 |
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| Research Abstract |
The chemistry of phosphinine, a heavier analogue of pyridine, has been studied extensively for a long time since the synthesis of the first stable phosphinine in 1966. In contrast to the chemistry of phosphinine, there have been limitedly reports on the synthesis and characterization of its polyaromatic analogue, such as phosphanaphthalenes and phosphaanthracenes. We report herein synthesis and novel property of a new type of phosphinines and phosphanaphthalenes. We have succeeded in the synthesis of polyaromatics containing a phosphorus atom by using carbon-phosphorus triple bond molecules as a key compound.
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