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2012 Fiscal Year Final Research Report

Development of dehydrogenative group 14 element-boran bond formation reaction catalyzed by an iron complex

Research Project

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Project/Area Number 23750063
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionOsaka City University

Principal Investigator

ITAZAKI Masumi  大阪市立大学, 大学院・理学研究科, 講師 (60382032)

Project Period (FY) 2011 – 2012
Keywords有機金属化学
Research Abstract

Reaction of Cp(CO)Fe(GePh_3)(py) with HBpin afforded the iron(IV) hydrido complex Cp(CO)Fe(H)(GePh_3)(Bpin). On the other hand, photoreaction of HBpin with 3 equimolar amount of Et_3SiH for 3 days at 5 ℃ in the presence of 10 mol% of Cp(

  • Research Products

    (31 results)

All 2013 2012 2011

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (21 results) Book (2 results)

  • [Journal Article] Selective Dehydrogenative SilylationHydrogenation Reaction of Divinyldisiloxane with Hydrosilane Catalyzed by an Iron Complex2012

    • Author(s)
      Roman N. Naumov, Masumi Itazaki, Masahiro Kamitani, and Hiroshi Nakazawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Pages: 804-807

    • DOI

      DOI:10.1021/ja209436s

    • Peer Reviewed
  • [Journal Article] O-CN Bond Cleavage of Cyanates by a Transition-Metal Complex2012

    • Author(s)
      Kozo Fukumoto, AbdelRahman A. Dahy, Tsukuru Oya, Kazumasa Hayasaka, Masumi Itazaki, Nobuaki Koga, and Hiroshi Nakazawa
    • Journal Title

      Organometallics

      Volume: 31 Pages: 787-790

    • DOI

      DOI:10.1021/om201257h

    • Peer Reviewed
  • [Journal Article] Catalytic Synthesis of Cyclic and Linear Germoxanes Mediated by Iron Complex2012

    • Author(s)
      Masahiro Kamitani, Kozo Fukumoto, Ryosuke Tada, Masumi Itazaki, and Hiroshi Nakazawa
    • Journal Title

      Organometallics

      Volume: 31

    • DOI

      DOI:10.1021/om300184

    • Peer Reviewed
  • [Journal Article] Regioselective Double Hydrophosphination of Terminal Aryacetylenes Catalyzed by an Iron Complex2012

    • Author(s)
      Masahiro Kamitani, Masumi Itazaki, Chihiro Tamiya, Hiroshi Nakazawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 11932-11935

    • DOI

      DOI:10.1021/ja304818c

    • Peer Reviewed
  • [Journal Article] Characterization, and Crystal Structure of cis-[Pt(Me)_2- {PPh_2(OMe)}_2] and the Conversion into cis-[Pt(OH_2)_2{PPh_2(Ome)}_2][Otf]_22011

    • Author(s)
      Masumi Itazaki, Y uka Shigesato, and Hiroshi Nakazawa
    • Journal Title

      Heteroatom Chem

      Volume: 22 Pages: 371-376

    • DOI

      DOI:10.1002/hc

    • Peer Reviewed
  • [Journal Article] Trans-Selective Hydrogermylation of Alkynes Promoted by Methylironand Bis(germyl)hydridoiron Complexes as a Catalyst Precursor2011

    • Author(s)
      Masumi Itazaki, Masahiro Kamitani, and Hiroshi Nakazawa
    • Journal Title

      Chem. Commun

      Volume: 47 Pages: 7854-7856

    • DOI

      DOI:10.1021/cr100347k

    • Peer Reviewed
  • [Journal Article] Dehydrogenative Coupling of Thiol with Hydrosilane Catalyzed by an Iron Complex2011

    • Author(s)
      Kozo Fukumoto, Michiho Kasa, TsukuruOya, Masumi Itazaki, and Hiroshi Nakazawa
    • Journal Title

      Organometallics

      Volume: 30 Pages: 3461-3463

    • DOI

      DOI:10.1021/om200377e

    • Peer Reviewed
  • [Journal Article] Synthesis of Silyl-molybdenium Complexes Connected by a 1,1'-Metallocenylene Unit and Their Electrochemical Properties2011

    • Author(s)
      Masumi Itazaki, Akio Ichimura, and Hiroshi Nakazawa
    • Journal Title

      Eur. J. Inorg. Chem.

      Pages: 5496-5501

    • DOI

      DOI:10.1002/ejic.201100867

    • Peer Reviewed
  • [Presentation] フェロセニルシリル配位子を 2 つ有するルテニウム(IV)ヒドリド錯体の合成と電気化学的性質2013

    • Author(s)
      板崎真澄, 重里有香, 南方牧子, 石井翔, 市村彰男, 中沢 浩
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀県、立命館大学
    • Year and Date
      20130322-25
  • [Presentation] 1,1'-フェロセンジカルコゲナト配位子を有する白金錯体の合成と反応性2013

    • Author(s)
      板崎真澄, 井関柾登, 伊藤昌輝, 中沢浩
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀県、立命館大学
    • Year and Date
      20130322-25
  • [Presentation] ハロゲン化インジウムを配位子とする 鉄およびルテニウム錯体の合成と構造2013

    • Author(s)
      伊藤昌輝, 板崎真澄, 中沢 浩
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀県、立命館大学
    • Year and Date
      20130322-25
  • [Presentation] 新規ヒドリド/ヒドロシリル二官能性鉄触媒の合成およびアルコールとの反応性2012

    • Author(s)
      神谷昌宏, 板崎真澄, 中沢 浩
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山県、富山大学
    • Year and Date
      20120921-23
  • [Presentation] 1,1-フェロセンジカルコゲナト基を配位子とする遷移金属多核錯体の合成と性質2012

    • Author(s)
      伊藤昌輝, 板崎真澄, 山本健弥, 中沢浩
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山県、富山大学
    • Year and Date
      20120921-23
  • [Presentation] Hydrogen Production from Alcohols Promoted by an Iron Complex2012

    • Author(s)
      神谷昌宏 , 板崎真澄 , 中沢 浩
    • Organizer
      第59有機金属化学討論会
    • Place of Presentation
      大阪府、大阪大学
    • Year and Date
      20120913-15
  • [Presentation] Hydrogermylation of Alkyne Promoted by an Iron Catalyst2012

    • Author(s)
      M. Kamitani, M. Itazaki, and H. Nakazawa
    • Organizer
      XXV International Conference on Organometallic Chemistry
    • Place of Presentation
      Lisbon, Portugal
    • Year and Date
      20120902-07
  • [Presentation] Double Hydrophosphination of Alkynes with Secondary Phosphones Promoted by Iron Catalyst2012

    • Author(s)
      H. Nakazawa, M. Kamitani, M. Itazaki, and C. Tamiya
    • Organizer
      19th International Conference on Phosphorus Chemistry
    • Place of Presentation
      Rotterdam, The Netherlands
    • Year and Date
      20120708-12
  • [Presentation] Selective Synthesis of Cyclic and Linear Germoxanes Catalyzed by an Iron Complex2012

    • Author(s)
      H. Nakazawa, M. Kamitani, R. Tada, K. Fukumoto, and M. Itazaki
    • Organizer
      The 10th International Conference on Heteroatom Chemistry、
    • Place of Presentation
      京都府、京都大学
    • Year and Date
      20120521-25
  • [Presentation] ジアミノ置換ホスフィンを丹治する白金錯体上のアルキル/ハロゲン交換反応に関する量子化学的研究2012

    • Author(s)
      高島麻里、土田敦子、重里有香、板崎真澄、中沢 浩、鷹野景子
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス
    • Year and Date
      2012-03-25
  • [Presentation] Synthesis of Silyl-molybdenum Complexes Connected by a 1,1'-Metallocenylene Unit and Their Electrochemical Properties2011

    • Author(s)
      M. Itazaki, A. Ichimura, and H. Nakazawa
    • Organizer
      Inorganic Chemistry '11
    • Place of Presentation
      Inorganic Chemistry '11
    • Year and Date
      2011-12-05
  • [Presentation] Synthesis of Silyl-molybdenum Complexes Connected by a 1,1'-Metallocenylene Unit and Their Electrochemical Properties2011

    • Author(s)
      M. Itazaki, A. Ichimura, and H. Nakazawa
    • Organizer
      Inorganic Symposium 2011
    • Place of Presentation
      Melbourne, Australia
    • Year and Date
      2011-11-30
  • [Presentation] Selective Synthesis of Linear Germoxanes Catalyzed by an Iron Complex2011

    • Author(s)
      R. Tada, M. Kamitani, M. Itazaki, and H. Nakazawa
    • Organizer
      The 16th Osaka City University International Symposium
    • Place of Presentation
      Osaka
    • Year and Date
      2011-11-09
  • [Presentation] Synthesis of Transition-metal Complexes Containing 1,1'-Ferrocenedithiolate or 1,1'-Ferrocenediserenate Ligand and Their Electrochemical Properties、2011

    • Author(s)
      M. Ito, M. Itazaki, K. Yamamoto, and H. Nakazawa
    • Organizer
      The 16th Osaka City University International Symposium
    • Place of Presentation
      Osaka
    • Year and Date
      2011-11-09
  • [Presentation] Double Hydrophosphination of Alkyne Promoted by Iron Catalyst2011

    • Author(s)
      C. Tamiya, M. Kamitani, M. Itazaki, and H. Nakazawa、
    • Organizer
      The 16th Osaka City University International Symposium
    • Place of Presentation
      Osaka
    • Year and Date
      2011-11-09
  • [Presentation] 1,1'-ビスシリルメタロセンを配位子とする白金ヒドリド二核錯体の合成と反応2011

    • Author(s)
      仲間幸俊、南方牧子、板崎真澄、中沢 浩
    • Organizer
      第15回ケイ素化学協会シンポジウム
    • Place of Presentation
      シ-パル須磨
    • Year and Date
      2011-10-21
  • [Presentation] Synthesis and Catalytic Reactivity of Iron(IV) Complex Bearing Two Heavier Group 14 Element Ligands2011

    • Author(s)
      M. Kamitani, M. Itazaki, K. Ueda, and H. Nakazawa
    • Organizer
      3rd Asian Conference on Coordination Chemistry
    • Place of Presentation
      New Delhi, India
    • Year and Date
      2011-10-19
  • [Presentation] ハロゲン化ホスフィンを担持する白金錯体の X/Me (X = Cl, Br) 交換反応に関する量子化学的研究2011

    • Author(s)
      土田敦子、高島麻里、重里有香、板崎真澄、中沢 浩、鷹野景子
    • Organizer
      錯体化学第61回討論会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      2011-09-17
  • [Presentation] Regioselective Synthesis of Vinyl Germanes Catalyzed by an Iron Complex2011

    • Author(s)
      神谷昌宏、板崎真澄、中沢 浩
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2011-09-08
  • [Presentation] Theoretical Study of Alkyl/Halogen Exchange Reaction on Pt Complexes with Phosphine Ligand2011

    • Author(s)
      高島麻里、土田敦子、重里有香、板崎真澄、中沢 浩、鷹野景子
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2011-09-08
  • [Presentation] Selective Formation of Cyclic and Linear Germoxanes from Hydrogermane and Amide Catalyzed by an Iron Complex2011

    • Author(s)
      H. Nakazawa, M. Kamitani, R. Tada, and M. Itazaki
    • Organizer
      The 3nd Latinoamerican Symposium on Coordination and Organometallic Chemistry
    • Place of Presentation
      La Serena, Chile
    • Year and Date
      2011-07-27
  • [Book] 無機化学演習 大学院入試問題を中心2012

    • Author(s)
      中沢 浩、西岡孝訓、篠田哲史、廣津昌和、三宅弘之、板崎真澄
    • Total Pages
      215
    • Publisher
      東京化学同人
  • [Book] Topics in Organometallic Chemistry Vol. 33 Chapter 22011

    • Author(s)
      Hiroshi Nakazawa and Masumi Itazaki
    • Total Pages
      55
    • Publisher
      Springer

URL: 

Published: 2014-09-25  

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