2012 Fiscal Year Final Research Report
Structural Chirality Based on Side-chain Ordering of Polymer and its application of Stimuli-responsive Chiral Discrimination
| Project/Area Number |
23750086
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Analytical chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
SHUNDO Atsuomi 九州大学, 大学院・工学研究院, 助教 (40585915)
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| Project Period (FY) |
2011 – 2012
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| Keywords | 表面・界面 / キラリティー / 薄膜 |
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| Research Abstract |
We have designed and synthesized a polymer having the structural chirality induced by the side-chain ordering. The contact angle measurements using chiral liquids as a probe revealed that the polymer film has the enantioselective surface properties. The enantioselectivity was associated with a surface organization via the local conformational change of the polymer chains. Also, we have successfully fabricated a polymer film, which enables us to determine the enantiomeric purity of the liquids by observing the change in the fluorescence emission.
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