2012 Fiscal Year Final Research Report
Study towards nitrene transfer reaction using azide based on design of new iron catalyst
| Project/Area Number |
23750116
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | The Institute of Physical and Chemical Research |
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Principal Investigator |
EGAMI Hiromichi 独立行政法人理化学研究所, 袖岡有機合成化学研究室, 客員研究員 (50553848)
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| Project Period (FY) |
2011 – 2012
|
| Keywords | 二核錯体 / 触媒 / 鉄 / 銅 / 酸化反応 / 酸化的官能基化反応 |
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| Research Abstract |
A synthetic method for a new series of ligands, which were designed based on a working hypothesis, has been established as originally planned, and some metal complexes were prepared. Although an efficient catalyst for a nitrene transfer reaction using azide as a nitrene source could not be found at this moment, it was found that some complexes worked as catalysts for aerobic oxidation during this study. On the other hand, a new method for oxidative introduction of an amine functionality into olefins was established.
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