2012 Fiscal Year Final Research Report
Synthesis of Polymer Membranes with Hierarchically Arrayed ChiralNanopores and Development of Supersmart Separation Ability
| Project/Area Number |
23750121
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Niigata University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2012
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| Keywords | 機能性高分子 |
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| Research Abstract |
Stereoregular one-handed helical artificial polymers similar to biopolymers such as DNA or enzymes were synthesized and could formed self-supporting membranescomposed of the regular one-handed helical polymers by casting of the polymer solution. By removing of chiral substituents hierarchically arranged along the main chain, self-supporting membranes having nano-pores imprinting of chiral information originated from the chiral substituents could be synthesized. The obtained membrane having chiral imprinted nano-pores showed a optical resolutionability which is promising to application for drug development.
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[Journal Article] Chiral Teleinduction in Asymmetric Polymerization of 3,5-Bis(hydroxymethyl)phenylacetylene Having a Chiral Group via a Very Long and Rigid Spacer at 4-Position2012
Author(s)
Yunosuke Abe, Toshiki Aoki, Hongge Jia, Shingo Hadano, Takeshi Namikoshi, YurikoKakihana, Lijia Liu, Yu Zang, Masahiro Teraguchi, Takashi Kaneko
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Journal Title
Chemistry Letters
Volume: 41(3)
Pages: 244-246
DOI
Peer Reviewed
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