2013 Fiscal Year Final Research Report
Development of Asymmetric Polymer Catalysts Based on Controlled Helical Structure
| Project/Area Number |
23750123
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
IIDA Hiroki 名古屋大学, 工学(系)研究科(研究院), 講師 (30464150)
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| Project Period (FY) |
2011 – 2013
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| Keywords | 機能性高分子 / キラリティ / 高分子不斉触媒 / 不斉識別 / らせん構造 |
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| Research Abstract |
In this project, we have developed optically active helical polymers containing organocatalytic units as the pendant or main chain, and investigated their asymmetric organocatalysis and chiral recognition ability with the anticipation that the one-handed helical conformation would enhance the enantioselectivity and chiral recognition ability as compared to those of the corresponding random polymers and monomers. We have successfully synthesized a series of optically active helical polymers consisting of naturally-occurring riboflavin (vitamin B2) and cinchona alkaloid derivatives that function as asymmetric catalysts, chiral stationary phases for HPLC, and chiral sensory materials.
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