2012 Fiscal Year Final Research Report
Synthesis of Functionalized Dendronized Polymers
| Project/Area Number |
23750127
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Tottori University (2012)
Kyoto University (2011) |
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Principal Investigator |
NOKAMI Toshiki 鳥取大学, 大学院・工学研究科, 准教授 (60402963)
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| Project Period (FY) |
2011 – 2012
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| Keywords | ナノ材料創成 / ナノ機能材料 / 高分子反応 / 分解 / 機能性高分子 / 高分子合成 |
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| Research Abstract |
In order to achieve the surface functionalization of dendronized polymers, it is necessary to develop the synthetic methods of dendronized polymers equipped with transformable functional groups at the terminal position. Therefore, we initiated our study by generating dendritic carbocations having transformable functional groups and investigated their reactions with polymers. Dendronized polymers thus-obtained were treated with palladium catalyst and organometallic reagents to demonstrated the surface modification of dendronized polymers by cross-coupling reactions.
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