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2012 Fiscal Year Final Research Report

Development of Optical Separation Systems Based on theEnantioselective Solvation Property of Chiral Ionic Liquids

Research Project

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Project/Area Number 23750147
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

ICHIKAWA Takahiro  東京農工大学, 大学院・工学研究院, 助教 (80598798)

Project Period (FY) 2011 – 2012
Keywordsイオン液体 / 液晶 / アミノ酸イオン液体 / 双連続キュービック液晶
Research Abstract

A series of amino acid ionic liquids were prepared as chiral ionic liquids. Mixing of these amino acid ionic liquids and some amphiphilic molecules provided lyotropic liquid-crystalline materials forming various nanostructures. It was found that these materials exhibited bicontinuous cubic phases having three-dimensionally interconnected nanochannels depending on the selection of amino acid anion, design of amphiphilic molecules, and the composition of the two components. The three-dimensional nachannels are composed of amino acid ionic liquids. It was found that these channels function as efficient ion transporting pathways.

  • Research Products

    (12 results)

All 2013 2012 2011

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (7 results)

  • [Journal Article] イオン液体界面研究の進歩と展開2013

    • Author(s)
      大野弘幸、一川尚広、河野雄樹
    • Journal Title

      表面科学

      Volume: 34巻 Pages: 166-172

    • URL

      http://www.sssj.org/jsssj/Vol34/34-04/index.htm

  • [Journal Article] 3DContinuousWaterNanosheetasaGyroidMinimalSurfaceFormedbyBicontinuousCubicLiquid-CrystallineZwitterions2012

    • Author(s)
      一川尚広、加藤隆史、大野弘幸
    • Journal Title

      JournaloftheAmericanChemicalSociety誌

      Volume: 134巻 Pages: 11354-11357

    • DOI

      DOI:10.1021/ja304124w

    • Peer Reviewed
  • [Journal Article] Nano-Biphasic Ionic Liquid SystemsComposed of Hydrophobic Phosphonium Salts and a Hydrophilic Ammonium Salt2012

    • Author(s)
      田口怜美、一川尚広、加藤隆史、大野弘幸
    • Journal Title

      Chemical Communications誌

      Volume: 48巻 Pages: 5271-5273

    • DOI

      DOI:10.1039/C2CC31074K

    • Peer Reviewed
  • [Journal Article] Co-Organisationof Ionic Liquids with Amphiphilic Diethanolamines: Construction of 3D Continuous Ionic Nanochannels through the Induction of Liquid-CrystallineBicontinuous Cubic Phases2012

    • Author(s)
      一川尚広、吉尾正史、田口怜美、鍵本純子、大野弘幸、加藤隆史
    • Journal Title

      Chemical Science誌

      Volume: 3巻 Pages: 2001-2008

    • DOI

      DOI:10.1039/c2sc00981a

    • Peer Reviewed
  • [Journal Article] AnisotropicProton-Conductive Materials Formed by the Self-Organization ofPhosphonium-Type Zwitterions2011

    • Author(s)
      上田紗織、鍵本純子、一川尚広、加藤隆史、大野弘幸
    • Journal Title

      Advanced Materials誌

      Volume: 23巻 Pages: 3071-3074

    • DOI

      DOI:10.1021/ja304124w

    • Peer Reviewed
  • [Presentation] JAISTInternational Symposium on IonicsMaterials2013

    • Author(s)
      一川尚広・加藤隆史・大野弘幸
    • Organizer
      Bicontinuous CubicLiquid-Crystalline Assemblies Formed through Self-Organization of IonicLiquids
    • Place of Presentation
      石川県、北陸先端科学技術大学院大学
    • Year and Date
      20130313-14
  • [Presentation] 2012年イオン液体討論会2012

    • Author(s)
      一川尚広・加藤隆史・大野弘幸
    • Organizer
      Zwitterionの自己組織化を利用した三次元プロトン伝導性界面の構築
    • Place of Presentation
      沖縄県、沖縄県男女共同参画センター「てぃるる」
    • Year and Date
      20121207-09
  • [Presentation] 2012年液晶討論会2012

    • Author(s)
      一川尚広・加藤隆史・大野弘幸
    • Organizer
      双連続キュービック液晶を用いた三次元プロトン伝導性界面の構築
    • Place of Presentation
      千葉県、千葉大学
    • Year and Date
      20120905-07
  • [Presentation] ILCC20122012

    • Author(s)
      一川尚広、吉尾正史、田口怜美、鍵本純子、大野弘幸、加藤隆史
    • Organizer
      Construction of 3D Continuous IonicNanochannels Through the Induction of Bicontinuous Cubic Liquid-Crystalline Phases
    • Place of Presentation
      ドイツ、Landeshauptstadt Mainz
    • Year and Date
      20120819-24
  • [Presentation] 2011年液晶討論会2011

    • Author(s)
      一川尚広、上田紗織、鍵本純子、加藤隆史、大野弘幸
    • Organizer
      ホスホニウム塩型Zwitterionを用いた異方的プロトン伝導材料の構築
    • Place of Presentation
      東京都、東京都市大学世田谷キャンパス
    • Year and Date
      20110911-13
  • [Presentation] FAPS2011

    • Author(s)
      一川尚広、吉尾正史、濱崎淳志、鍵本純子、大野弘幸、加藤隆史
    • Organizer
      Development of Nanostructured Ion-Conductive Polymer Films Having 3D Interconnected Ion Nano-Channels
    • Place of Presentation
      中国、China National Convention Center
    • Year and Date
      20110508-11
  • [Presentation] 液晶化学シンポジウム2011

    • Author(s)
      一川尚広、上田紗織、鍵本純子、加藤隆史、大野弘幸
    • Organizer
      Zwitterionの自己組織化による異方的プロトン伝導材料の構築
    • Place of Presentation
      東京大学山上会館
    • Year and Date
      2011-06-07

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Published: 2014-09-25  

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