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2012 Fiscal Year Final Research Report

Development of photoconnectable molecular materials for efficient formation of photopatterning structure

Research Project

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Project/Area Number 23750153
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionYokohama National University

Principal Investigator

UBUKATA Takashi  横浜国立大学, 大学院・工学研究院, 准教授 (00344028)

Project Period (FY) 2011 – 2012
Keywords光物性 / 光架橋 / 光開裂 / 光微細加工 / レリーフ
Research Abstract

We have designed and synthesized a series of photopolymerizable molecules. Thin films were prepared from the synthesized molecules. Solid state polymerization proceeded upon irradiation with ultra-violet light. When the film was irradiated with spatially patterned ultra-violet light, regular surface reliefs with the same period of the patterned light were produced due to the lateral mass transfer from the shaded areas to the irradiated areas. Though the produced surface relief could be erased by heating, the stability of the relief structure was improved as compared to the other surface relief forming materials.

  • Research Products

    (27 results)

All 2013 2012 2011

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (18 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Bisarylindenols: Fixation of Conformation Makes Basic Properties of Photochromism based on6π-Electrocyclization Exceptional2012

    • Author(s)
      Hatsune Ogawa, Kazuya Takagi, Takashi Ubukata, Akiko Okamoto, Noriyuki Yonezawa, Stephanie Delbaere, Yasushi Yokoyama
    • Journal Title

      Chem. Commun

      Volume: 48 Pages: 11838-11840

    • DOI

      DOI:n10.1039/c2cc35793c

    • Peer Reviewed
  • [Journal Article] Photo-triggered Surface Relief of Polystyrene Films-Highly Photo-sensitive Formation by the Addition of a Benzophenone Derivative2012

    • Author(s)
      Takashi Ubukata, Shintaro Yamamoto, Yusuke Moriya, Shohei Fujii, Yasushi Yokoyama
    • Journal Title

      J.Photopolym. Sci. Technol.

      Volume: 25 Pages: 675-678

    • DOI

      DOI:10.2494/photopolymer.25.675

    • Peer Reviewed
  • [Journal Article] Phototriggered Micromanufacturing Using Photoresponsive Amorphous SpirooxazineFilms2012

    • Author(s)
      Takashi Ubukata, Shohei Fujii, Kento Arimatsu, Yasushi Yokoyama
    • Journal Title

      J. Mater. Chem.

      Volume: 22 Pages: 14410-14417

    • DOI

      DOI:10.1039/c2jm32149a

    • Peer Reviewed
  • [Journal Article] Facile One-Step Photopatterning of Polystyrene Films2012

    • Author(s)
      Takashi Ubukata, Yusuke Moriya, Yasushi Yokoyama
    • Journal Title

      Polym. J

      Volume: 44 Pages: 966-972

    • Peer Reviewed
  • [Journal Article] Dual-Mode Fluorescence Switching of Photochromic Bisthiazolylcoumarin2012

    • Author(s)
      Kazushi Suzuki, Takashi Ubukata, Yasushi Yokoyama
    • Journal Title

      Chem. Commun.

      Volume: 48 Pages: 765-767

    • DOI

      DOI:10.1039/c1cc166516j

    • Peer Reviewed
  • [Journal Article] Photochromic Behavior of a Bisthienylethene Bearing Cu(I)-1,10-phenanthroline Complexes2012

    • Author(s)
      Shun Uehara, Yuma Hiromoto, Stela Minkovska, Kazushi Suzuki, Takashi Ubukata, Yasushi Yokoyama
    • Journal Title

      Dyes Pigments

      Volume: 92 Pages: 861-867

    • DOI

      DOI:10.1016/j.dyepig.2011.04.003

    • Peer Reviewed
  • [Journal Article] Highly Diastereoselective Photochromic Ring Closure of Bisbenzothienylethenes Possessing Dual Fluorinated Stereocontroller2011

    • Author(s)
      Yasushi Yokoyama, Tohomohiko Hasegawa, Takashi Ubukata
    • Journal Title

      Dyes Pigments

      Volume: 89 Pages: 223-229

    • DOI

      DOI:1016/j.dyepig.2010.03.008

    • Peer Reviewed
  • [Presentation] 局所的な光反応による表面レリーフ形成2013

    • Author(s)
      生方俊
    • Organizer
      光応答分子材料に関する3大学共同セミナー
    • Place of Presentation
      キャンパスプラザ京都
    • Year and Date
      2013-03-26
  • [Presentation] スピロオキサジン薄膜およびドロップレットの光誘起物質移動2013

    • Author(s)
      有松研人・藤井祥平・生方俊
    • Organizer
      第八回ナノテク交流シンポジウム
    • Place of Presentation
      横浜市立大学金沢八景キャンパス
    • Year and Date
      2013-03-06
  • [Presentation] Formation of Phototriggered Surface Relief on Photopolymerizable Anthracene Film2012

    • Author(s)
      Megumi Nakayama, Takashi Ubukata, Yasushi Yokoyama
    • Organizer
      The9th SPSJ International Polymer Conference(IPC 2012)
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      2012-12-12
  • [Presentation] Phototriggered Self-micromanufacturing Using Photoresponsive Organic Films2012

    • Author(s)
      Takashi Ubukata, Shohei Fujii, Kento Arimatsu
    • Organizer
      2012EMN Fall Meeting
    • Place of Presentation
      Las Vegas, Nevada, USA
    • Year and Date
      2012-11-30
  • [Presentation] Photo-Triggered Mass Transfer by Spatially Patterned Photo ‐ Isomerization2012

    • Author(s)
      Takashi Ubukata, Shohei Fujii, Kento Arimatsu
    • Organizer
      ICEAN-2012: International Conference on Emerging Advanced Nanomaterials
    • Place of Presentation
      Brisbane, Australia
    • Year and Date
      2012-10-23
  • [Presentation] 光物質移動によるレリーフ形成2012

    • Author(s)
      生方 俊
    • Organizer
      産業技術総合研究所所内講演会
    • Place of Presentation
      産業総合研究所つくばセンター
    • Year and Date
      2012-10-03
  • [Presentation] 光によるスピロオキサジン分子の移動に基づく表面レリーフ2012

    • Author(s)
      生方 俊 ・藤井祥平・有松研人・横山 泰
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2012-09-20
  • [Presentation] スピロオキサジン薄膜の光表面レリーフ形成2012

    • Author(s)
      有松研人・藤井祥平・生方 俊 ・横山 泰
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2012-09-19
  • [Presentation] 光反応による拡散制御に基づくレリーフ形成2012

    • Author(s)
      生方 俊
    • Organizer
      第2回液晶若手シンポジウム
    • Place of Presentation
      芝浦工業大学芝浦キャンパス
    • Year and Date
      2012-09-08
  • [Presentation] Phototriggered Surface Relief Formation of Polystyrene Films2012

    • Author(s)
      Takashi Ubukata, Shintaro Yamamoto, Yusuke Moriya, Shohei Fujii, Kento Arimatsu, Yasushi Yokoyama
    • Organizer
      The 29th International Conference of Photopolymer Science and Technology (ICPST29)
    • Place of Presentation
      Chiba, Japan
    • Year and Date
      2012-06-29
  • [Presentation] 光異性化によるスピロオキサジンドロップ レットの移動2012

    • Author(s)
      有松研人・藤井祥平・生方 俊 ・横山 泰
    • Organizer
      第53回湘北地区懇話会
    • Place of Presentation
      神奈川大学湘南ひらつかキャンパス
    • Year and Date
      2012-06-15
  • [Presentation] 光連結性ア ントラセン薄膜を用いた光表面レリーフ形成2012

    • Author(s)
      中山 恵・生方 俊 ・横山 泰
    • Organizer
      第61回高分子年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2012-05-29
  • [Presentation] 光異性化によるスピロオキサジンドロップ レットの移動2012

    • Author(s)
      有松研人・藤井祥平・生方 俊 ・横山 泰
    • Organizer
      第61回高分子年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2012-05-29
  • [Presentation] 光を用いた分子拡散制御によるレリーフ形成2012

    • Author(s)
      生方 俊
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学 日 吉・矢上キャンパス
    • Year and Date
      2012-03-26
  • [Presentation] 光反応による拡散制御に基づく レリーフ創製2012

    • Author(s)
      生方 俊
    • Organizer
      精密ネットワークポリマー研究会 第5回若手シンポジウム
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2012-03-09
  • [Presentation] ジアリールエテンアモルファス薄膜による光表面レリーフ形成2012

    • Author(s)
      中山 恵・生方 俊 ・横山 泰
    • Organizer
      第七回ナノテク交流シンポジウム
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2012-03-02
  • [Presentation] 泰ス ピロオキサジン薄膜の光物質移動によるレリーフ形成2011

    • Author(s)
      生方 俊 ・藤井祥平・有松研人・横山
    • Organizer
      特定領域研究「フォトクロミズムの攻究とメカニカル機能の創出」第8回公開シンポジウム
    • Place of Presentation
      東京大学本郷キャンパス
    • Year and Date
      2011-11-29
  • [Presentation] ベンゾフェノン混合ポリスチレン薄膜の光表面レリーフ2011

    • Author(s)
      生方俊・山本慎太郎・横山泰
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学津島
    • Year and Date
      2011-09-30
  • [Book] Molecular Switches 22011

    • Author(s)
      Yasushi Yokoyama, Tsuyoshi Gushiken, Takashi Ubukata
    • Total Pages
      81-95
    • Publisher
      Wiley-VCH
  • [Patent(Industrial Property Rights)] パターン形成方法2012

    • Inventor(s)
      生方 俊、中山 恵、木原 秀元、吉 田 勝
    • Industrial Property Rights Holder
      生方 俊、中山 恵、木原 秀元、吉 田 勝
    • Industrial Property Number
      特許 特願 2012-250411
    • Filing Date
      2012-11-14

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Published: 2014-09-25  

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