Function of ion transport in 1-D channels of porous coordination polymer

2012 Fiscal Year Final Research Report

• Project/Area Number: 23750155
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Functional materials chemistry
• Research Institution: Kyoto University
• Principal Investigator: HORIKE Satoshi 京都大学, 工学研究科・合成・生物化学専攻, 助教 (70552652)
• Project Period (FY): 2011 – 2012
• Keywords: イオン伝導 / 錯体化学 / 固体 NMR / 配位高分子

Research Abstract

Coordination polymer having 1 nm of 1-D channels are suitable to accommodate the proton carrier molecules and we observed the anhydrous proton conductivity above 100 degC. The accommodated azoles are able to rotate in solid state, and the dynamic behavior provides the anhydrous proton conduction. The conductivity were monitored by solid state NMR and impedance spectroscopy, and the optimized structure shows over 10-3S/cm of conductivity.

Research Products

• [Journal Article] Post-synthesis modification of a porous coordination polymer by LiCl to enhance H+ transpor (2013)
  • Author(s): Satoshi Horike, Yusuke Kamitsubo, Munehiro Inukai, Tomohiro Fukushima, Daiki Umeyama, Tomoya Itakura, Susumu Kitagawa
  • Journal Title: J. Am. Chem. Soc Volume: 135 Pages: 4612-4615
  • Peer Reviewed
• [Journal Article] Pore design of two-dimensional coordination polymers toward selective adsorption (2013)
  • Author(s): Yuh Hijikata, Satoshi Horike, Masayuki Sugimoto, Munehiro Inukai, Tomohiro Fukushima, Susumu Kitagawa
  • Journal Title: Inorg. Chem Volume: 52 Pages: 3634-3642
  • Peer Reviewed
• [Journal Article] Susumu KitagawaSoft 2-D layer porous coordination polymers with 1,2-di(4-pyridyl)ethaneAust (2013)
  • Author(s): Keisuke Kishida, Satoshi Horike, Kanokwan Kongpatpanich
  • Journal Title: J. Chem Volume: 66 Pages: 464-469.
  • Peer Reviewed
• [Journal Article] Fe2+ Layered Porous Coordination Polymers and Soft Encapsulation of Guest via Redox Activity (2013)
  • Author(s): Satoshi Horike, Masayuki Sugimoto, Kanokwan Kongpatpanich, Yuh Hijikata, Munehiro Inukai, Daiki Umeyama, Shinji Kitao, Makoto Seto, Susumu Kitagawa
  • Journal Title: J. Mater. Chem. Volume: 1 Pages: 3675-3679
  • Peer Reviewed
• [Journal Article] Highly Selective CO2 Adsorption Accompanied with Low-Energy Regeneration in a Two-Dimensional Cu(II) Porous Coordination Polymer with Inorganic Fluorinated PF6- Anions (2012)
  • Author(s): Shin-ichiro Noro, Yuh Hijikata, Munehiro Inukai, Tomohiro Fukushima, Satoshi Horike, Masakazu Higuchi, Susumu Kitagawa, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: Inorg. Chem Volume: 52 Pages: 280-285
  • Peer Reviewed
• [Journal Article] Investigation of post-grafted groups of a porous coordination polymer and its proton conduction behavior (2012)
  • Author(s): Munehiro Inukai, Satoshi Horike, Daiki Umeyama, Yuh Hijikata, Susumu Kitagawa
  • Journal Title: Dalton Trans Volume: 41 Pages: 13261-13263
  • Peer Reviewed
• [Journal Article] Modular Design of Domain Assembly in Porous Coordination Polymer Crystals via Reactivity-Directed Crystallization Process (2012)
  • Author(s): Tomohiro Fukushima, Satoshi Horike, Hirokazu Kobayashi, Masahiko Tsujimoto, Seiji Isoda, Maw Lin Foo, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
  • Journal Title: J. Am. Chem. Soc Volume: 134 Pages: 13341-13347
  • Peer Reviewed
• [Journal Article] Inherent Proton Conduction in 2-D Coordination Framework (2012)
  • Author(s): Daiki Umeyama, Satoshi Horike, Munehiro Inukai, Tomoya Itakura, Susumu Kitagawa
  • Journal Title: J. Am. Chem. Soc Volume: 134 Pages: 12780-12785
  • Peer Reviewed
• [Journal Article] A Soft Copper(II) Porous Coordination Polymer with Unprecedented Aqua Bridge and Selective Adsorption Properties (2012)
  • Author(s): Elsa Quartapelle Procopio, Tomohiro Fukushima, E. Barea, Jorge A. R. Navarro, Satoshi Horike, Susumu Kitagawa
  • Journal Title: Chem. Eur Volume: 18 Pages: 13117-13125
  • Peer Reviewed
• [Journal Article] Ligand-based Solid Solution Approach to Stabilisation of Sulphonic Acid Groups in Porous Coordination Polymer Zr6O4(OH)4(BDC)6 (UiO-66) (2012)
  • Author(s): Maw Lin Foo, Satoshi Horike, Tomohiro Fukushima, Yuh Hijikata, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
  • Journal Title: Dalton Trans Volume: 41 Pages: 13791-13794
  • Peer Reviewed
• [Journal Article] Dense Coordination Network Capable of Selective CO2 Capture from C1 and C2 Hydrocarbons (2012)
  • Author(s): Satoshi Horike, Keisuke Kishida, Yoshihiro Watanabe, Yasutaka Inubushi, Daiki Umeyama, Masayuki Sugimoto, Tomohiro Fukushima, Munehiro Inukai, Susumu Kitagawa
  • Journal Title: J. Am. Chem. Soc Volume: 134 Pages: 9852-9855
  • Peer Reviewed
• [Journal Article] Design of Flexible Lewis Acidic Sites in Porous Coordination Polymers by using the Viologen Moiety (2012)
  • Author(s): Masakazu Higuchi, Kohei Nakamura, Satoshi Horike, Yuh Hijikata, Nobuhiro Yanai, Tomohiro Fukushima, Jungeun Kim, Kenichi Kato, Masaki Takata, Daisuke Watanabe, Shinji Oshima, Susumu Kitagawa
  • Journal Title: Angew. Chem. Int. Volume: 51 Pages: 8369-8372
  • Peer Reviewed
• [Journal Article] Coordination-Network-Based Ionic Plastic Crystal for Anhydrous Proton Conductivity (2012)
  • Author(s): Satoshi Horike, Daiki Umeyama, Munehiro Inukai, Tomoya Itakura, Susumu Kitagawa
  • Journal Title: J. Am. Chem. Soc Volume: 134 Pages: 7612-7615
  • Peer Reviewed
• [Journal Article] An Alkaline Earth I3O0 Porous Coordination Polymer: [Ba2TMA(NO3)(DMF)] (H3TMA = trimesic acid) (2012)
  • Author(s): Maw Lin Foo, Satoshi Horike, Yasutaka Inubushi, Susumu Kitagawa
  • Journal Title: Angew. Chem. Int Volume: 51 Pages: 6107-6111
  • Peer Reviewed
• [Journal Article] Synthesis and Adsorption Properties of Azulene-Containing Porous Interdigitated Framework (2012)
  • Author(s): Keisuke Kishida, Satoshi Horike, Keiji Nakagawa, Susumu Kitagawa
  • Journal Title: Chem. Lett Volume: 41 Pages: 425-426
  • Peer Reviewed
• [Journal Article] A Solid Solution Approach to 2D Coordination Polymers for CH4/CO2 and CH4/C2H6 Gas Separation: Equilibrium and Kinetic Studies (2012)
  • Author(s): Satoshi Horike, Yasutaka Inubushi, Takashi Hori, Tomohiro Fukushima, Susumu Kitagawa
  • Journal Title: Chem. Sci Volume: 3 Pages: 116-120
  • Peer Reviewed
• [Presentation] 金属錯体機能の根源を探る～分子構造とその変化様式の探求最前線 (2013)
  • Organizer: 分子研研究会
  • Place of Presentation: 分子科学研究所
  • Year and Date: 2013-03-13
• [Presentation] Ion transfer in the restricted channels of coordination polymer (2013)
  • Organizer: iCeMS Trilateral Australia-USA-Japan Symposium on Porous Materials
  • Place of Presentation: 京都大学
  • Year and Date: 2013-03-08
• [Presentation] Dynamic coordination framework materials for new energy resources (2013)
  • Organizer: International meeting "Nanomaterial Futures" of Bristol Centre for Functional Nanomaterials
  • Place of Presentation: ブリストル大学
  • Year and Date: 2013-02-19
• [Presentation] 多孔性錯体の動的結晶化学を用いた環境・エネルギー固体材料の開発 (2012)
  • Organizer: 第92回日本化学会年会
  • Place of Presentation: 慶應義塾大学
  • Year and Date: 2012-03-26
• [Presentation] Porous coordination polymer as crystalline ion transporter (2011)
  • Organizer: 第62回錯体化学討論会
  • Place of Presentation: 富山大学
  • Year and Date: 2011-09-17
• [Book] 空間の「柔らかさ」を利用した CO2 分離 (2012)
  • Author(s): 堀毛悟史、犬伏康貴
  • Total Pages: 38-39
• [Book] イオン伝導性配位高分子堀毛悟史 (2012)
  • Author(s): 堀毛悟史
  • Total Pages: 884-885
  • Publisher: 日本化学会
• [Book] 配位高分子を用いたリチウム二次電池-無機・有機に続く第三の材料となるか (2012)
  • Author(s): 堀毛悟史
  • Total Pages: 67-68
  • Publisher: 化学同人
• [Book] 材料科学の基礎 (2012)
  • Author(s): 堀毛悟史、坂本裕俊、杉本雅行、福島知宏、岸田圭輔、梅山大樹、北川進
  • Total Pages: 2-13
  • Publisher: シグマ アルドリッチ ジャパン株式会社
• [Book] Metal-Organic Frameworks : Applications from Catalysis to Gas StoragePart 1 - Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future (2011)
  • Author(s): Satoshi Horike, Susumu Kitagawa
  • Total Pages: 3-21
  • Publisher: Wiley-VCH