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2012 Fiscal Year Final Research Report

Parallel Polymer Reactions on Site-Isolated Solid Electrodes

Research Project

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Project/Area Number 23750172
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

INAGI Shinsuke  東京工業大学, 大学院・総合理工学研究科, 講師 (70456268)

Project Period (FY) 2011 – 2012
Keywords高効率反応設計 / 高分子反応 / 電解反応 / 導電性高分子 / バイポーラ電解 / 環境 調和型プロセス / パラレル反応 / 傾斜材料
Research Abstract

In this work, a novel method involving anodic oxidation and cathodic reduction for polymers in one-pot was developed. These parallel polymer reactions successfully produced two products from a single polymer at the same time with high current efficiencies. The use of bipolar electrochemistry well extended the parallel reactions to provide novel gradient materials.

  • Research Products

    (10 results)

All 2013 2012 2011 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (3 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Parallel Polymer Reactions of a Polyfluorene Derivative via Electrochemical Oxidation and Reduction2013

    • Author(s)
      S. Inagi, H. Nagai, I. Tomita, T. Fuchigami
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] Electro-Click Modification of Conducting Polymer Surface Using Cu(I) Species Generated on a Bipolar Electrode in a GradientManner2012

    • Author(s)
      N. Shida, Y. Ishiguro, M. Atobe, T.Fuchigami, S. Inagi
    • Journal Title

      ACS Macro Lett

      Volume: 1 Pages: 656-659

    • Peer Reviewed
  • [Journal Article] Site-controlled Application ofElectric Potential on a Conducting Polymer "Canvas"2012

    • Author(s)
      Y. Ishiguro, S. Inagi, T. Fuchigami
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 4034

    • Peer Reviewed
  • [Presentation] 電極電子移動に基づいた導電性高分子膜の機能化に関する研究2013

    • Author(s)
      稲木信介
    • Organizer
      電気化学会第80回大会
    • Place of Presentation
      東北大学川内キャンパス
    • Year and Date
      2013-03-30
  • [Presentation] Gradient Introduction of Fluoro-Functional Groups onto Conducting Polymer Surface2012

    • Author(s)
      S. Inagi
    • Organizer
      The 8th Japanese-French Joint Seminar on Fluorine Chemistry
    • Place of Presentation
      Otani Hall, Kyoto
    • Year and Date
      2012-07-20
  • [Presentation] Solid-state Modification of Conducting Polymers on Electrode2011

    • Author(s)
      S. Inagi, N. Shida, T. Fuchigami
    • Organizer
      10th International Symposium onOrganic Reactions
    • Place of Presentation
      KeioUniversity, Yokohama
    • Year and Date
      2011-11-23
  • [Book] Trends in Polyaniline Research2013

    • Author(s)
      S. Inagi, N. Shida, T. Fuchigami
    • Total Pages
      (in press)
    • Publisher
      Nova Science Publishers, Inc
  • [Book] Encyclopedia of Applied Electrochemistry2013

    • Author(s)
      S. Inagi
    • Total Pages
      (in press)
    • Publisher
      Springer
  • [Remarks]

    • URL

      http://www.echem.titech.ac.jp/~inagi/index.html

  • [Patent(Industrial Property Rights)] 高分子膜の製造方法、高分子膜付き導電性基板、高分子膜製造用電解重合装置

    • Inventor(s)
      稲木信介,淵上寿雄,石黒豊
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      特許、特願 2011-196319

URL: 

Published: 2014-09-25  

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