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2012 Fiscal Year Final Research Report

Surface structures analysis and function control for lithium battery reaction

Research Project

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Project/Area Number 23750237
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

HIRAYAMA Masaaki  東京工業大学, 大学院・総合理工学研究科, 講師 (30531165)

Project Period (FY) 2011 – 2012
Keywordsイオン交換体 / 伝導体 / 二次電池
Research Abstract

Interfacial reactions of lithium batteries have been determined by in situ X-ray surface scattering measurements using epitaxial thin-films electrodes. The interracial structures determine the power density and the stability of lithium-excess layered material electrodes. Surface modification by Li3 PO4 solid electrolyte improved the stability of the electrode structure upon battery operations. Mechanical and technical development of surface structures is of considerable importance for improving the power characteristics and cyclability of new-generation batteries.

  • Research Products

    (15 results)

All 2013 2012 Other

All Journal Article (5 results) Presentation (8 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Fabrication and electrochemical properties of LiMn 2 O4 /SrRuO3 multi-layer epitaxial thin film electrodes2013

    • Author(s)
      Kota Suzuki, Kyungsu Kim, Sou Taminato, Masaaki Hirayama and Ryoji Kanno
    • Journal Title

      Journal of Power Sources

      Volume: 226 Pages: 340-345

    • DOI

      doi:10.1016/j.jpowsour.2012.11.008.

  • [Journal Article] Multiple Electron Reaction of Li2 RuO3Electrode for Lithium Batteries2013

    • Author(s)
      SouTaminato, Masaaki Hirayama, Kunimitsu Yamamoto, Yueming Zheng and Ryoji Kanno
    • Journal Title

      Journal of the Japan Society of Powder and Powder Metallurgy

      Volume: 60 Pages: 24-28

    • DOI

      doi:10.2497/jjspm.60.24

  • [Journal Article] High-capacity phase formation by surface modification of Li3 PO4 on nanosized Li2 RuO3 electrode for lithium batteries2012

    • Author(s)
      Yueming Zheng, Sou Taminato, Youlong Xu, Kota Suzuki, Kyungsu Kim, Masaaki Hirayama and Ryoji Kanno
    • Journal Title

      Journal of Power Sources

      Volume: 208 Pages: 447-451

    • DOI

      doi:10.1016/j.jpowsour.2012.02.044

  • [Journal Article] Oxygen Evolution and Reduction Reactions on La0.8 Sr 0.2 CoO3 (001), (110), and (111) Surfaces in an Alkaline Solution2012

    • Author(s)
      Mamoru Komo, Asuna Hagiwara, Sou Taminato, Masaaki Hirayama and Ryoji Kanno
    • Journal Title

      Electrochemistry

      Volume: 80 Pages: 834-838

    • DOI

      doi:10.5796/electrochemistry.80.834.

  • [Journal Article] Functional evaluation of lithium battery materials based on the control of anisotropy2012

    • Author(s)
      Masaaki Hirayama and Ryoji Kanno
    • Journal Title

      Bulletin of the Ceramic Society of Japan

      Volume: 47 Pages: 270-274

  • [Presentation] 中性子反射率法によるリチウム電池電極/電解質界面構造変化の直接観察2013

    • Author(s)
      平山雅章
    • Organizer
      中性子産業利用推進協議会薄膜・界面研究会
    • Year and Date
      2013-09-03
  • [Presentation] 中性子反射率法を用いたLi Ti O 負極表面の皮膜形成機構解析2013

    • Author(s)
      平山雅章, Kim Kyungsu, 鈴木耕太, 田港聡, 菅野了次, 山田悟史, 米村雅雄
    • Organizer
      電気化学会第80回大会
    • Year and Date
      2013-03-29
  • [Presentation] リチウム電池電極電解質界面における構造と電池特性2013

    • Author(s)
      平山雅章
    • Organizer
      化合物新磁性材料研究会
    • Year and Date
      2013-03-15
  • [Presentation] 中性子反射率法によるLi4 Ti5 O12 電極/電解質界面の構造解析2012

    • Author(s)
      平山雅章, 鈴木耕太, Kim KyungSu, 田港聡, 菅野了次, 山田悟史, 米村雅雄
    • Organizer
      第53回電池討論会
    • Year and Date
      2012-11-15
  • [Presentation] In Situ Neutron Reflectometry Analysis ofLi4 Ti5 O12 /Electrolyte Interface UsingTwo-Dimensional Model Electrode2012

    • Author(s)
      M. Hirayama, K. Suzuki, K. Kim, S. Taminato, R. Kanno, N. Yamada, M. Yonemura
    • Organizer
      Pacific Rim Meeting on Electrochemiacl and Solid-State Science (PRiME2012)
    • Year and Date
      2012-10-09
  • [Presentation] Enhanced Electrochemical Properties of Li4 Ti5 O12 Epitaxial Thin Film Electrode with Surface Modification2012

    • Author(s)
      K. Kim, K. Suzuki, S. Taminato, K. Tamura, J. Mizuki, J. Son, M. Hirayama, R. Kanno
    • Organizer
      Pacific Rim Meeting on Electrochemiacl and Solid-State Science (PRiME2012)
    • Year and Date
      2012-10-09
  • [Presentation] Interfacial Reaction on Li3 PO4 /Li2 RuO3Thin-Film Electrode2012

    • Author(s)
      S. Taminato, K. Suzuki, K.Kim, J. Son, K. Tamura, J. Mizuki, M. Hirayama, R. Kanno
    • Organizer
      Pacific Rim Meeting on Electrochemiacl and Solid-State Science (PRiME2012)
    • Year and Date
      2012-10-09
  • [Presentation] Studies on Reactions and Structures at Electrode/Electrolyte Interface Using Epitaxial Model Electrodes2012

    • Author(s)
      R. Kanno, M.Hirayama, K. Tamura
    • Organizer
      Pacific Rim Meeting onElectrochemiacl and Solid-StateScience(PRiME2012)
    • Year and Date
      2012-10-08
  • [Book] 高性能リチウムイオン電池開発最前線(共著)2013

    • Total Pages
      45-53
    • Publisher
      エヌ・ティー・エス
  • [Remarks]

    • URL

      http://www.echem.titech.ac.jp/~kanno/index.html

URL: 

Published: 2014-09-25  

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