2013 Fiscal Year Final Research Report
Syntheses of novel lithium-ion conductors by using inorganic-organic hybrid layered crystals
| Project/Area Number |
23750246
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Tokai University |
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Principal Investigator |
ITO Takeru 東海大学, 理学部, 講師 (50376935)
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| Research Collaborator |
OZEKI Tomoji 東京工業大学, 理工学研究科, 准教授 (60214136)
NARUKE Haruo 東京工業大学, 資源化学研究所, 准教授 (40237623)
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| Project Period (FY) |
2011 – 2013
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| Keywords | ハイブリッド材料 / ポリ酸 / 層状結晶 / 界面活性剤 / 伝導性 |
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| Research Abstract |
Inorganic-organic hybrid crystals containing polyoxometalate inorganic cluster anion and cationic surfactant were successfully synthesized by a simple cation-exchange solution process. These hybrid crystals, which are rare series of materials, consisted of alternate stacking manner of polyoxometalate inorganic layers and surfactant organic layers. In addition, polyoxometalate-surfactant hybrid crystals containing metal ions or protons were obtained. These hybrid crystals exhibited anhydrous conductivity at intermediate temperature range over 373 K, and are promising candidates for ion-conductive solid electrolytes.
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